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A theoretical study of [M(PH3)4] (M = Ru or Fe), models for the highly reactive d8 intermediates [M(dmpe)2] (dmpe = Me2PCH2CH2PMe2). Zero activation energies for addition of CO and oxidative addition of H2‡
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R. Perutz
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O. Eisenstein
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S. Macgregor
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M. Whittlesey
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