Analytical methods for the quantification of volatile aromatic compounds

Abstract The investigation of odorants is not an easy task, which needs to be undertaken in the context of fit-for-purpose quality systems. To date, great attention has been paid to determination of the volatile fractions of odorants, since they are responsible for the attributes of global flavor [i.e. a combination of olfactory (aroma) and gustatory (taste) sensations produced by chemicals]. This kind of determination can be carried out by analytical techniques [e.g., gas chromatography (GC) combined with mass spectrometry and/or olfactometric GC]. Methods complementary to GC analysis are available, allowing assessment of the olfactory impact by an electronic nose (e-nose) or a panel of selected individuals. Also, we consider some innovative analytical techniques to study the effects of odorants in food during consumption.

[1]  Chiara Cordero,et al.  Essential oils and volatiles: sample preparation and analysis. A review , 2010 .

[2]  Jonathan P. Williams,et al.  The use of recently described ionisation techniques for the rapid analysis of some common drugs and samples of biological origin. , 2006, Rapid communications in mass spectrometry : RCM.

[3]  F. Dusan,et al.  Essential oils--their antimicrobial activity against Escherichia coli and effect on intestinal cell viability. , 2006 .

[4]  Elisabeth Guichard,et al.  Relationships between molecular structure and perceived odor quality of ligands for a human olfactory receptor. , 2008, Chemical senses.

[5]  P. Zerbini,et al.  SHORT-TERM TRAINING AND ASSESSMENT FOR PERFORMANCE OF A SENSORY DESCRIPTIVE PANEL FOR THE OLFACTOMETRIC ANALYSIS OF AROMA EXTRACTS , 2009 .

[6]  B. Gullett,et al.  Use of REMPI–TOFMS for real-time measurement of trace aromatics during operation of aircraft ground equipment , 2008 .

[7]  R. R. Steiner,et al.  Validation of the Direct Analysis in Real Time Source for Use in Forensic Drug Screening , 2009, Journal of forensic sciences.

[8]  H. T. Nagle,et al.  Handbook of Machine Olfaction , 2002 .

[9]  Frank Heckel,et al.  Influence of technological processing on apple aroma analysed by high resolution gas chromatography–mass spectrometry and on-line gas chromatography-combustion/pyrolysis-isotope ratio mass spectrometry , 2006 .

[10]  Andrew M. Taylor,et al.  Food Flavour Technology , 2003 .

[11]  Alphus D. Wilson,et al.  Applications and Advances in Electronic-Nose Technologies , 2009, Sensors.

[12]  P. Vernocchi,et al.  Influence of starch addition and dough microstructure on fermentation aroma production by yeasts and lactobacilli , 2008 .

[13]  John R. Piggott,et al.  Dynamic methods of sensory analysis , 2000 .

[14]  T. Visser FT-IR detection in gas chromatography , 2002 .

[15]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[16]  Chiara Cordero,et al.  Development of fast enantioselective gas-chromatographic analysis using gas-chromatographic method-translation software in routine essential oil analysis (lavender essential oil). , 2010, Journal of chromatography. A.

[17]  J. Holopainen,et al.  Real-time monitoring of herbivore induced volatile emissions in the field. , 2010, Physiologia plantarum.

[18]  M. Adams,et al.  Eucalypt smoke and wildfires: Temperature dependent emissions of biogenic volatile organic compounds , 2009 .

[19]  Eric Jover,et al.  Twin comprehensive two-dimensional gas chromatographic system: concept and applications. , 2005, Journal of chromatography. A.

[20]  R. Fausto,et al.  Comparative matrix isolation infrared spectroscopy study of 1,3- and 1,4-diene monoterpenes (α-phellandrene and γ-terpinene). , 2011, The journal of physical chemistry. A.

[21]  T. Cajka,et al.  Challenging applications offered by direct analysis in real time (DART) in food-quality and safety analysis , 2011 .

[22]  C. Cordero,et al.  Identification, quantitation and method validation for the analysis of suspected allergens in fragrances by comprehensive two-dimensional gas chromatography coupled with quadrupole mass spectrometry and with flame ionization detection. , 2007, Journal of chromatography. A.

