Synthesis and optical properties of different colloidal systems of gold nanoparticles in a chiral dispersant agent

Three kinds of colloids containing gold nanoparticles (AuNP) were obtained by three different methods of synthesis, using castor oil as dispersant agent and tetrachloroauric (III) acid as gold source. The colloidal systems were characterized by Uv-vis spectroscopy and transmission electron microscopy (TEM). Each method gave rise to quasispherical shape and different size distribution of AuNP. The TEM images of the nanostrutured systems show that from each method of synthesis, nanoparticles of different average sizes, equal to 7, 15, and 55 nm, were produced. These characteristics are reflected by the presence of different maximum wavelength absorption, indicating that each colloid presents distinct surface Plasmon resonance bands.

[1]  R. Raval Chemistry: Mirrors in Flatland , 2003, Nature.

[2]  J. Dupont,et al.  Transition-metal nanoparticles in imidazolium ionic liquids: recyclable catalysts for biphasic hydrogenation reactions. , 2002, Journal of the American Chemical Society.

[3]  Luis M. Liz-Marzán,et al.  Reduction and Stabilization of Silver Nanoparticles in Ethanol by Nonionic Surfactants , 1996 .

[4]  A. Bakuzis,et al.  Aggregate formation on polydisperse ferrofluids: A Monte Carlo analysis , 2005 .

[5]  J. Dupont,et al.  The role of Pd nanoparticles in ionic liquid in the Heck reaction. , 2005, Journal of the American Chemical Society.

[6]  R. Murray,et al.  Monolayer-protected cluster molecules. , 2000, Accounts of chemical research.

[7]  Shuming Nie,et al.  Direct Observation of Size-Dependent Optical Enhancement in Single Metal Nanoparticles , 1998 .

[8]  Babeş,et al.  Synthesis of Iron Oxide Nanoparticles Used as MRI Contrast Agents: A Parametric Study. , 1999, Journal of colloid and interface science.

[9]  Gerald J. Meyer,et al.  Biological applications of high aspect ratio nanoparticles , 2004 .

[10]  Jandir M. Hickmann,et al.  Large spatial self-phase modulation in castor oil enhanced by gold nanoparticles , 2006, SPIE LASE.

[11]  Robert C. Haddon,et al.  C60 thin film transistors , 1995 .

[12]  Paul Mulvaney,et al.  Synthesis of Nanosized Gold−Silica Core−Shell Particles , 1996 .

[13]  Luis M. Liz-Marzán,et al.  Nanometals: Formation and color , 2004 .

[14]  Michael Vollmer,et al.  Optical properties of metal clusters , 1995 .

[15]  R. L. Williamson,et al.  Optical properties of gold colloids formed in inverse micelles , 1993 .

[16]  R. Tannenbaum,et al.  Cluster Coagulation and Growth Limited by Surface Interactions with Polymers , 2000, nlin/0003053.

[17]  Jinwoo Cheon,et al.  Surface modulation of magnetic nanocrystals in the development of highly efficient magnetic resonance probes for intracellular labeling. , 2005, Journal of the American Chemical Society.

[18]  Paul Mulvaney,et al.  Surface Plasmon Spectroscopy of Nanosized Metal Particles , 1996 .

[19]  K. Kneipp,et al.  Surface-enhanced Raman optical activity on adenine in silver colloidal solution. , 2006, Analytical chemistry.

[20]  L. A. Goldblatt,et al.  Chromatographie analysis of seed oils. Fatty acid composition of castor oil , 1962 .

[21]  Mathias Brust,et al.  Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system , 1994 .

[22]  L. Lewis Chemical catalysis by colloids and clusters , 1993 .