A review on novel processes of biodiesel production from waste cooking oil

Fossil fuel depletion, environmental concerns, and steep hikes in the price of fossil fuels are driving scientists to search for alternative fuels. The characteristics of biodiesel have made the pursuit of high quality biodiesel production attractive. Utilization of waste cooking oil is a key component in reducing biodiesel production costs up to 60–90%. Researchers have used various types of homogeneous and heterogeneous catalyzed transesterification reaction for biodiesel production. Meanwhile, the effect of novel processes such as membrane reactor, reactive distillation column, reactive absorption, ultrasonic and microwave irradiation significantly influenced the final conversion, yield and in particular, the quality of product. This article attempts to cover all possible techniques in production of biodiesel from waste cooking oil.

[1]  K. Chua,et al.  PRODUCTION OF ETHYL ESTER (BIODIESEL) FROM USED FRYING OIL: OPTIMIZATION OF TRANSESTERIFICATION PROCESS USING MICROWAVE IRRADIATION , 2004 .

[2]  Pedro Felizardo,et al.  Production of biodiesel from waste frying oils. , 2006, Waste management.

[3]  A. Kondo,et al.  Whole cell biocatalyst for biodiesel fuel production utilizing Rhizopus oryzae cells immobilized within biomass support particles. , 2001, Biochemical engineering journal.

[4]  Z. Xiu,et al.  Calcined sodium silicate as solid base catalyst for biodiesel production , 2010 .

[5]  Li Tian,et al.  Ultrasonic irradiation with vibration for biodiesel production from soybean oil by Novozym 435. , 2010 .

[6]  L. C. Meher,et al.  Biodiesel Productions from Vegetable Oils Using Heterogeneous Catalysts and Their Applications as Lubricity Additives , 2006, 2006 IEEE EIC Climate Change Conference.

[7]  G. Marin,et al.  Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production , 2006 .

[8]  Don W. Green,et al.  Perry's chemical engineers' handbook. 7th ed. , 1997 .

[9]  In-Beum Lee,et al.  Limitations and Countermeasures of PID Controllers , 1996 .

[10]  Richard A. Venditti,et al.  Biodiesel synthesis via homogeneous Lewis acid-catalyzed transesterification , 2009 .

[11]  L. Bournay,et al.  New heterogeneous process for biodiesel production : A way to improve the quality and the value of the crude glycerin produced by biodiesel plants , 2005 .

[12]  G. Dönmez,et al.  Microbial oil production from thermophile cyanobacteria for biodiesel production , 2011 .

[13]  G. Yadav,et al.  Sulfated zirconia and its modified versions as promising catalysts for industrial processes , 1999 .

[14]  D. Clements,et al.  Biodiesel Production Technology: August 2002--January 2004 , 2004 .

[15]  J. Encinar,et al.  Biodiesel from Used Frying Oil. Variables Affecting the Yields and Characteristics of the Biodiesel , 2005 .

[16]  Farid Nasir Ani,et al.  A review on microwave-assisted production of biodiesel , 2012 .

[17]  M. Allawzi,et al.  Parametric study of biodiesel production from used soybean oil , 2008 .

[18]  Pen-Chi Chiang,et al.  Ozonation of CI Reactive Black 5 Using Rotating Packed Bed and Stirred Tank Reactor , 2005 .

[19]  Rushang M. Joshi,et al.  FLOW PROPERTIES OF BIODIESEL FUEL BLENDS AT LOW TEMPERATURES , 2007 .

[20]  H. Civelekoǧlu,et al.  Deacidification of sulfur olive oil. I. Single-stage liquid-liquid extraction of miscella with ethyl alcohol , 1991 .

[21]  Benjamin A. Wilhite,et al.  CONTINUOUS-FLOW PREPARATION OF BIODIESEL USING MICROWAVE HEATING , 2007 .

[22]  Xiqing Wang,et al.  Sulfonated ordered mesoporous carbon for catalytic preparation of biodiesel , 2008 .

[23]  Shuli Yan,et al.  Advancements in Heterogeneous Catalysis for Biodiesel Synthesis , 2010 .

[24]  A. A. Refaat,et al.  Different techniques for the production of biodiesel from waste vegetable oil , 2010 .

[25]  A. Phan,et al.  Biodiesel production from waste cooking oils , 2008 .

[26]  Shuli Yan,et al.  Simultaneous transesterification and esterification of unrefined or waste oils over ZnO-La2O3 catalysts , 2009 .

[27]  Chia-Chang Lin,et al.  Volatile organic compounds absorption in a cross-flow rotating packed bed. , 2008, Environmental science & technology.

[28]  Yc Leung,et al.  A clean biodiesel fuel produced from recycled oils and grease trap oils , 2002 .

[29]  M. Dubé,et al.  Biodiesel production using a membrane reactor. , 2007, Bioresource technology.

[30]  Ivan V. Kozhevnikov,et al.  Heteropoly acids as catalysts for liquid-phase esterification and transesterification , 2008 .

[31]  Solvent-Free Esterification of Oleic Acid and Oleyl Alcohol Using Membrane Reactor and Lipase-Surfactant Complex , 1998 .

[32]  S. Al‐Zuhair,et al.  Adsorption of Lipase on Hollow Fiber Membrane Chips , 2005, Artificial cells, blood substitutes, and immobilization biotechnology.

[33]  Satoshi Furuta,et al.  Biodiesel fuel production with solid amorphous-zirconia catalysis in fixed bed reactor. , 2006 .

[34]  Dennis Y.C. Leung,et al.  Optimization of biodiesel production from camelina oil using orthogonal experiment , 2011 .

[35]  Yong Wang,et al.  COMPARISON OF TWO DIFFERENT PROCESSES TO SYNTHESIZE BIODIESEL BY WASTE COOKING OIL , 2006 .

[36]  Kang-Shin Chen,et al.  Improving biodiesel yields from waste cooking oil by using sodium methoxide and a microwave heating system , 2012 .

[37]  B. Shanks,et al.  Conversion of oils and fats using advanced mesoporous heterogeneous catalysts , 2006 .