[23]  Jana Hajslova,et al.  Ambient mass spectrometry employing direct analysis in real time (DART) ion source for olive oil quality and authenticity assessment. , 2009, Analytica chimica acta.

[24]  Kenneth S Suslick,et al.  Colorimetric sensor arrays for volatile organic compounds. , 2006, Analytical chemistry.

[25]  R. R. Steiner,et al.  Detection of Gamma‐Hydroxybutyric Acid in Various Drink Matrices via AccuTOF‐DART * , 2009, Journal of forensic sciences.

[26]  C. Yeretzian,et al.  When machine tastes coffee: instrumental approach to predict the sensory profile of espresso coffee. , 2008, Analytical chemistry.

[27]  N. Noor,et al.  Analysis of the Chemical Composition of the Essential Oil of Polygonum minus Huds. Using Two-Dimensional Gas Chromatography-Time-of-Flight Mass Spectrometry (GC-TOF MS) , 2010, Molecules.

[28]  M. Adams,et al.  Temperature-dependent release of volatile organic compounds of eucalypts by direct analysis in real time (DART) mass spectrometry. , 2009, Rapid communications in mass spectrometry : RCM.

[29]  U. Brinkman,et al.  Recent developments in the application of comprehensive two-dimensional gas chromatography. , 2008, Journal of chromatography. A.

[30]  Andrew M. Taylor,et al.  Atmospheric pressure chemical ionisation mass spectrometry for in vivo analysis of volatile flavour release , 2000 .

[31]  I. Schellenberg,et al.  Comparison of different extraction methods for the determination of essential oils and related compounds from aromatic plants and optimization of solid-phase microextraction/gas chromatography , 2007, Analytical and bioanalytical chemistry.

[32]  H. Troy Nagle,et al.  Handbook of Machine Olfaction: Electronic Nose Technology , 2003 .

[33]  V Belgiorno,et al.  Instrumental characterization of odour: a combination of olfactory and analytical methods. , 2009, Water science and technology : a journal of the International Association on Water Pollution Research.

[34]  Andrew L. Lee,et al.  A Model of Peak Amplitude Enhancement in Orthogonal Two-Dimensional Gas Chromatography , 2001 .

[35]  K. P. Madhusudanan,et al.  Profiling of Piper betle Linn. cultivars by direct analysis in real time mass spectrometric technique. , 2010, Biomedical chromatography : BMC.

[36]  A. Voilley,et al.  Influence of the food matrix structure on the retention of aroma compounds. , 2000, Journal of agricultural and food chemistry.

[37]  A. Buettner,et al.  Characterization of an olfactometer by proton-transfer-reaction mass spectrometry , 2010 .

[38]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[39]  C. Cordero,et al.  Automated headspace solid-phase dynamic extraction to analyse the volatile fraction of food matrices. , 2004, Journal of chromatography. A.

[40]  F. Fernández,et al.  Optimization of a direct analysis in real time/time-of-flight mass spectrometry method for rapid serum metabolomic fingerprinting , 2010, Journal of the American Society for Mass Spectrometry.

[41]  C. Cordero,et al.  Conventional and narrow bore short capillary columns with cyclodextrin derivatives as chiral selectors to speed-up enantioselective gas chromatography and enantioselective gas chromatography-mass spectrometry analyses. , 2008, Journal of chromatography. A.

[42]  C. Turner Modern extraction techniques : food and agricultural samples , 2006 .

[43]  R. Linforth,et al.  Dynamic headspace analysis of the release of volatile organic compounds from ethanolic systems by direct APCI-MS. , 2005, Journal of agricultural and food chemistry.

[44]  R. Flocchini,et al.  The application of thermal desorption GC/MS with simultaneous olfactory evaluation for the characterization and quantification of odor compounds from a dairy. , 2002, Journal of agricultural and food chemistry.

[45]  Taste–Odor Integration in Espresso Coffee , 2008 .

[46]  G. Nicolini,et al.  Hyphenated gas chromatography-mass spectrometry analysis of 3-mercaptohexan-1-ol and 3-mercaptohexyl acetate in wine: Comparison with results of other sampling procedures via a robust regression. , 2008, Analytica chimica acta.

[47]  Y. H. Hui,et al.  Handbook of fruit and vegetable flavors , 2010 .

