Compared with traditional radio frequency identification (RFID), computational RFID (CRFID) tag has more powerful computing capability, but it shows poor performance when it follows EPC Class-1 Generation-2 protocol especially transmitting large amounts of data. In fact, the operation of the CRFID tag entirely depends on the state of energy. For this point, this study proposes an optimised protocol called LILAC. LILAC allows tags to select the communication time slot according to their current voltage value measured by using an analogue-to-digital converter rather than randomly selecting, the authors proposed a more reasonable time slot mapping algorithm for LILAC that increases the success rate of tag responding. In addition, they design a data transmission format that can be retransmitted to improve the uplink throughput. Finally, they implemented LILAC on a CRFID platform and practically measured several parameters to compare with the existing well-known protocol. The results of experiments show that LILAC increases the maximum communication distance by more than half in the access phase and doubles the goodput of the backscatter link in both the inventory and access phase.