STRUCTURAL AND ELECTRICAL STUDIES OF SOME FIRST ROW COMPLEXES OF PYRAZINAMIDE

Abstract Complexes of pyrazinamide with the cobalt(II) chloride and bromide, nickel(II) thiocyanate and bromide and copper(II) chloride and bromide are described. Magnetic measurements and electronic and infrared spectroscopy have been used to intestigate the stereochemistry of the complexes. Electrical measurements have shown the existence of two types of conduction in the compounds-ohmic and space charge effects with carrier trapping.

[1]  E. Maslowsky Vibrational Spectra of Organometallic Compounds , 2018, Focus on Catalysts.

[2]  J. R. Allan,et al.  Some first row transition metal complexes of nicotinamide and nicotinic acid , 1979 .

[3]  J. R. Allan,et al.  Complexes of the ethylpyridines with the halides of cobalt(II), nickel(II) and copper(II) , 1978 .

[4]  道行 植之原,et al.  S.M. Sze: Physics of Semiconductor Devices, Wiley-Interscience,New York, 1969, 812頁, 16.5×23.5cm, 7,980円. , 1970 .

[5]  R. Paul,et al.  Structure of donor-acceptor complexes—IX coordination compounds of imides with metal halides , 1969 .

[6]  F. Cotton,et al.  Assignment of the electronic absorption spectra of bis(.beta.-ketoenolate) complexes of copper(II) and nickel(II) , 1967 .

[7]  F. Cotton,et al.  The Electronic Structures of Bis(β-ketoenolato)copper(II) Complexes , 1966 .

[8]  W. Hatfield,et al.  Spectral and Magnetic Properties of Chlorocuprates , 1964 .

[9]  F. Cotton,et al.  Electronic Spectra of β-Diketone Complexes. III. α-Substituted β-Diketone Complexes of Copper(II) , 1963 .

[10]  T. S. Piper,et al.  Crystal Spectrum of Cs2CuBr4 , 1962 .

[11]  R. Rivest,et al.  CO-ORDINATION COMPLEXES OF TITANIUM (IV) HALIDES: 1. PREPARATION AND INFRARED SPECTRA OF THE COMPLEXES OF TITANIUM (IV) HALIDES WITH N,N-DIMETHYL AND N,N-DIPHENYL FORMAMIDE , 1960 .

[12]  R. Rivest,et al.  DONOR ACCEPTOR REACTIONS OF TITANIUM TETRACHLORIDE WITH FORMAMIDE AND N,N-DIMETHYL FORMAMIDE , 1958 .

[13]  M. Lampert Simplified Theory of One‐Carrier Currents with Field‐Dependent Mobilities , 1958 .

[14]  M. Lampert,et al.  Simplified Theory of Space-Charge-Limited Currents in an Insulator with Traps , 1956 .

[15]  Albert Rose,et al.  Space-Charge-Limited Currents in Solids , 1955 .

[16]  M. Goldstein,et al.  The far-infrared spectra (450 – 80 cm−1) of octahedral halogen-bridged transition metal(II) complexes , 1970 .

[17]  W. Geary,et al.  Transition-metal complexes of the 1,2-dipyridylethylene isomers. Part IV. Far-infrared spectra (450–80 cm.–1) of cobalt(II), nickel(II), and copper(II) halide derivatives , 1969 .

[18]  S. M. Sze,et al.  Physics of semiconductor devices , 1969 .

[19]  Stuart A. Rice,et al.  Inorganic Electronic Spectroscopy , 1968 .

[20]  R. Gurney,et al.  Electronic Processes in Ionic Crystals , 1964 .

[21]  R. Muller A unified approach to the theory of space-charge-limited currents in an insulator with traps , 1963 .

[22]  H. Flood,et al.  Binuclear Complexes. I. The Electronic Structure of Copper Acetate. , 1962 .

[23]  K. W. Bagnall,et al.  314. Some acetamide complexes of the actinide tetrachlorides. Part I. Uranium, neptunium, and plutonium , 1961 .

[24]  W. Gerrard,et al.  433. Spectra and structure of amide complexes , 1960 .