Thermopower and resistivity due to dislocations in monovalent metals

Using the partial-wave method, the residual electrical resistivity and the additional and characteristic thermopowers of dislocations for noble and alkaline metals are calculated. Just the scattering of electrons by the dislocation core is considered. The existence of resonance electron states near the Fermi energy within the thermal scatter kBT is supposed. The lattice dilatation ΔV = bB2 (bB is the steady Burgers vector) is taken into account. Various forms of rectangular potential simulating the dislocation core are investigated. It is shown that unlike the dislocation resistivity, the thermoelectric characteristic of dislocations shows high sensitivity to change of the width of the resonance level and its localization relative to the Fermi energy. A model dislocation potential is suggested; with it, a rather good agreement with available experimental data is obtained.

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