[48]  N. Bârsan,et al.  Electronic nose: current status and future trends. , 2008, Chemical reviews.

[49]  M. Bücking,et al.  Headspace GC and sensory analysis characterization of the influence of different milk additives on the flavor release of coffee beverages. , 2002, Journal of agricultural and food chemistry.

[50]  P. Marriott,et al.  Development of a switchable multidimensional/comprehensive two-dimensional gas chromatographic analytical system. , 2010, Journal of chromatography. A.

[51]  P. Marriott,et al.  Multiple component isolation in preparative multidimensional gas chromatography with characterisation by mass spectrometry and nuclear magnetic resonance spectroscopy. , 2009, Journal of chromatography. A.

[52]  Y. Goda,et al.  Identification of a cannabimimetic indole as a designer drug in a herbal product , 2009, Forensic Toxicology.

[53]  O. Haefliger,et al.  Direct mass spectrometric analysis of flavors and fragrances in real applications using DART. , 2007, Rapid communications in mass spectrometry : RCM.

[54]  C. Salles,et al.  In-Mouth Mechanisms Leading to Flavor Release and Perception , 2010, Critical reviews in food science and nutrition.

[55]  P. Marriott,et al.  New operational modes for multidimensional and comprehensive gas chromatography by using cryogenic modulation. , 2000, Journal of chromatography. A.

[56]  R. Linforth,et al.  Effects of Ethanol, Carbonation and Hop Acids on Volatile Delivery in a Model Beer System , 2011 .

[57]  K. Roos Effect of texture and microstructure on flavour retention and release , 2003 .

[58]  Tom Gerats,et al.  The plant genome: an evolutionary perspective on structure and function. , 2011, The Plant journal : for cell and molecular biology.

[59]  L. T. Scott,et al.  Routine analysis and characterization of highly insoluble polycyclic aromatic compounds by direct analysis in real time mass spectrometry (DART). , 2010, The Analyst.

[60]  T. Wampler Analysis of Food Volatiles Using Headspace- Gas Chromatographic Techniques , 2001 .

[61]  M. Santonico,et al.  Olfactory systems for medical applications , 2008 .

[62]  J. Pawliszyn,et al.  Determination of flavour profile in Iranian fragrant rice samples using cold-fibre SPME–GC–TOF–MS , 2007 .

[64]  Philip J Marriott,et al.  The combination of gas chromatography-olfactometry and multidimensional gas chromatography for the characterisation of essential oils. , 2007, Journal of chromatography. A.

[65]  Leonard Steinborn,et al.  International Organization for Standardization ISO/IEC 17025 General Requirements for the Competence of Testing and Calibration Laboratories , 2004 .

[66]  C. Cordero,et al.  Comprehensive two-dimensional gas chromatography in the analysis of volatile samples of natural origin: a multidisciplinary approach to evaluate the influence of second dimension column coated with mixed stationary phases on system orthogonality. , 2006, Journal of chromatography. A.

[67]  Glen P. Jackson,et al.  Isotope Ratio Mass Spectrometry. , 2009, The Analyst.

[68]  J. Piggott Dynamism in flavour science and sensory methodology , 2000 .

[69]  David R Walt,et al.  Extending the longevity of fluorescence-based sensor arrays using adaptive exposure. , 2005, Analytical chemistry.

[70]  Yasuyuki Sagara,et al.  Analysis of Freshly Brewed Espresso Using a Retronasal Aroma Simulator and Influence of Milk Addition , 2009 .

[71]  Janusz Pawliszyn,et al.  Solid phase microextraction : theory and practice , 1997 .

[72]  Liang Feng,et al.  Discrimination of complex mixtures by a colorimetric sensor array: coffee aromas. , 2010, Analytical chemistry.

[73]  P. Marriott,et al.  Emerging opportunities for flavor analysis through hyphenated gas chromatography. , 2009, Journal of agricultural and food chemistry.

[74]  D. Walt,et al.  Optical fiber-based biosensors , 2004, Analytical and bioanalytical chemistry.

[75]  R. Negri,et al.  Electronic nose based discrimination of a perfumery compound in a fragrance , 2003 .

[76]  F. Begnaud,et al.  Multidimensional gas chromatography using a double cool-strand interface. , 2005, Journal of chromatography. A.