Spatiotemporal Characteristics and Health Risk Assessment of Heavy Metals in PM2.5 in Zhejiang Province

The spatiotemporal characteristics and human health risks of 12 heavy metals (Al, As, Be, Cd, Cr, Hg, Mn, Ni, Pb, Sb, Se, and Tl) in fine particulate matter (PM2.5) in Zhejiang Province were investigated. The annual average PM2.5 concentration was 58.83 µg/m3 in 2015 in Zhejiang. Element contents in PM2.5 varied greatly with the season and locations. Al, Pb, and Mn were the most abundant elements among the studied metal(loid)s in PM2.5. The non-carcinogenic risks of the 12 elements through inhalation and dermal contact exposure were lower than the safe level for children and adults. However, there were potential non-carcinogenic risks of Tl, As, and Sb for children and Tl for adults through ingestion exposure. The carcinogenic risks from As, Be, Cd, Cr, Pb, and Ni through inhalation exposure were less than the acceptable level (1 × 10−4) for children and adults. Pb may carry a potential carcinogenic risk for both children and adults through ingestion. More attention should be paid to alleviate non-carcinogenic and carcinogenic health risks posed by particle-bound toxic elements through ingestion exposure.

[1]  S. Gupta,et al.  Human health risk analysis from disinfection by-products (DBPs) in drinking and bathing water of some Indian cities , 2014, Journal of Environmental Health Science and Engineering.

[2]  Han-qing Kang,et al.  Analysis of a long-lasting haze episode in Nanjing, China , 2013 .

[3]  Ruiqin Zhang,et al.  PM2.5 in an industrial district of Zhengzhou, China: Chemical composition and source apportionment , 2013 .

[4]  M. Shao,et al.  Fractionation of airborne particulate-bound elements in haze-fog episode and associated health risks in a megacity of southeast China. , 2016, Environmental pollution.

[5]  A. Cohen,et al.  Exposure assessment for estimation of the global burden of disease attributable to outdoor air pollution. , 2012, Environmental science & technology.

[6]  Katarzyna Juda-Rezler,et al.  Determination and analysis of PM10 source apportionment during episodes of air pollution in Central Eastern European urban areas: The case of wintertime 2006 , 2011 .

[7]  Jichun Wu,et al.  Fractionation and health risks of atmospheric particle-bound As and heavy metals in summer and winter. , 2014, The Science of the total environment.

[8]  Tiantian Li,et al.  The relationship between airborne fine particle matter and emergency ambulance dispatches in a southwestern city in Chengdu, China. , 2017, Environmental pollution.

[9]  James S. Brown,et al.  Particulate Matter–Induced Health Effects: Who Is Susceptible? , 2010, Environmental health perspectives.

[10]  Yinchang Feng,et al.  Assessment of heavy metal pollution characteristics and human health risk of exposure to ambient PM2.5 in Tianjin, China , 2015 .

[11]  R. Esworthy Air Quality: EPA's 2013 Changes to the Particulate Matter (PM) Standard , 2013 .

[12]  G. Glonek,et al.  The effects of air pollution on asthma hospital admissions in Adelaide, South Australia, 2003–2013: time‐series and case–crossover analyses , 2016, Clinical and experimental allergy : journal of the British Society for Allergy and Clinical Immunology.

[13]  Thomas F Bateson,et al.  Children's Response to Air Pollutants , 2007, Journal of toxicology and environmental health. Part A.

[14]  Jun Wang,et al.  Contamination characteristics and possible sources of PM10 and PM2.5 in different functional areas of Shanghai, China , 2013 .

[15]  J. Chow,et al.  Spatial distribution of PM2.5 associated organic compounds in central California , 2006 .

[16]  A. Bari,et al.  Regional sources of particulate sulfate, SO2, PM2.5, HCl, and HNO3, in New York, NY , 2003 .

[17]  H. Takano,et al.  Particulate Matter–Induced Health Effects: Who Is Susceptible? , 2011, Environmental health perspectives.

[18]  Jiang Yuan,et al.  Risk Assessment of Information System , 2011 .

[19]  B. Srimuruganandam,et al.  Source characterization of PM10 and PM2.5 mass using a chemical mass balance model at urban roadside. , 2012, The Science of the total environment.

[20]  Jiming Hao,et al.  Long-term trend of haze pollution and impact of particulate matter in the Yangtze River Delta, China. , 2013, Environmental pollution.

[21]  Deng Xia-ju Air Quality in Zhejiang Province and the Impact of Main Meteorological Elements , 2014 .

[22]  Lingqing Wang,et al.  Risk assessment of atmospheric heavy metals exposure in Baotou, a typical industrial city in northern China , 2016, Environmental Geochemistry and Health.

[23]  Ki-Hyun Kim,et al.  A review on the human health impact of airborne particulate matter. , 2015, Environment international.

[24]  Prashant Kumar,et al.  Air pollution and public health: the challenges for Delhi, India , 2017, Reviews on environmental health.

[25]  J. Brook,et al.  Associations between personal exposures and fixed-site ambient measurements of fine particulate matter, nitrogen dioxide, and carbon monoxide in Toronto, Canada , 2006, Journal of Exposure Science and Environmental Epidemiology.

[26]  Renjian Zhang,et al.  Chemical composition of PM2.5 in an urban environment in Chengdu, China:Importance of springtime dust storms and biomass burning , 2013 .

[27]  X. Qing,et al.  Assessment of heavy metal pollution and human health risk in urban soils of steel industrial city (Anshan), Liaoning, Northeast China. , 2015, Ecotoxicology and environmental safety.

[28]  Ajay Taneja,et al.  Metal concentration of PM(2.5) and PM(10) particles and seasonal variations in urban and rural environment of Agra, India. , 2009, The Science of the total environment.

[29]  Sheng-mao Hong,et al.  Variation of PM2.5 concentration in Hangzhou, China , 2013 .

[30]  Y. Q. Wang,et al.  Atmospheric aerosol compositions in China: Spatial/temporal variability, chemical signature, regional haze distribution and comparisons with global aerosols , 2011 .

[31]  Jichun Wu,et al.  Bioaccessibility and health risk of arsenic and heavy metals (Cd, Co, Cr, Cu, Ni, Pb, Zn and Mn) in TSP and PM2.5 in Nanjing, China , 2012 .

[32]  Yufen Zhang,et al.  Estimation of the Main Factors Influencing Haze, Based on a Long-term Monitoring Campaign in Hangzhou, China , 2011 .

[33]  L. Folinsbee Human health effects of air pollution. , 1993, Environmental health perspectives.