论文信息 - PHOTOOXIDATION OF SOME MESOIONIC AND RELATED SYSTEMS

PHOTOOXIDATION OF SOME MESOIONIC AND RELATED SYSTEMS

Photooxidation of several mesoionic compounds gave ring cleavage products, some of which were apparently formed via the endoperoxides of the mesoionic rings. Photooxidation of a Δ2-oxazolin-4-one and a Δ2-thiazolin-4-one gave the corresponding 4,4′-bisoxa- and bisthiazolinone in dichloromethane, whereas the former gave benzamide in dimethylformamide.

H. Kato | K. Tani | Y. Tamura | Haruki Eurumisawa

[1] A. M. Trozzolo,et al. Sensitized photooxygenations of .DELTA.2-oxazolin-5-ones and related studies , 1979 .

[2] Hans Gottharddt,et al. Synthese und Cycloadditionen neuer Dimerer aus mesoionischen 1,3‐Dithiolonen , 1979 .

[3] A. Holm,et al. Photoinduced ring opening and fragmentation of isomeric mesoionic anhydro-4(5)-hydroxythiazolium hydroxides and of anhydro-5-hydroxy-3-methyl-2-phe , 1979 .

[4] A. Mori,et al. Synthetic Photochemistry. IV. The Reaction of Betaines with Singlet Oxygen , 1974 .

[5] R. Murray,et al. Oxidation of Diazo Compounds with Singlet Oxygen. Formation of Ozonides , 1974 .

[6] H. Bayer,et al. Darstellung und Eigenschaften mesoionischer Oxazolone , 1970 .

[7] R. Huisgen,et al. 1,3-Dipolar cycloaddition reactions. LIII. Question of the 1,3-dipolar nature of .DELTA.2-oxazolin-5-ones , 1970 .