On the determination of axial dispersion coefficient in a batch oscillatory baffled column using laser induced fluorescence

Abstract We report a novel method of obtaining tracer concentration profiles and determining the axial dispersion coefficient in a batch oscillatory baffled column (OBC) utilising the laser induced fluorescence (LIF) technique. In LIF, a dye fluoresces when it is induced by a laser. By receiving the wavelength of the light emitted by the dye, the intensity of the dye can be converted into the concentration. This technique is non-intrusive and has a number of unique advantages in comparison with the traditional tracer method. One of such advantages is that it can be used to investigate the concentration profiles in different areas of the cell axially and radially, which has led to, for the first time, the quantitative determination of the radial dispersion in the OBC. In short, LIF is a viable and powerful tool in quantifying mixing and dispersion in both the OBC and other reactor systems.

[1]  Xiongwei Ni,et al.  On the discussion of the dimensionless groups governing oscillatory flow in a baffled tube , 1997 .

[2]  G. Jeffreys The theory of backmixing : By J. C. Mecklenburgh and S. Hartland; published by Wiley, London, 1975; 506 pp.; price £20. , 1977 .

[3]  R. Aris On the dispersion of a solute in a fluid flowing through a tube , 1956, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[4]  Malcolm R. Mackley,et al.  Mixing and dispersion in a baffled tube for steady laminar and pulsatile flow , 1991 .

[5]  Malcolm R. Mackley,et al.  Experimental fluid dispersion measurements in periodic baffled tube arrays , 1993 .

[6]  J. S. Vrentas,et al.  Dispersion in laminar tube flow at low Peclet numbers or short times , 1988 .

[7]  Edward L Cussler,et al.  Diffusion: Mass Transfer in Fluid Systems , 1984 .

[8]  Tony Howes,et al.  On the effect of tracer density on axial dispersion in a batch oscillatory baffled column , 2002 .

[9]  Malcolm R. Mackley,et al.  Experimental residence time distribution measurements for unsteady flow in baffled tubes , 1989 .

[10]  Malcolm R. Mackley,et al.  Experimental observations on flow patterns and energy losses for oscillatory flow in ducts containing sharp edges , 1989 .

[11]  W. Gill A note on the solution of transient dispersion problems , 1967, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[12]  Octave Levenspiel,et al.  Notes on the diffusion-type model for the longitudinal mixing of fluids in flow , 1995 .