Two‐Inch‐Sized Perovskite CH3NH3PbX3 (X = Cl, Br, I) Crystals: Growth and Characterization

Two-inch-sized perovskite crystals, CH3 NH3 PbX3 (X=I, Br, Cl), with high crystalline quality are prepared by a solution-grown strategy. The availability of large perovskite crystals is expected to transform its broad applications in photovoltaics, optoelectronics, lasers, photodetectors, LEDs, etc., just as crystalline silicon has done in revolutionizing the modern electronics and photovoltaic industries.

[1]  Blaise J. Thompson,et al.  Solution growth of single crystal methylammonium lead halide perovskite nanostructures for optoelectronic and photovoltaic applications. , 2015, Journal of the American Chemical Society.

[2]  H. Bolink,et al.  Trap‐Assisted Non‐Radiative Recombination in Organic–Inorganic Perovskite Solar Cells , 2015, Advanced materials.

[3]  Qingfeng Dong,et al.  Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals , 2015, Science.

[4]  E. Sargent,et al.  Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals , 2015, Science.

[5]  Yang Liu,et al.  Bulk crystal growth of hybrid perovskite material CH3NH3PbI3 , 2015 .

[6]  Yongbo Yuan,et al.  Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells , 2014, Nature Communications.

[7]  W. Jaegermann,et al.  Properties of CH3NH3PbX3 (X = I, Br, Cl) Powders as Precursors for Organic/Inorganic Solar Cells , 2014 .

[8]  M. Grätzel,et al.  Thermal Behavior of Methylammonium Lead- trihalide Perovskite Photovoltaic Light Harvesters , 2014 .

[9]  M. Grätzel,et al.  A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability , 2014, Science.

[10]  Peng Gao,et al.  Effect of Annealing Temperature on Film Morphology of Organic–Inorganic Hybrid Pervoskite Solid‐State Solar Cells , 2014 .

[11]  Christophe Ballif,et al.  Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance. , 2014, The journal of physical chemistry letters.

[12]  David Cahen,et al.  Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells. , 2014, The journal of physical chemistry letters.

[13]  Yixin Zhao,et al.  Mesoporous perovskite solar cells: material composition, charge-carrier dynamics, and device characteristics. , 2014, Faraday discussions.

[14]  T. Dittrich,et al.  Formation of a passivating CH3NH3PbI3/PbI2 interface during moderate heating of CH3NH3PbI3 layers , 2013 .

[15]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[16]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[17]  Mercouri G Kanatzidis,et al.  Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. , 2013, Inorganic chemistry.

[18]  Martin Schreyer,et al.  Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications , 2013 .

[19]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[20]  R. Ramer,et al.  Films and crystalline powder of PbI2 intercalated with ammonia and pyridine , 2009 .

[21]  B. Pivac,et al.  Dislocation-related deep levels in carbon rich p-type polycrystalline silicon , 2007 .

[22]  I. Swainson,et al.  The ordered phase of methylammonium lead chloride CH3ND3PbCl3 , 2005 .

[23]  J. Abushama,et al.  Investigation of defect properties in Cu(In,Ga)Se2 solar cells by deep-level transient spectroscopy , 2004 .

[24]  H. Mashiyama,et al.  Structural Study on Cubic–Tetragonal Transition of CH3NH3PbI3 , 2002 .

[25]  F. Hasoon,et al.  Deep-level impurities in CdTe/CdS thin-film solar cells , 2000 .

[26]  A. Kasuya,et al.  Blue shift in ultraviolet absorption spectra of monodisperse CeO2−x nanoparticles , 2000 .

[27]  Modélisation moléculaire et calcul des fréquences de vibration du sous-réseau perovskite dans CH3NH3PbCl3 , 1999 .

[28]  Kangning Liang,et al.  Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique , 1998 .

[29]  A. Maâlej,et al.  Phase transitions and crystal dynamics in the cubic perovskite CH3NH3PbCl3 , 1997 .

[30]  J. R. Ayres,et al.  Characterization of trapping states in polycrystalline‐silicon thin film transistors by deep level transient spectroscopy , 1993 .

[31]  Hiroshi Suga,et al.  Calorimetric and IR spectroscopic studies of phase transitions in methylammonium trihalogenoplumbates (II) , 1990 .

[32]  Albrecht Poglitsch,et al.  Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy , 1987 .

[33]  O. Knop,et al.  Cation rotation in methylammonium lead halides , 1985 .

[34]  R. D. Shannon Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides , 1976 .

[35]  R. Bube Trap Density Determination by Space‐Charge‐Limited Currents , 1962 .