[38]  K. Murugesan,et al.  Performance optimization of Jatropha biodiesel engine model using Taguchi approach , 2009 .

[39]  Ki-Teak Lee,et al.  Production of alkyl ester as biodiesel from fractionated lard and restaurant grease , 2002 .

[40]  L. Canoira,et al.  Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow , 2000 .

[41]  D. C. Deka,et al.  High quality biodiesel from yellow oleander (Thevetia peruviana) seed oil. , 2011 .

[42]  J. V. Gerpen,et al.  BIODIESEL PRODUCTION FROM OILS AND FATS WITH HIGH FREE FATTY ACIDS , 2001 .

[43]  Costin Sorin Bildea,et al.  Innovative process for fatty acid esters by dual reactive distillation , 2009, Comput. Chem. Eng..

[44]  Ayhan Demirbas,et al.  Political, economic and environmental impacts of biofuels: A review , 2009 .

[45]  A. Pierre,et al.  Application of silica aerogel encapsulated lipases in the synthesis of biodiesel by transesterification reactions , 2006 .

[46]  Naoko Ellis,et al.  Biochar based solid acid catalyst for biodiesel production , 2010 .

[47]  J. Sinisterra,et al.  Application of ultrasound to biotechnology: an overview. , 1992, Ultrasonics.

[48]  A. Rodrigues,et al.  Continuous enzymatic production of biodiesel from virgin and waste sunflower oil in supercritical carbon dioxide , 2011 .

[49]  Hideo Noda,et al.  Conversion of vegetable oil to biodiesel using immobilized Candida antarctica lipase , 1999 .

[50]  Jianli Wang,et al.  Preparation of biodiesel with the help of ultrasonic and hydrodynamic cavitation. , 2006, Ultrasonics.

[51]  A. F. Errazu,et al.  Techno-economic study of different alternatives for biodiesel production , 2008 .

[52]  S. Bhatia,et al.  ULTRASONIC-ASSISTED BIODIESEL PRODUCTION PROCESS FROM PALM OIL USING ALKALINE EARTH METAL OXIDES AS THE HETEROGENEOUS CATALYSTS , 2010 .

[53]  V. Gude,et al.  Microwave-Assisted Catalytic Transesterification of Camelina Sativa Oil , 2010 .

[54]  E. S. Umdu,et al.  Transesterification of Nannochloropsis oculata microalga's lipid to biodiesel on Al2O3 supported CaO and MgO catalysts. , 2009, Bioresource technology.

[55]  S. Godtfredsen,et al.  The future impact of industrial lipases , 1991 .

[56]  Anton A. Kiss Biodiesel by Reactive Absorption – Towards Green Technologies , 2009 .

[57]  S. T. El Sheltawy,et al.  Production optimization and quality assessment of biodiesel from waste vegetable oil , 2008 .

[58]  Shweta Shah,et al.  Lipase catalyzed preparation of biodiesel from Jatropha oil in a solvent free system. , 2007 .

[59]  Leilei Xu,et al.  Preparation of mesoporous polyoxometalate–tantalum pentoxide composite catalyst for efficient esterification of fatty acid , 2008 .

[60]  Nidal Hilal,et al.  Immobilization of cross-linked lipase aggregates within microporous polymeric membranes , 2004 .

[61]  Dora E. López,et al.  Transesterification of triacetin with methanol on solid acid and base catalysts , 2005 .

[62]  Bambang Veriansyah,et al.  Synthesis of biodiesel from rapeseed oil using supercritical methanol with metal oxide catalysts. , 2010, Bioresource technology.

[63]  A. Singh,et al.  A NOVEL CONTINUOUS-FLOW REACTOR USING REACTIVE DISTILLATION FOR BIODIESEL PRODUCTION , 2006 .

[64]  A. Demirbas,et al.  BIODIESEL FROM SUNFLOWER OIL IN SUPERCRITICAL METHANOL WITH CALCIUM OXIDE , 2007 .

[65]  Fabio Polonara,et al.  A review analyzing the industrial biodiesel production practice starting from vegetable oil refining , 2012 .

[66]  K. Muthukumar,et al.  An overview of enzymatic production of biodiesel. , 2008, Bioresource technology.

[67]  A. Tomašević,et al.  Methanolysis of used frying oil , 2003 .

[68]  M. Atapour,et al.  Characterization and transesterification of Iranian bitter almond oil for biodiesel production , 2011 .

[69]  Keat-Teong Lee,et al.  Renewable and sustainable bioenergies production from palm oil mill effluent (POME): win-win strategies toward better environmental protection. , 2011, Biotechnology advances.

[70]  Dora E. López,et al.  Synthesis of Biodiesel via Acid Catalysis , 2005 .

[71]  Yoshio Tominaga,et al.  Enzymatic conversion of waste edible oil to biodiesel fuel in a fixed-bed bioreactor , 2001 .

[72]  Dehua Liu,et al.  Conversion of Soybean Oil to Biodiesel Fuel Using Lipozyme TL IM in a Solvent-free Medium , 2004 .

[73]  M. R. Islam,et al.  Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production , 2008 .

[74]  Jyh-Ping Chen,et al.  Sol-gel powders and supported sol-gel polymers for immobilization of lipase in ester synthesis , 2003 .

[75]  H. Noureddini,et al.  A continuous process for the conversion of vegetable oils into methyl esters of fatty acids , 1998 .

[76]  X. Miao,et al.  Effective acid-catalyzed transesterification for biodiesel production. , 2009 .

[77]  Yi-Hsu Ju,et al.  Lipase‐catalyzed production of biodiesel from rice bran oil , 2005 .

[78]  J. Marchetti,et al.  Possible methods for biodiesel production , 2007 .

[79]  M Vinatoru,et al.  Aspects of ultrasonically assisted transesterification of various vegetable oils with methanol. , 2006, Ultrasonics sonochemistry.

[80]  Y. Chisti Biodiesel from microalgae. , 2007, Biotechnology advances.

