High critical current Ag and Ag alloy sheathed multifilament Bi-2223 tapes

Ag sheathed (BiPb/sub 2/)Sr/sub 2/Ca/sub 2/Cu/sub 3/O/sub 10/ (Bi-2223) multifilament tapes with filament numbers of 19, 37, 55, and 85 were produced by the powder-in-tube method. Enhanced tape performance has been achieved by optimisation of the processing conditions. Key factors are addressed that include elimination of the 2212 phase, improving grain connectivity through reducing the 2201 phase and alkaline earth cuprate phases, increasing superconductor core density as well as enhancing current contribution from edge filaments. A high J/sub c/ of 50 kA/cm/sup 2/ with an I/sub c/ of 42 A has been achieved reproducibly in 19 filament tapes with dimensions of 0.16/spl times/2.8 mm/sup 2/ and silver/superconductor ratios of 4.4:1. By reducing the silver ratio, a J/sub e/ of 14 kA/cm/sup 2/ with an I/sub c/ of 48 A has been obtained in 55 filament tapes and an I/sub c/ of 84 A has been obtained in a tape with dimensions of 4/spl times/0.23 mm/sup 2/. A record J/sub c/ of more than 30 kA/cm/sup 2/ with an I/sub c/ of 32 A was achieved in 250 metres long standard tapes. A 1250 m long pure Ag sheathed tape and an 1100 m long Ag alloyed tape have been produced with a J/sub c/ of higher than 25 kA/cm/sup 2/ by using optimised process parameters.

[1]  P. Grant Superconductivity and electric power: promises, promises ... past, present and future , 1997, IEEE Transactions on Applied Superconductivity.

[2]  Á. Larrea,et al.  Formation and stability of the 2223 phase in high-Jc Ag-sheathed (Bi,Pb)2Sr2Ca2Cu3O10+ delta tapes , 1994 .

[3]  A. Iyer,et al.  Transport critical current density above at 77 K in superconducting tapes made by the Ag wire-in-tube method , 1996 .

[4]  T. Freltoft,et al.  TOPICAL REVIEW: The mechanical deformation of superconducting BiSrCaCuO/Ag composites , 1997 .

[5]  S. Dou,et al.  The effect of mechanical deformation on silver - core interface and critical current density in Ag - Bi-2223 single- and multifilament tapes , 1996 .

[6]  D. Larbalestier,et al.  Enhancement of the 77 K irreversibility field and critical current density of (Bi,Pb)2Sr2Ca 2Cu3Ox tapes by manipulation of the final cooling rate , 1996 .

[7]  S. Dou,et al.  Effect of (Pb, Bi)3Sr2Ca2CuOy phase on critical current density of Ag/(Bi, Pb)2Sr2Ca2Cu3O10 tapes , 1997 .

[8]  P. Haldar,et al.  Synchrotron x‐ray scattering measurements of bulk structural properties in superconducting (Bi,Pb)2Sr2Ca2Cu3O10–Ag tapes , 1996 .

[9]  G. Quirion,et al.  Rapid phase formation in Bi-2223/Ag superconducting tapes , 1995 .

[10]  S. Dou,et al.  Preparation of Ag - Bi-2223 tape by controlling the phase evolution prior to sintering , 1996 .

[11]  D. Larbalestier,et al.  Position-sensitive measurements of the local critical current density in Ag sheathed high-temperature superconductor (Bi, Pb)2Sr2Ca2Cu3Oy tapes: The importance of local micro- and macro-structure , 1994 .

[12]  D. Larbalestier,et al.  Evidence for preferential formation of the (Bi,Pb)2Sr2Ca2Cu3Ox phase at the Ag interface in Ag‐sheathed (Bi,Pb)2Sr2Ca2Cu3Ox tapes , 1993 .

[13]  Meiling Zhou,et al.  BiPbSrCaCuO superconductors prepared by the multiple pressing and sintering process , 1990 .

[14]  H. Kronmüller,et al.  Current capability of filaments depending on their position in (Bi,Pb)2Sr2Ca2Cu3O10+δ ‐multifilament tapes , 1996 .

[15]  H. Liu,et al.  Stability of high-Tc phase in Ag-clad Bi-based superconducting wires , 1992 .

[16]  P. Bodin,et al.  Influence of the powder calcination temperature on the microstructure in Bi(Pb)-2223 tapes , 1997, IEEE Transactions on Applied Superconductivity.

[17]  R. D. Blaugher,et al.  Superconducting Electric Power Applications , 1996 .

[18]  S. Dou,et al.  Effect of sintering temperature on phase composition and J/sub c/ of Ag-sheathed Bi-2223 single and multifilamentary tapes , 1997, IEEE Transactions on Applied Superconductivity.

[19]  S. Murase,et al.  Densification effect on the microstructure and critical current density in (Bi,Pb)2Sr2Ca2Cu3OxAg sheathed tape , 1994 .

[20]  H. Poulsen,et al.  Structural studies of BSCCO/Ag-tapes by high-energy synchrotron X-ray diffraction , 1998 .

[21]  J. Gannon,et al.  Advances in the design and fabrication of high-Tc composite conductors , 1994 .

[22]  S. Dou,et al.  Ag-sheathed Bi(Pb)SrCaCuO superconducting tapes , 1993 .