Fluids of clusters in attractive colloids.

We show that colloidal particles with attractive interactions induced by a nonadsorbing polymer exhibit a stable phase consisting of a fluid of clusters of particles. This phase persists even in the absence of any long-range repulsion due to charge, contrary to expectations based on simulation and theory. Cluster morphology depends strongly on the range of the interparticle attraction: With a shorter range, clusters are tenuous and branched; with a longer range, they are more compact.

[1]  M. Cates,et al.  Theory and simulation of gelation, arrest and yielding in attracting colloids , 2004, cond-mat/0403684.

[2]  D A Weitz,et al.  Charge stabilization in nonpolar solvents. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[3]  A. Blaaderen,et al.  A colloidal model system with an interaction tunable from hard sphere to soft and dipolar , 2003, Nature.

[4]  P. B. Warren,et al.  Phase Behaviour of Colloid + Polymer Mixtures , 1992 .

[5]  Paul Bartlett,et al.  Dynamical arrest in attractive colloids: the effect of long-range repulsion. , 2005, Physical review letters.

[6]  P. Meakin Formation of fractal clusters and networks by irreversible diffusion-limited aggregation , 1983 .

[7]  Frédéric Cardinaux,et al.  Equilibrium cluster formation in concentrated protein solutions and colloids , 2004, Nature.

[8]  Jan Groenewold,et al.  Anomalously large equilibrium clusters of colloids , 2001 .

[9]  W. Kegel,et al.  Colloidal cluster phases, gelation and nuclear matter , 2004 .

[10]  Stefano Mossa,et al.  Equilibrium cluster phases and low-density arrested disordered states: the role of short-range attraction and long-range repulsion. , 2004, Physical review letters.

[11]  Poon,et al.  Phase behavior of a model colloid-polymer mixture. , 1995, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.

[12]  D. Frenkel,et al.  Breakdown of classical nucleation theory near isostructural phase transitions. , 2004, Physical review letters.

[13]  P. Mazur,et al.  Self-diffusion of spheres in a concentrated suspension , 1983 .

[14]  Giglio,et al.  Spinodal-type dynamics in fractal aggregation of colloidal clusters. , 1992, Physical review letters.

[15]  P. F. Onyon Polymer Handbook , 1972, Nature.

[16]  V. Prasad,et al.  Glasslike kinetic arrest at the colloidal-gelation transition. , 2001, Physical review letters.