[81]  M. Misra,et al.  Quintinite as a bifunctional heterogeneous catalyst for biodiesel synthesis , 2011 .

[82]  Yuanfa Liu,et al.  Refining of biodiesel by ceramic membrane separation , 2009 .

[83]  José M. Encinar,et al.  Ethanolysis of used frying oil. Biodiesel preparation and characterization , 2007 .

[84]  Y. Ju,et al.  Biodiesel production from rice bran by a two-step in-situ process. , 2010, Bioresource technology.

[85]  Jian-Zhong Yin,et al.  Biodiesel from soybean oil in supercritical methanol with co-solvent. , 2008 .

[86]  N. Laosiripojana,et al.  Biocatalytic ethanolysis of palm oil for biodiesel production using microcrystalline lipase in tert-butanol system , 2010 .

[87]  Munir Cheryan,et al.  Continuous production of palm methyl esters , 2000 .

[88]  S. Šiler-Marinković,et al.  Kinetics of lipase-catalyzed hydrolysis of palm oil in lecithin/izooctane reversed micelles , 1998, Applied Microbiology and Biotechnology.

[89]  Ali O. Al-Shyoukh,et al.  Experimental evaluation of the transesterification of waste palm oil into biodiesel. , 2002, Bioresource technology.

[90]  P. Gogate,et al.  Intensification of esterification of acids for synthesis of biodiesel using acoustic and hydrodynamic cavitation. , 2008, Ultrasonics sonochemistry.

[91]  M Vinatoru,et al.  Ultrasonic versus silent methylation of vegetable oils. , 2006, Ultrasonics sonochemistry.

[92]  Alexandre C. Dimian,et al.  Biodiesel production by heat-integrated reactive distillation , 2008 .

[93]  G. Rozycki,et al.  The history of ultrasound. , 1998, The Surgical clinics of North America.

[94]  M. Iso,et al.  Production of biodiesel fuel from triglycerides and alcohol using immobilized lipase , 2001 .

[95]  Yunjun Yan,et al.  Production of biodiesel catalyzed by immobilized Pseudomonas cepacia lipase from Sapium sebiferum oil in micro-aqueous phase , 2010 .

[96]  J. Cabral,et al.  Sol-gel encapsulation: an efficient and versatile immobilization technique for cutinase in non-aqueous media. , 2006, Journal of biotechnology.

[97]  Changwei Hu,et al.  Integration of extraction and transesterification of lipid from jatropha seeds for the production of biodiesel , 2012 .

[98]  Dong Ying,et al.  Biodiesel production from crude rice bran oil and properties as fuel , 2009 .

[99]  Hideo Noda,et al.  Biodiesel-fuel production in a packed-bed reactor using lipase-producing Rhizopus oryzae cells immobilized within biomass support particles. , 2007 .

[100]  Jincheng Ding,et al.  Preparation and characterization of PSSA/PVA catalytic membrane for biodiesel production , 2010 .

[101]  G. Corro,et al.  Two-step biodiesel production from Jatropha curcas crude oil using SiO2·HF solid catalyst for FFA esterification step , 2010 .

[102]  A. Kondo,et al.  Pretreatment of immobilized Candida antarctica lipase for biodiesel fuel production from plant oil. , 2000, Journal of bioscience and bioengineering.

[103]  S. Yusup,et al.  Base catalyzed transesterification of acid treated vegetable oil blend for biodiesel production , 2010 .

[104]  A. A. Refaat,et al.  Optimum reaction time, performance and exhaust emissions of biodiesel produced by microwave irradiation , 2008 .

[105]  Wenlei Xie,et al.  Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil , 2006 .

[106]  Yasuaki Maeda,et al.  Methanolysis of triolein by low frequency ultrasonic irradiation , 2008 .

[107]  Rajender S. Varma,et al.  Solvent-free accelerated organic syntheses using microwaves , 2001 .

[108]  V. Agreda,et al.  High-purity methyl acetate via reactive distillation , 1990 .

[109]  Yomi Watanabe,et al.  Continuous production of biodiesel fuel from vegetable oil using immobilized Candida antarctica lipase , 2000 .

[110]  Y. Ghasemi,et al.  Chlorella sp.: A new strain with highly saturated fatty acids for biodiesel production in bubble-column photobioreactor , 2011 .

[111]  A. Mendes,et al.  Methanol steam reforming in a dual-bed membrane reactor for producing PEMFC grade hydrogen , 2010 .

[112]  A. Demirbas,et al.  Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification , 2009 .

[113]  C. Muraleedharan,et al.  Use of vegetable oils as I.C. engine fuels—A review , 2004 .

[114]  Shenlin Zhu,et al.  Comparison of membrane extraction with traditional extraction methods for biodiesel production , 2006 .

[115]  M. Lapuerta,et al.  Correlation for the estimation of the cetane number of biodiesel fuels and implications on the iodine number , 2009 .

[116]  Elio Santacesaria,et al.  Transesterification of Soybean Oil to Biodiesel by Using Heterogeneous Basic Catalysts , 2006 .

[117]  James R. Fair,et al.  Distillation Studies in a High-Gravity Contactor , 1996 .

[118]  D. Leung,et al.  A review on biodiesel production using catalyzed transesterification , 2010 .

[119]  Jinyue Yan,et al.  Biofuels in Asia , 2009 .

[120]  S. Erhan,et al.  Metathesis of methyl soyate with ruthenium catalysts , 2006 .

[121]  A. Agarwal,et al.  Biodiesel development from rice bran oil: Transesterification process optimization and fuel characterization , 2008 .

[122]  Elio Santacesaria,et al.  Synthesis of biodiesel via homogeneous Lewis acid catalyst , 2005 .

[123]  Poonam,et al.  Fast, easy ethanolysis of coconut oil for biodiesel production assisted by ultrasonication. , 2010, Ultrasonics sonochemistry.

[124]  S. Bhatia,et al.  Optimization of ultrasonic-assisted heterogeneous biodiesel production from palm oil: A response surface methodology approach , 2010 .

[125]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[126]  Havva Balat,et al.  Progress in biodiesel processing , 2010 .

