Hot off the Press.

A personal selection of 32 recent papers is presented covering various aspects of current developments in bioorganic chemistry and novel natural products such as chevalinulin A from Aspergillus chevalieri.

[1]  Lan Liu,et al.  Elucidation of the Complete Biosynthetic Pathway of Phomoxanthone A and Identification of a Para-Para Selective Phenol Coupling Dimerase. , 2022, Organic letters.

[2]  M. Nett,et al.  Discovery, Biosynthetic Origin, and Heterologous Production of Massinidine, an Antiplasmodial Alkaloid. , 2022, Organic letters.

[3]  Xiao‐Ming Li,et al.  Chevalinulins A and B, Proangiogenic Alkaloids with a Spiro[bicyclo[2.2.2]octane-diketopiperazine] Skeleton from Deep-Sea Cold-Seep-Derived Fungus Aspergillus chevalieri CS-122. , 2022, Organic letters.

[4]  P. Duan,et al.  Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids , 2022, ACS catalysis.

[5]  Dan Zhu,et al.  Lycophlegmarinines A–F, new Lycopodium alkaloids from Phlegmariurus phlegmaria , 2022, Tetrahedron.

[6]  I. Abe,et al.  A Multifunctional Cytochrome P450 and a Meroterpenoid Cyclase in the Biosynthesis of Fungal Meroterpenoid Atlantinone B. , 2022, Organic letters.

[7]  H. Hailes,et al.  Stereoselective Transaminase‐Mediated Synthesis of Serotonin and Melatonin Receptor Agonists , 2022, Advanced Synthesis & Catalysis.

[8]  Xiaochi Ma,et al.  Cytotoxic diterpenoid dimer containing an intricately caged core from Euphorbia fischeriana. , 2022, Bioorganic chemistry.

[9]  E. Parker,et al.  Aminoacylation of Indole Diterpenes by Cluster-Specific Monomodular NRPS-like Enzymes. , 2022, Organic letters.

[10]  Shinji Kishimoto,et al.  Alkaloid Biosynthetic Enzyme Generates Diastereomeric Pair via Two Distinct Mechanisms. , 2022, Journal of the American Chemical Society.

[11]  M. Nishiyama,et al.  Cryptic Oxidative Transamination of Hydroxynaphthoquinone in Natural Product Biosynthesis. , 2022, Journal of the American Chemical Society.

[12]  A. Luzhetskyy,et al.  Novel Biosynthetic Route to the Isoquinoline Scaffold. , 2022, ACS chemical biology.

[13]  Yuzhu Tan,et al.  Phaseollin A, a novel pterocarpan with a unique 6/7/5/6/6 skeleton from Phaseolus lunatus L. , 2022, Tetrahedron Letters.

[14]  L. Gan,et al.  (±)-Heterocageflavone, anti-inflammatory isoprenylated flavonoids with a tricyclo[5.3.1.03,8]undecane moiety from Artocarpus heterophyllus. , 2022, Bioorganic chemistry.

[15]  N. Jiao,et al.  Characterization of a Cryptic NRPS Gene Cluster in Bacillus velezensis FZB42 Reveals a Discrete Oxidase Involved in Multithiazole Biosynthesis , 2022, ACS Catalysis.

[16]  H. Kuang,et al.  Anti‐proliferative properties of Schinensilactone A, A Schnortriterpenoid with 7,8‐seco‐1,8‐cyclo Scaffold against Caco‐2 by inducing cell apoptosis from the Leaves of Schisandra chinensis , 2022, Chinese Journal of Chemistry.

[17]  T. Wen,et al.  An Unprecedented Tetracyclic Diterpenoid with Anti-inflammatory Activity from Papiliomyces sp , 2022, Tetrahedron Letters.

[18]  F. Arnold,et al.  Biocatalytic One-Carbon Ring Expansion of Aziridines to Azetidines via a Highly Enantioselective [1,2]-Stevens Rearrangement. , 2021, Journal of the American Chemical Society.

[19]  Xuan Zhang,et al.  Alternatones A and B, two polyketides possessing novel skeletons from entophyte Alternaria alternate L-10 , 2021, Journal of Asian natural products research.

[20]  Fan-dong Kong,et al.  A new picrotoxane-type sesquiterpene from Dendrobium nobile Lindl , 2020, Natural product research.

[21]  Ting Yan,et al.  A novel alkaloid from the seeds of Sophora alopecuroides L , 2012, Natural product research.