Monitoring and Blending Biofuels Using a Microfluidic Sensor

Density measurements have long been used to monitor petrochemical distillation. The density of the petrochemicals decreases as one moves up the distillation column. Measuring the density or specific gravity of biodiesel has been reported to be the preferred method of blending biodiesel fuel for both accuracy and ease of use. To see widespread use, a measurement technology must not only be capable of accurately monitoring a parameter, but it must do so in an economical way. This paper explores the application of microelectromechanical systems technology to fuel monitoring, quality control, and blending. This microfluidic sensor has on-chip density/specific gravity, temperature, and viscosity measurement ca- pabilities, as will be demonstrated in the experimental results. The ability to differentiate between gasoline, ethanol, diesel, biodiesel, butanol, Fischer-Tropsch fuel, water, and air contamination with a density mea- surement and in some cases a viscosity measurement will be demonstrated. Using gravimetric measure- ments, based on fluid density, concentrations of fuel blends like ethanol-gasoline can be measured. Con- tamination levels of water in ethanol can also be measured in this manner. The density of fuel over temperature can be made with this sensing technology and applied to custody transfer. Potential microflu- idic clogging issues are addressed by filtration and by adding the capability of sensing flow through the sensor. Measuring fluids under high flow rates is accommodated with a bypass design. An intrinsically safe circuit has been developed to enable use of this technology with flammable liquids. Vibration testing has been undertaken to show that these micromachined devices, with their high resonant frequencies, are immune to vehicular and aviation vibration, unlike conventional density metres made using larger resonat- ing steel tubing.

[1]  D. S. Eddy,et al.  Application of MEMS technology in automotive sensors and actuators , 1998 .

[2]  Sonbol Massoud-Ansari,et al.  CORIOLIS MASS FLOW, DENSITY AND TEMPERATURE SENSING WITH A SINGLE VACCUM SEALED MEMS CHIP , 2004 .

[3]  N. M. Kéita,et al.  Behaviour of straight pipe Coriolis mass flowmeters in the metering of gas: theoretical predictions with experimental verification , 1994 .

[4]  Nader Najafi,et al.  Embedded MEMS-based concentration sensor for fuel cell and biofuel applications , 2008 .

[5]  J. A. Kinast,et al.  Production of Biodiesels from Multiple Feedstocks and Properties of Biodiesels and Biodiesel/Diesel Blends: Final Report; Report 1 in a Series of 6 , 2003 .

[6]  N. Najafi,et al.  Dynamic and kinematic viscosity measurements with a resonating microtube , 2009 .

[7]  Nader Najafi,et al.  A By-Pass Sensor Package Design Enabling the Use of Microfluidics in High Flow Rate Applications , 2006 .

[8]  K. Varde,et al.  A Comparison of Burn Characteristics and Exhaust Emissions from Off-Highway Engines Fueled by E0 and E85 , 2004 .

[9]  Sonbol Massoud-Ansari,et al.  A variable temperature, resonant density sensor made using an improved chip-level vacuum package , 2003 .

[10]  A. F Skea,et al.  Effects of gas leaks in oil flow on single-phase flowmeters , 1999 .

[11]  L. L. Stavinoha,et al.  Alternative Fuels: Assessment of Fischer-Tropsch Fuel for Military Use in 6.5L Diesel Engine , 2004 .

[12]  Justin Duban,et al.  On Farm Methods of Biodiesel Blend Detection , 2006 .

[13]  James J. Eberhardt,et al.  On-Road Use of Fischer-Tropsch Diesel Blends , 1999 .

[14]  Robert L. Furey,et al.  Emissions, Fuel Economy, and Driveability Effects of Methanol/Butanol/Gasoline Fuel Blends , 1982 .

[15]  Mustafa Ertunc Tat,et al.  Physical Properties and Composition Detection of Biodiesel-diesel Fuel Blends , 2002 .

[16]  F. N. Alasfour BUTANOL—A SINGLE CYLINDER ENGINE STUDY: ENGINE PERFORMANCE , 1997 .