[127]  A. McAloon,et al.  A process model to estimate biodiesel production costs. , 2006, Bioresource technology.

[128]  Giancarlo Cravotto,et al.  A new pilot flow reactor for high-intensity ultrasound irradiation. Application to the synthesis of biodiesel. , 2010, Ultrasonics sonochemistry.

[129]  Nehemias Curvelo Pereira,et al.  Separation of biodiesel and glycerol using ceramic membranes , 2010 .

[130]  Eric J. Doskocil,et al.  Transesterification of soybean oil with zeolite and metal catalysts , 2004 .

[131]  Alain Marty,et al.  Esterification and Interesterification Activities of Lipases from Rhizopus niveus and Mucor miehei in Three Different Types of Organic Media: A Comparative Study , 1998 .

[132]  P. T. Vasudevan,et al.  Enzyme catalyzed production of biodiesel from olive oil , 2006, Applied biochemistry and biotechnology.

[133]  Li Wang,et al.  Lipase-catalyzed transesterification of rapeseed oils for biodiesel production with a novel organic solvent as the reaction medium , 2006 .

[134]  N. Hilal,et al.  Lipase-immobilized biocatalytic membranes for enzymatic esterification: Comparison of various approaches to membrane preparation , 2006 .

[135]  Rubens Maciel Filho,et al.  Biodiesel Production from Integration Between Reaction and Separation System: Reactive Distillation Process , 2010, Applied biochemistry and biotechnology.

[136]  Jincheng Ding,et al.  Preparation and characterization of the organic-inorganic hybrid membrane for biodiesel production. , 2010, Bioresource technology.

[137]  Zichen Wang,et al.  In situ production of fatty acid methyl ester from low quality rice bran: An economical route for biodiesel production , 2010 .

[138]  C. G. Smith,et al.  Mass transfer effects in solvent‐free fat interesterification reactions: Influences on catalyst design , 1994, Biotechnology and bioengineering.

[139]  Keat Teong Lee,et al.  Life cycle assessment of palm biodiesel: Revealing facts and benefits for sustainability , 2009 .

[140]  M. Kouzu,et al.  A process to transesterify vegetable oil with methanol in the presence of quick lime bit functioning as solid base catalyst , 2009 .

[141]  Ayhan Demirbas,et al.  Competitive liquid biofuels from biomass , 2011 .

[142]  D. Royon,et al.  Enzymatic production of biodiesel from cotton seed oil using t-butanol as a solvent. , 2007, Bioresource technology.

[143]  Stanley Bruckenstein,et al.  Dual porous electrode membrane cell for detection of nonelectroactive species in flowing streams , 1987 .

[144]  A. C. Dimian,et al.  Solid acid catalysts for biodiesel production - towards sustainable energy , 2006 .

[145]  Dipti Singh,et al.  Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review , 2010 .

[146]  M. P. Dorado,et al.  EXHAUST EMISSIONS FROM A DIESEL ENGINE FUELED WITH TRANSESTERIFIED WASTE OLIVE OIL , 2003 .

[147]  Farid Nasir Ani,et al.  THE PRODUCTION OF BIODIESEL FROM WASTE COOKING OIL USING MICROWAVE IRRADIATION , 2011 .

[148]  Rajamani Krishna,et al.  Modelling reactive distillation , 2000 .

[149]  J. C. Thompson,et al.  Experimental optimization of a continuous-flow reactive distillation reactor for biodiesel production. , 2005 .

[150]  Ramkrishna Sen,et al.  Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics , 2011 .

[151]  A. Harvey,et al.  Kinetic of myristic acid esterification with methanol in the presence of triglycerides over sulfated zirconia , 2011 .

[152]  Jinke Chang,et al.  Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil , 2012 .

[153]  Guo Chen,et al.  Preparation of solid acid catalyst from glucose-starch mixture for biodiesel production. , 2011, Bioresource technology.

[154]  Weiliang Cao,et al.  Preparation of biodiesel from soybean oil using supercritical methanol and co-solvent , 2005 .

[155]  K. Lee,et al.  Tungsten oxide zirconia as solid superacid catalyst for esterification of waste acid oil (dark oil). , 2010, Bioresource technology.

[156]  Giovanni Modica,et al.  Fatty acid methyl esters synthesis from triglycerides over heterogeneous catalysts in the presence of microwaves , 2004 .

[157]  S. Yusup,et al.  Reactive extraction and in situ esterification of Jatropha curcas L. seeds for the production of biodiesel , 2010 .

[158]  M. G. Kontominas,et al.  Biodiesel Production: Reaction and Process Parameters of Alkali-Catalyzed Transesterification of Waste Frying Oils , 2007 .

[159]  A. Kondo,et al.  Effect of methanol and water contents on production of biodiesel fuel from plant oil catalyzed by various lipases in a solvent-free system. , 2001, Journal of bioscience and bioengineering.

[160]  Ángeles Cancela,et al.  Macroalgae: Raw material for biodiesel production , 2011 .

[161]  Marc A. Dubé,et al.  Glycerol removal from biodiesel using membrane separation technology , 2010 .

[162]  Ján Cvengroš,et al.  Used frying oils and fats and their utilization in the production of methyl esters of higher fatty acids , 2004 .

[163]  Hsiao-Ping Huang,et al.  Production of high-purity ethyl acetate using reactive distillation: Experimental and start-up procedure , 2008 .

[164]  Bolun Yang,et al.  Synthesis of biodiesel from soybean oil and methanol catalyzed by zeolite beta modified with La3 , 2007 .

[165]  M. J. Nye,et al.  Conversion of used frying oil to diesel fuel by transesterification: Preliminary tests , 1983 .

[166]  Alexandre C. Dimian,et al.  Fatty acid esterification by reactive distillation. Part 1: equilibrium-based design , 2003 .

[167]  J M Dias,et al.  COMPARISON OF DIFFERENT HOMOGENEOUS ALKALI CATALYSTS DURING TRANSESTERIFICATION OF WASTE AND VIRGIN OILS AND EVALUATION OF BIODIESEL QUALITY , 2008 .

