Past and Present of Sol-Gel Science and Technology

In the last twenty years sol-gel science has undergone a spectacular development. The various stages of the sol-gel process have been scrutinised in considerable detail and a sound basis for future technological developments established. In the beginning the studies centred mainly on silica and silicate glasses and were progressively extended to many ceramics and composites. A turning point was reached with the emergence of ormosils and of organic-inorganic nanocomposites. This opened the gateway to whole classes of new materials. The present studies show a definite tendency towards very specialised high-tech applications.

[1]  Lisa C. Klein,et al.  Sol-Gel Optics , 1994 .

[2]  G. Nicolaon,et al.  Inorganic oxide aerogels , 1976 .

[3]  J. Mackenzie Nonlinear optical materials by the sol-gel method , 1993 .

[4]  S. Sakka The current state of sol-gel technology , 1994 .

[5]  J. Traverse,et al.  A comparative study of “gels” and oxide mixtures as starting materials for the nucleation and crystallization of silicate glasses , 1976 .

[6]  L. Hench,et al.  The sol-gel process , 1990 .

[7]  Yuji Yamamoto,et al.  Formation of sheets and coating films from alkoxide solutions , 1984 .

[8]  R. Roy Aids in Hydrothermal Experimentation: II, Methods of Making Mixtures for Both “Dry” and “Wet” Phase Equilibrium Studies , 1956 .

[9]  T. Minami,et al.  Fine-patterning on glass substrates by the sol-gel method , 1988 .

[10]  J. Phalippou,et al.  Synthesis of glasses from gels: the problem of monolithic gels , 1982 .

[11]  R. Roy,et al.  An experimental study of the formation and properties of synthetic serpentines and related layer silicate minerals , 1954 .

[12]  C. Brinker Sol-gel science , 1990 .

[13]  D. Partlow,et al.  Wide spectrum antireflective coating for fused silica and other glasses. , 1984, Applied optics.

[14]  H. Dislich New Routes to Multicomponent Oxide Glasses , 1971 .

[15]  D. Uhlmann,et al.  Ultrastructure processing of ceramics, glasses, and composites , 1992 .

[16]  J. Mackenzie Structures and properties of Ormosils , 1994 .

[17]  S. Kistler,et al.  Coherent Expanded Aerogels and Jellies. , 1931, Nature.

[18]  J. Zarzycki Fractal properties of gels , 1987 .