Crystalline AlN thin films were deposited by laser ablation of high purity Al target in nitrogen reactive atmosphere. An YAG laser (λ=1.06 μm, tFWHM=10 ns, 0.3 J/pulse), was used as laser source. The material was collected on (100) and (111) Si wafers, The target collector distance was varied in the range 3–6 cm, the nitrogen pressure was set in the range of 10−3–10−1 mbar, the collectors were heated at different temperatures between 20 and 350°C. The influence of the process parameters on the physical and piezoelectric properties of the deposited films was analyzed. X-ray diffraction studies revealed different crystalline orientation depending on deposition conditions: collectors temperature, position and orientation, reactive gas pressure, incident laser fluence. The profile of Al and N atoms inside the film were characterized by SIMS analysis. Small oxygen traces are present at collector–film interface. Depth profile X-ray photoelectron spectroscopy confirms the existence — in particular experimental conditions — of only Al–N bonds inside the film.