[168]  M. Zong,et al.  Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts. , 2008, Bioresource technology.

[169]  Jie Zhang,et al.  Efficient preparation of biodiesel from rapeseed oil over modified CaO , 2011 .

[170]  Susana Marmesat,et al.  Analysis of used frying fats for the production of biodiesel , 2008 .

[171]  Masitah Hasan,et al.  Kinetics of the enzymatic hydrolysis of palm oil by lipase , 2003 .

[172]  A. Kondo,et al.  Biodiesel fuel production by transesterification of oils. , 2001, Journal of bioscience and bioengineering.

[173]  N. Sdrula A study using classical or membrane separation in the biodiesel process , 2010 .

[174]  Chia-Chang Lin,et al.  Ozone oxidation in a rotating packed bed , 2003 .

[175]  Miguel Mattea,et al.  Ultrafiltration of vegetable oils: Degumming by polymeric membranes , 2001 .

[176]  Jie Chang,et al.  Synthesis of biodiesel from waste cooking oil using immobilized lipase in fixed bed reactor. , 2009 .

[177]  Yogesh Chandra Sharma,et al.  Response to the comments on “Advancements in development and characterization of biodiesel: A review”. Sharma YC, Singh B, Upadhyay SN. Fuel 2008;87:2355–73 by Clifford Jones , 2009 .

[178]  Takuya Fukumura,et al.  Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst. , 2007, Bioresource technology.

[179]  Jianghua Wang,et al.  Biodiesel production from high acid value waste frying oil catalyzed by superacid heteropolyacid , 2008, Biotechnology and bioengineering.

[180]  J. H. Van Gerpen,et al.  A pilot plant to produce biodiesel from high free fatty acid feedstocks. , 2003 .

[181]  M. P. Dorado,et al.  AN ALKALI–CATALYZED TRANSESTERIFICATION PROCESS FOR HIGH FREE FATTY ACID WASTE OILS , 2002 .

[182]  T J Mason,et al.  Large scale sonochemical processing: aspiration and actuality. , 2000, Ultrasonics sonochemistry.

[183]  Ching Hua Lee,et al.  Optimized synthesis of lipase‐catalyzed biodiesel by Novozym 435 , 2005 .

[184]  Bai Rongxian,et al.  Study on the carbon dioxide hydrogenation to iso-alkanes over Fe-Zn-M/zeolite composite catalysts , 2004 .

[185]  Sunderasan Srinivasan,et al.  The food v. fuel debate: A nuanced view of incentive structures , 2009 .

[186]  P. Sivakumar,et al.  Production of biodiesel from mixed waste vegetable oil using an aluminium hydrogen sulphate as a heterogeneous acid catalyst. , 2011, Bioresource technology.

[187]  L. C. Meher,et al.  Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification , 2006 .

[188]  Keat-Teong Lee,et al.  Mixed methanol–ethanol technology to produce greener biodiesel from waste cooking oil: A breakthrough for SO42−/SnO2–SiO2 catalyst , 2011 .

[189]  M. Mbarawa,et al.  Alkaline catalyzed biodiesel production from moringa oleifera oil with optimized production parameters , 2010 .

[190]  S. Meneghetti,et al.  Fatty acid methyl esters preparation in the presence of maltolate and n-butoxide Ti(IV) and Zr(IV) complexes , 2008 .

[191]  Tsutomu Sakai,et al.  Economic assessment of batch biodiesel production processes using homogeneous and heterogeneous alkali catalysts. , 2009, Bioresource technology.

[192]  Shazia Sultana,et al.  Optimization of base catalyzed transesterification of peanut oil biodiesel , 2009 .

[193]  Akihiko Kondo,et al.  Effect of fatty acid membrane composition on whole-cell biocatalysts for biodiesel-fuel production , 2004 .

[194]  A. A. Kiss Novel process for biodiesel by reactive absorption , 2009 .

[195]  Martin Mittelbach,et al.  Lipase catalyzed alcoholysis of sunflower oil , 1990 .

[196]  T. Okuhara Water-tolerant solid acid catalysts. , 2002, Chemical reviews.

[197]  Elio Santacesaria,et al.  Heterogeneous catalysts for biodiesel production , 2008 .

[198]  L. A. Smith,et al.  New MTBE design now commercial. [Methyl tertiary butyl ether] , 1982 .

[199]  N. Chollacoop,et al.  Waste shells of mollusk and egg as biodiesel production catalysts. , 2010, Bioresource technology.

[200]  K. Bélafi-Bakó,et al.  Enzymatic Biodiesel Production from Sunflower Oil by Candida antarctica Lipase in a Solvent-free System , 2002 .

[201]  Xuewu Zhang,et al.  Biodiesel Production by Microalgal Biotechnology , 2018, Renewable Energy.

[202]  V. Brei Superacids Based on Zirconium Dioxide , 2005 .

[203]  Aleksandra R. Zarubica,et al.  Kinetics of biodiesel synthesis from sunflower oil over CaO heterogeneous catalyst , 2010 .

[204]  M. Hasan,et al.  Hydrolysis of palm and olive oils by immobilised lipase using hollow fibre reactor , 2007 .

[205]  Pen-Chi Chiang,et al.  Modeling ozonation process with pollutant in a rotating packed bed , 2005 .

[206]  Mahadhir Mohamed,et al.  A two-step biodiesel production from waste cooking oil : optimization of pre-treatment step , 2009 .

[207]  D. Leung,et al.  Transesterification of neat and used frying oil : Optimization for biodiesel production , 2006 .

[208]  A. Vyas,et al.  PRODUCTION OF BIODIESEL THROUGH TRANSESTERIFICATION OF JATROPHA OIL USING KNO3/AL2O3 SOLID CATALYST , 2009 .

[209]  Zeeshan Nawaz,et al.  Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst , 2010 .

[210]  R. Prasad,et al.  Lipase-mediated conversion of vegetable oils into biodiesel using ethyl acetate as acyl acceptor. , 2007, Bioresource technology.

