It is known that the transport sector has a fundamental importance to the modern society, once the economic development is directly linked to mobility. Over the years, the transport became linked to different environmental problems, among them, can be detached greenhouse gases emissions in the atmosphere, where in recent decades can be perceived the intensification and targeting of efforts in research and development of new technologies to reduce the levels of greenhouse gases emissions in the atmosphere. In this context, it can be highlighted the modern systems of electronic engine management, new automotive catalysts and the use of renewable fuels which contribute to reducing the environmental impact. This research had as its purpose the analysis of fuels characteristics used for testing, comparative analysis of gas emissions from a motor vehicle running on ethanol or natural gas fuels according to NBR 6601 and conducting tests to estimate the maximum catalytic efficiency. For the implementation of trial, a flex vehicle was installed in a chassis dynamometer equipped with a gas analyzer, in order that before the completion of the urban driving cycle, were determined the content of hydrocarbons corrected, carbon monoxide corrected, carbon dioxide and oxygen present in gas emissions from the engine. The research concluded that: the performance analysis for characterization of fuel showed consistent with ANP specifications; after tests performances, it can be stated that NATURAL GAS FUEL was the fuel which had the highest content of hydrocarbons and carbon monoxide corrected, while ethanol had the highest amount of carbon dioxide and oxygen residue present in gas emissions; before a comparative analysis, the vehicle catalyst showed the best performance for reducing the content of hydrocarbon corrected present in exhaustion gases when it worked with NATURAL GAS FUEL and showed maximum efficiency of 100% to reduce the content of carbon monoxide corrected for both fuels. Before this, it can be stated that the vehicle catalyst showed satisfactory performance, achieving good reduction levels of greenhouse gases emissions.
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