论文信息 - Synthesis of 5-[(E)-1-Alkenyl]-3(2H)-furanones by the Stereoselective Dehydration with Me3SiCl - 字舞流文

Synthesis of 5-[(E)-1-Alkenyl]-3(2H)-furanones by the Stereoselective Dehydration with Me3SiCl

The stereoselective dehydration of 5-(2-hydroxyalkyl)-3(2H)-furanones is accomplished conveniently by the treatment with Me3SiCl in acetonitrile to give 5-[(E)-1-alkenyl]-3(2H)-furanones.

M. Utaka | T. Sakai | S. Tsuboi | A. Takeda | K. Kohda

[1] K. Kawazu,et al. Stereoselective Synthesis of Octadecapolyenoic Esters as an Insecticide , 1987 .

[2] B. Byrne,et al. The stereoselective synthesis of ethyl 2(E),4(Z)-decadienoate , 1986 .

[3] Hiroshi Ito,et al. A convenient synthesis of geiparvarin , 1984 .

[4] M. Utaka,et al. New synthesis of .alpha.-benzoyloxy aldehydes. Application to the stereoselective synthesis of conjugated (E,E)-dienoic esters , 1982 .

[5] Amos B. Smith,et al. Synthesis and configurational assignment of geiparvarin: a novel antitumor agent , 1981 .

[6] M. Jung,et al. Direct synthesis of dibenzocyclooctadienes via double ortho Friedel-Crafts alkylation by the use of aldehyde-trimethylsilyl iodide adducts , 1978 .

[7] P. C. Huang,et al. Letter: Eremantholide a, a novel tumor-inhibiting compound from Eremanthus elaeagnus Schultz-Bip. (Compositae). , 2002, Journal of the American Chemical Society.

[8] F. Lahey,et al. The coumarins of Geijera parviflora Lindl , 1967 .