[211]  Man Kee Lam,et al.  Potential of using organic fertilizer to cultivate Chlorella vulgaris for biodiesel production , 2012 .

[212]  Process for fatty acid methyl esters by dual reactive distillation , 2007 .

[213]  Ş. Altun,et al.  Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine , 2009 .

[214]  Tapio Salmi,et al.  Three-phase catalytic hydrogenation of xylose to xylitol — prolonging the catalyst activity by means of on-line ultrasonic treatment , 2001 .

[215]  U. A. Asli,et al.  A new heterogeneous ZnL2 catalyst on a structured support for biodiesel production , 2009 .

[216]  D. Chang,et al.  Removal of free fatty acid in waste frying oil by esterification with methanol on zeolite catalysts. , 2008, Bioresource technology.

[217]  T. Tan,et al.  Biodiesel production with immobilized lipase: A review. , 2010, Biotechnology advances.

[218]  R. Chakraborty,et al.  Application of calcined waste fish (Labeo rohita) scale as low-cost heterogeneous catalyst for biodiesel synthesis. , 2011, Bioresource technology.

[219]  D. M. Alonso,et al.  Deactivation of organosulfonic acid functionalized silica catalysts during biodiesel synthesis , 2010 .

[220]  A. Kamaruddin,et al.  Continuous biosynthesis of biodiesel from waste cooking palm oil in a packed bed reactor: optimization using response surface methodology (RSM) and mass transfer studies. , 2009, Bioresource technology.

[221]  M. G. Kulkarni,et al.  PRODUCTION OF BIODIESEL FROM WASTE FRYER GREASE USING MIXED METHANOL/ETHANOL SYSTEM , 2007 .

[222]  Jinfu Wang,et al.  Experimental Studies on the Catalytic Distillation for Hydrolysis of Methyl Acetate , 2001 .

[223]  Biodiesel production by integrated reactive-separation design , 2007 .

[224]  E. Molina-Grima,et al.  Biocatalysis: towards ever greener biodiesel production. , 2009, Biotechnology advances.

[225]  Jianfeng Chen,et al.  Scale-up Preparation of Organized Mesoporous Alumina in a Rotating Packed Bed , 2007 .

[226]  Dadan Kusdiana,et al.  Biodiesel fuel from rapeseed oil as prepared in supercritical methanol , 2001 .

[227]  O. İlgen Dolomite as a heterogeneous catalyst for transesterification of canola oil , 2011 .

[228]  Weiliang Cao,et al.  Preparation of biodiesel from soybean oil using supercritical methanol and CO2 as co-solvent , 2005 .

[229]  R. Srivastava,et al.  Hydrophobic, solid acid catalysts for production of biofuels and lubricants , 2006 .

[230]  Jeffrey Philip Obbard,et al.  Recovery and pre-treatment of fats, oil and grease from grease interceptors for biodiesel production , 2010 .

[231]  Dehua Liu,et al.  Comparative study on lipase-catalyzed transformation of soybean oil for biodiesel production with different acyl acceptors , 2004 .

[232]  C. R. Wolf,et al.  Utilization of metal complexes as catalysts in the transesterification of Brazilian vegetable oils with different alcohols , 2004 .

[233]  M. Dubé,et al.  Methanol recycling in the production of biodiesel in a membrane reactor , 2008 .

[234]  Kok Tat Tan,et al.  Biodiesel production by non-catalytic supercritical methyl acetate: Thermal stability study , 2013 .

[235]  E. H. Pryde,et al.  Variables affecting the yields of fatty esters from transesterified vegetable oils , 1984 .

[236]  Ángel Sánchez,et al.  Culture aspects of Isochrysis galbana for biodiesel production , 2013 .

[237]  Dilhan M. Kalyon,et al.  Conversion of biomass to fuel: Transesterification of vegetable oil to biodiesel using KF loaded nano-γ-Al2O3 as catalyst , 2009 .

[238]  Smita Krishnan,et al.  The effect of fatty acid concentration and water content on the production of biodiesel by lipase , 2006 .

[239]  Alexandre C. Dimian,et al.  Entrainer-enhanced reactive distillation , 2002 .

[240]  Jianfeng Chen,et al.  Micromixing Efficiency in a Rotating Packed Bed: Experiments and Simulation , 2005 .

[241]  C. Nolasco-Hipólito,et al.  Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties , 2001 .

[242]  Maialen Sánchez,et al.  Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts: Comparison with homogeneous NaOH , 2007 .

[243]  David Pimentel,et al.  Food Versus Biofuels: Environmental and Economic Costs , 2009 .

[244]  Masato Kouzu,et al.  Transesterification of vegetable oil into biodiesel catalyzed by CaO: A review , 2012 .

[245]  Yi-Hung Chen,et al.  A continuous-flow biodiesel production process using a rotating packed bed. , 2010, Bioresource technology.

[246]  A. Vyas,et al.  A review on FAME production processes , 2010 .

[247]  T. Foglia,et al.  The General Applicability of in Situ Transesterification for the Production of Fatty Acid Esters from a Variety of Feedstocks , 2007 .

[248]  S. Bhatia,et al.  Biodiesel production from palm oil via heterogeneous transesterification , 2009 .

[249]  M. Mohammadi,et al.  Biodiesel Production from Microalgae , 2013 .

[250]  Bryan Orchard,et al.  Developments in biofuel processing technologies , 2007 .

[251]  G. Lin,et al.  Ultrasound-promoted lipase-catalyzed reactions , 1995 .

[252]  Jichu Yang,et al.  Transesterification of soybean oil with nano-MgO or not in supercritical and subcritical methanol , 2007 .

[253]  R. Hernandez,et al.  Base-Catalyzed Fast Transesterification of Soybean Oil Using Ultrasonication , 2007 .

[254]  Yong Wang,et al.  Preparation of biodiesel from waste cooking oil via two-step catalyzed process. , 2007 .

[255]  Rajesh Gopinath,et al.  Solid acid catalyzed biodiesel production from waste cooking oil , 2008 .

