Dispersion of Velocity and Anomalous Absorption of Ultrasonics in Nitrogen

By means of the interferometer, the velocity and absorption of ultrasonic waves in nitrogen were measured at the frequency of 2.992 mc/sec, in the pressure range of 2.09 to 76 cm of Hg at a temperature of 29°C. A dispersion of velocity was found ranging from 354.3 meters/sec to 364.4 meters/sec. The ratio αexp/αclass dropped from 1.40 to 1.32, and the corresponding value of Cv/R dropped from 2.50 to 2.08.Theoretical values for the change in velocity and in the absorption ratio, calculated by applying the equations for the exchange of energy between translational and vibrational degrees of freedom, show good agreement with the observed values. The increase in velocity and the decrease in αexp/αclass is interpreted as due to the slow exchange of energy between the translational and rotational degrees of freedom. The relaxation time for rotation was found to be 1.2×10−9 second.