Dispersion characteristics of various contents of nano‐TiO2 and its effect on the properties of cement‐based composite

Effect of nano‐TiO2 on the compressive strength and permeability of cement paste was studied, and the mechanism was revealed through investigating the hydration evolution and hydration products distribution of cement containing various contents of nano‐TiO2. Hydration Heat of cement, microstructure and pore structure of cement paste indicated that nano‐TiO2 could act as “nuclear” to accelerate the cement hydration, and this acceleration effect strengthened upon the nano‐TiO2 content at early age while reversed at long age. Distribution uniformity of nano‐TiO2 and hydration products was characterized and quantitative evaluated based on the method of energy dispersive X‐ray spectroscopy, which showed that the dispersion of nano‐TiO2 and hydration products had a high relativity, and the most uniform distribution was achieved at a small content of nano‐TiO2. The main effect of nano‐TiO2 on the properties of cement paste at early age and long age was the accelerated hydration and the improved distribution uniformity, respectively.

[1]  L. Nilsson,et al.  Chloride diffusivity in high strength concrete at different ages , 1992 .

[2]  Anne B. Abell,et al.  Mercury Intrusion Porosimetry and Image Analysis of Cement-Based Materials. , 1999, Journal of colloid and interface science.

[3]  I. Richardson The nature of C-S-H in hardened cements , 1999 .

[4]  Pierre-Claude Aitcin,et al.  Cements of yesterday and today Concrete of tomorrow , 2000 .

[5]  Kiyofumi Kurumisawa,et al.  Development of technique for observing pores in hardened cement paste , 2002 .

[6]  J. Ou,et al.  Microstructure of cement mortar with nano-particles , 2004 .

[7]  J. Ou,et al.  Abrasion resistance of concrete containing nano-particles for pavement , 2006 .

[8]  Y. Qing,et al.  Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume , 2007 .

[9]  J. Ou,et al.  Flexural fatigue performance of concrete containing nano-particles for pavement , 2007 .

[10]  Sun Wei,et al.  Preparation of C200 green reactive powder concrete and its static–dynamic behaviors , 2008 .

[11]  M. Konsta-Gdoutos,et al.  Exploration of fracture characteristics , nanoscale properties and nanostructure of cementitious matrices with carbon nanotubes and carbon nanofibers , 2010 .

[12]  F. Pacheco-Torgal,et al.  Nanotechnology: Advantages and drawbacks in the field of construction and building materials , 2011 .

[13]  A. Nazari,et al.  Abrasion resistance of concrete containing SiO 2 and Al 2O 3 nanoparticles in different curing media , 2011 .

[14]  Hui Li,et al.  Pore structure and chloride permeability of concrete containing nano-particles for pavement , 2011 .

[15]  J. Provis,et al.  Structure of Portland Cement Pastes Blended with Sonicated Silica Fume , 2012 .

[16]  Xianming Shi,et al.  Transport Properties of Carbon-Nanotube/Cement Composites , 2012, Journal of Materials Engineering and Performance.

[17]  L. Singh,et al.  Beneficial role of nanosilica in cement based materials – A review , 2013 .

[18]  Surendra P. Shah,et al.  Modification of cement-based materials with nanoparticles , 2013 .

[19]  Hui Li,et al.  Chloride diffusion in concrete containing nano-TiO2 under coupled effect of scouring , 2014 .

[20]  Hongjian Du,et al.  Durability performances of concrete with nano-silica , 2014 .

[21]  Hongjian Du,et al.  Effect of nano-silica on the mechanical and transport properties of lightweight concrete , 2015 .

[22]  Hongjian Du,et al.  Enhancement of barrier properties of cement mortar with graphene nanoplatelet , 2015 .

[23]  Hui Li,et al.  Crystallization of calcium silicate hydrates on the surface of nanomaterials , 2017 .

[24]  A. Inozemtcev,et al.  Nanoscale modifier as an adhesive for hollow microspheres to increase the strength of high‐strength lightweight concrete , 2017 .

[25]  F. Ali,et al.  Structural performance of ultra‐high‐performance fiber‐reinforced concrete beams , 2017 .

[26]  Hui Li,et al.  Effects of nano-SiO2 on the permeability-related properties of cement-based composites with different water/cement ratios , 2018, Journal of Materials Science.

[27]  Yunsheng Zhang,et al.  Modelling of diffusion behavior of ions in low-density and high-density calcium silicate hydrate , 2017 .

[28]  Faiz Shaikh,et al.  Effect of mixing methods of nano silica on properties of recycled aggregate concrete , 2018 .

[29]  Faiz Shaikh,et al.  Effects of fly ash fineness, nano silica, and curing types on mechanical and durability properties of fly ash mortars , 2018 .

[30]  Min Liu,et al.  Anisotropic electrical and abrasion-sensing properties of cement-based composites containing aligned nickel powder , 2018 .

[31]  Hui Li,et al.  Improved interfacial strength of SiO2 coated carbon fiber in cement matrix , 2018, Cement and Concrete Composites.