[256]  Heyou Han,et al.  Nano-magnetic catalyst KF/CaOFe 3O 4 for biodiesel production , 2011 .

[257]  A. Demirbas,et al.  Comparison of transesterification methods for production of biodiesel from vegetable oils and fats. , 2008 .

[258]  M. Olutoye,et al.  Synthesis of fatty acid methyl ester from used vegetable cooking oil by solid reusable Mg 1-x Zn 1+x O2 catalyst. , 2011, Bioresource technology.

[259]  Xiaohu Fan,et al.  Preparation and characterization of biodiesel produced from recycled canola oil. , 2009 .

[260]  Susana Luque,et al.  PRODUCTION OF BIODIESEL FROM VEGETABLE OILS , 2008 .

[261]  E. H. Pryde,et al.  Fuel properties of eleven vegetable oils , 1982 .

[262]  C. Stavarache,et al.  Fatty acids methyl esters from vegetable oil by means of ultrasonic energy. , 2005, Ultrasonics sonochemistry.

[263]  Younis Jamal,et al.  Production of biodiesel: A technical review , 2011 .

[264]  M. G. Kulkarni,et al.  WASTE COOKING OIL – AN ECONOMICAL SOURCE FOR BIODIESEL: A REVIEW , 2006 .

[265]  E. H. Pryde,et al.  Transesterification kinetics of soybean oil 1 , 1986 .

[266]  Chia-Chang Lin,et al.  Removal of carbon dioxide by absorption in a rotating packed bed , 2003 .

[267]  Qingyu Wu,et al.  Application of sweet sorghum for biodiesel production by heterotrophic microalga Chlorella protothecoides , 2010 .

[268]  Feng Yan,et al.  Biodiesel production using cation-exchange resin as heterogeneous catalyst. , 2010, Bioresource technology.

[269]  Yasuaki Maeda,et al.  Ultrasound-assisted production of biodiesel fuel from vegetable oils in a small scale circulation process. , 2010, Bioresource technology.

[270]  Kiyotaka Sato,et al.  Crystallization behavior of neat biodiesel and biodiesel treated with ozonized vegetable oil , 2005 .

[271]  Dae Won Lee,et al.  The heterogeneous catalyst system for the continuous conversion of free fatty acids in used vegetable oils for the production of biodiesel , 2008 .

[272]  Wallace M. Antunes,et al.  Transesterification of soybean oil with methanol catalyzed by basic solids , 2008 .

[273]  S. Kamarudin,et al.  Microwave-assisted transesterification of jatropha and waste frying palm oil , 2009 .

[274]  Costin Sorin Bildea,et al.  Integrated reactive absorption process for synthesis of fatty esters. , 2011, Bioresource technology.

[275]  P. T. Vasudevan,et al.  Biodiesel production—current state of the art and challenges , 2008, Journal of Industrial Microbiology & Biotechnology.

[276]  Shabbir H. Gheewala,et al.  Full chain energy analysis of biodiesel production from palm oil in Thailand , 2009 .

[277]  Lloyd S. White,et al.  Solvent recovery from lube oil filtrates with a polyimide membrane , 2000 .

[278]  Maryam Alshehhi,et al.  Enzymatic production of biodiesel from used/waste vegetable oils: Design of a pilot plant , 2011 .

[279]  A. C. Dimian,et al.  Biodiesel by catalytic reactive distillation powered by metal oxides , 2008 .

[280]  Changwei Hu,et al.  One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst , 2011 .

[281]  Andreas Beckmann,et al.  Reactive distillation : industrial applications, process design & scale-up , 2001 .

[282]  A. Kondo,et al.  Biodiesel fuel production from plant oil catalyzed by Rhizopus oryzae lipase in a water-containing system without an organic solvent. , 1999, Journal of bioscience and bioengineering.

[283]  Brent H. Shanks,et al.  Esterification of biomass pyrolysis model acids over sulfonic acid-functionalized mesoporous silicas , 2009 .

[284]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 1. Process design and technological assessment. , 2003, Bioresource technology.

[285]  A. Gedanken,et al.  Continuous Flow, Circulating Microwave System and Its Application in Nanoparticle Fabrication and Biodiesel Synthesis , 2008 .

[286]  J. Petrus,et al.  The optimisation of soybean oil degumming on a pilot plant scale using a ceramic membrane , 2008 .

[287]  M. Canakci,et al.  EVALUATING WASTE COOKING OILS AS ALTERNATIVE DIESEL FUEL , 2005 .

[288]  A. Górak,et al.  Process Analysis of Hybrid Separation Processes: Combination of Distillation and Pervaporation , 2006 .

[289]  P. Chiang,et al.  Combined photolysis and catalytic ozonation of dimethyl phthalate in a high-gravity rotating packed bed. , 2009, Journal of hazardous materials.

[290]  M. P. Dorado,et al.  KINETIC PARAMETERS AFFECTING THE ALKALI-CATALYZED TRANSESTERIFICATION PROCESS OF USED OLIVE OIL , 2004 .

[291]  L. C. Meher,et al.  TRANSESTERIFICATION OF KARANJA (PONGAMIA PINNATA) OIL BY SOLID BASIC CATALYSTS , 2006 .

[292]  Rattanachai Pairintra,et al.  Microwave assisted in continuous biodiesel production from waste frying palm oil and its performance in a 100 kW diesel generator , 2008 .

[293]  S. Furuta,et al.  Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure , 2004 .

[294]  S. Chuepeng,et al.  Solid Acid Catalyst for Biodiesel Production from Waste Used Cooking Oils , 2009 .

[295]  Susana Marmesat,et al.  Quality of used frying fats and oils : comparison of rapid tests based on chemical and physical oil properties , 2007 .

[296]  M. Charoenchaitrakool,et al.  Statistical optimization for biodiesel production from waste frying oil through two-step catalyzed process , 2011 .

[297]  Yun Guo,et al.  A novel solid superbase of Eu2O3/Al2O3 and its catalytic performance for the transesterification of soybean oil to biodiesel , 2007 .

[298]  Kok Tat Tan,et al.  Potential of waste palm cooking oil for catalyst-free biodiesel production , 2011 .

[299]  Gökhan Çaylı,et al.  Increased yields in biodiesel production from used cooking oils by a two step process: Comparison with one step process by using TGA , 2008 .

[300]  Dilek Kazan,et al.  Biodiesel production from waste oils by using lipase immobilized on hydrotalcite and zeolites , 2007 .

[302]  Ian McCallum,et al.  Optimizing biodiesel production in India , 2009 .

[303]  Hak Joo Kim,et al.  TRANSESTERIFICATION OF VEGETABLE OIL TO BIODIESEL USING HETEROGENEOUS BASE CATALYST , 2004 .

[304]  T. Foglia,et al.  Production of alkyl esters from tallow and grease using lipase immobilized in a phyllosilicate sol-gel , 2001 .

[305]  Man Kee Lam,et al.  Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: a review. , 2010, Biotechnology advances.

[306]  L. C. Meher,et al.  Technical aspects of biodiesel production by transesterification—a review , 2006 .

[307]  C. Stavarache,et al.  Ultrasonically driven continuous process for vegetable oil transesterification. , 2007, Ultrasonics sonochemistry.

[308]  W. Daud,et al.  Activity of solid catalysts for biodiesel production: A review , 2009 .

[309]  J. Marchetti,et al.  Comparison of different heterogeneous catalysts and different alcohols for the esterification reaction of oleic acid , 2008 .

[310]  Fei Wang,et al.  In situ alkaline transesterification of cottonseed oil for production of biodiesel and nontoxic cottonseed meal. , 2008, Bioresource technology.

[311]  Yomi Watanabe,et al.  Enzymatic alcoholysis for biodiesel fuel production and application of the reaction to oil processing , 2002 .

[312]  R. A. Ashworth,et al.  Removal of volatile organic compounds from groundwater using a rotary air stripper , 1992 .

[313]  J. V. Gerpen,et al.  Biodiesel processing and production , 2005 .

[314]  Brian J. Krohn,et al.  A continuous catalytic system for biodiesel production , 2008 .

[315]  J. U. Obibuzor,et al.  Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils. , 2000, Biochemical Society transactions.

[316]  Yasuaki Maeda,et al.  A two-step continuous ultrasound assisted production of biodiesel fuel from waste cooking oils: a practical and economical approach to produce high quality biodiesel fuel. , 2010, Bioresource technology.

[317]  H. Noureddini,et al.  Immobilized Pseudomonas cepacia lipase for biodiesel fuel production from soybean oil. , 2005, Bioresource technology.

[318]  B. Singh,et al.  Advancements in development and characterization of biodiesel: A review , 2008 .

[319]  Ching-Yuan Chang,et al.  Pt-catalyzed ozonation of aqueous phenol solution using high-gravity rotating packed bed. , 2009, Journal of hazardous materials.

[320]  A. Demirbas,et al.  Relationships derived from physical properties of vegetable oil and biodiesel fuels , 2008 .

[321]  Jinyue Yan,et al.  Energy from algae: Current status and future trends: Algal biofuels – A status report , 2011 .

[322]  Geert Versteeg,et al.  Current hurdles to the success of high temperature membrane reactorS , 1994 .

[323]  Guanyi Chen,et al.  Biodiesel production from waste cooking oil via alkali catalyst and its engine test , 2008 .

[324]  M. Almeida,et al.  Comparison of the performance of different homogeneous alkali catalysts during transesterification of waste and virgin oils and evaluation of biodiesel quality , 2008 .

[325]  Timothy J. Mason,et al.  The uses of ultrasound in food technology , 1996 .

[326]  Andrzej Górak,et al.  Hybrid separation processes—Combination of reactive distillation with membrane separation , 2007 .

[327]  T. Baba,et al.  Selective transesterification of triolein with methanol to methyl oleate and glycerol using alumina loaded with alkali metal salt as a solid-base catalyst , 2005 .

[328]  Erik Dahlquist,et al.  Synthesis of biodiesel from vegetable oil with methanol catalyzed by Li-doped magnesium oxide catalysts , 2010 .

[329]  Jianfeng Chen,et al.  Characterization of micromixing efficiency in rotating packed beds by chemical methods , 2006 .

[330]  Dimitrios Samios,et al.  The use of a modified TDSP for biodiesel production from soybean, linseed and waste cooking oil , 2011 .

[331]  Do Van Manh,et al.  Biodiesel production from Tung oil and blended oil via ultrasonic transesterification process , 2011 .

[332]  Jae-Hoon Hwang,et al.  Characterization of microalgal species isolated from fresh water bodies as a potential source for biodiesel production , 2011 .

[333]  Chia-Chang Lin,et al.  Characteristics of a Rotating Packed Bed , 1996 .

[334]  E. Dahlquist,et al.  Intensification of biodiesel synthesis using zigzag micro-channel reactors. , 2009, Bioresource technology.

[335]  Ke-Shun Liu Preparation of fatty acid methyl esters for gas-chromatographic analysis of lipids in biological materials , 1994 .

[336]  T. Foglia,et al.  Lipase-catalyzed production of biodiesel , 1996 .

[337]  Ping Sun,et al.  Biodiesel production from mixed soybean oil and rapeseed oil , 2011 .

[338]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis. , 2003, Bioresource technology.

[339]  M. Sharma,et al.  Acid base catalyzed transesterification kinetics of waste cooking oil , 2011 .

[340]  Filiz Karaosmanoǧlu,et al.  Investigation of the Refining Step of Biodiesel Production , 1996 .

[341]  A. Luengnaruemitchai,et al.  A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil , 2009 .

[342]  Pen-Chi Chiang,et al.  Modeling ozone contacting process in a rotating packed bed , 2004 .

[343]  M. Mbarawa,et al.  Technical aspects of production and analysis of biodiesel from used cooking oil--A review , 2009 .

[344]  Geert Versteeg,et al.  High-temperature membrane reactors: potential and problems , 1999 .