Carrier localization in In-rich InGaN/GaN multiple quantum wells for green light-emitting diodes

Carrier localization phenomena in indium-rich InGaN/GaN multiple quantum wells (MQWs) grown on sapphire and GaN substrates were investigated. Temperature-dependent photoluminescence (PL) spectroscopy, ultraviolet near-field scanning optical microscopy (NSOM), and confocal time-resolved PL (TRPL) spectroscopy were employed to verify the correlation between carrier localization and crystal quality. From the spatially resolved PL measurements, we observed that the distribution and shape of luminescent clusters, which were known as an outcome of the carrier localization, are strongly affected by the crystalline quality. Spectroscopic analysis of the NSOM signal shows that carrier localization of MQWs with low crystalline quality is different from that of MQWs with high crystalline quality. This interrelation between carrier localization and crystal quality is well supported by confocal TRPL results.

[1]  Jeffrey Y. Tsao,et al.  Prospects for LED lighting , 2004, SPIE Optics + Photonics.

[2]  Jonathan J. Wierer,et al.  III -nitride photonic-crystal light-emitting diodes with high extraction efficiency , 2009 .

[3]  Ja-Yeon Kim,et al.  Green light-emitting diodes with self-assembled in-rich InGaN quantum dots , 2007 .

[4]  Jing Zhang,et al.  Efficiency-Droop Suppression by Using Large-Bandgap AlGaInN Thin Barrier Layers in InGaN Quantum-Well Light-Emitting Diodes , 2013, IEEE Photonics Journal.

[5]  Nelson Tansu,et al.  Approaches for high internal quantum efficiency green InGaN light-emitting diodes with large overlap quantum wells. , 2011, Optics express.

[6]  W. Shan,et al.  Temperature dependence of interband transitions in GaN grown by metalorganic chemical vapor deposition , 1995 .

[7]  Pallab Bhattacharya,et al.  InGaN/GaN self-organized quantum dot green light emitting diodes with reduced efficiency droop , 2010 .

[8]  D. Bour,et al.  Nitride-based semiconductors for blue and green light-emitting devices , 1997, Nature.

[9]  M. Reiche,et al.  Nitride semiconductors free of electrostatic fields for efficient white light-emitting diodes , 2000, Nature.

[10]  Y. Kotsar,et al.  Internal quantum efficiency of III-nitride quantum dot superlattices grown by plasma-assisted molecular-beam epitaxy , 2011 .

[11]  Shuji Nakamura,et al.  The Roles of Structural Imperfections in InGaN-Based Blue Light-Emitting Diodes and Laser Diodes , 1998 .

[12]  H. Fujioka,et al.  Fabrication of full-color InGaN-based light-emitting diodes on amorphous substrates by pulsed sputtering , 2014, Scientific Reports.

[13]  R. Horng,et al.  Defect reduction of laterally regrown GaN on GaN/patterned sapphire substrates , 2009 .

[14]  Isamu Akasaki,et al.  Crystal Growth and Conductivity Control of Group III Nitride Semiconductors and Their Application to Short Wavelength Light Emitters , 1997 .

[15]  Yen-Kuang Kuo,et al.  Enhancement in hole-injection efficiency of blue InGaN light-emitting diodes from reduced polarization by some specific designs for the electron blocking layer. , 2010, Optics letters.

[16]  Jen-Inn Chyi,et al.  Effect of composition inhomogeneity on the photoluminescence of InGaN/GaN multiple quantum wells upon thermal annealing , 2002 .

[17]  Jung Han,et al.  Low-Dislocation-Density GaN from a Single Growth on a Textured Substrate , 2000 .

[18]  S. Nunoue,et al.  InGaN Light-Emitting Diodes on c-Face Sapphire Substrates in Green Gap Spectral Range , 2013 .

[19]  Oliver Ambacher,et al.  Large Free-Standing GaN Substrates by Hydride Vapor Phase Epitaxy and Laser-Induced Liftoff , 1999 .

[20]  S. Dhar,et al.  Quantum-confined stark effect in localized luminescent centers within InGaN/GaN quantum-well based light emitting diodes , 2012 .

[21]  I. Krestnikov,et al.  Quantum dot origin of luminescence in InGaN-GaN structures , 2002 .

[22]  L. Lee,et al.  Room-temperature quantum-dot-like luminescence from site-controlled InGaN quantum disks , 2011 .

[23]  Asif Khan,et al.  Ultraviolet light-emitting diodes based on group three nitrides , 2008 .

[24]  R. Lin,et al.  Origins of efficient green light emission in phase-separated InGaN quantum wells , 2006 .

[25]  Noriaki Horiuchi,et al.  Light-emitting diodes: Natural white light , 2010 .

[26]  Grigory Simin,et al.  Indium-incorporation-induced transformation of optical, photoluminescence and lasing properties of InGaN epilayers , 2003 .

[27]  D. Clarke,et al.  MOSAIC STRUCTURE IN EPITAXIAL THIN FILMS HAVING LARGE LATTICE MISMATCH , 1997 .

[28]  Michael F. Shlesinger,et al.  FRACTAL TIME IN CONDENSED MATTER , 1988 .

[29]  F. H. Long,et al.  Time-resolved photoluminescence measurements of quantum dots in InGaN multiple quantum wells and light-emitting diodes , 1999 .

[30]  Yoichi Kawakami,et al.  Nanoscopic recombination processes in InGaN/GaN quantum wells emitting violet, blue, and green spectra , 2008 .

[31]  S. Mohammad,et al.  High-Luminosity Blue and Blue-Green Gallium Nitride Light-Emitting Diodes , 1995, Science.

[32]  Isamu Akasaki,et al.  Breakthroughs in Improving Crystal Quality of GaN and Invention of the p–n Junction Blue-Light-Emitting Diode , 2006 .

[33]  Y. S. Wu,et al.  Improved crystal quality and performance of GaN-based light-emitting diodes by decreasing the slanted angle of patterned sapphire , 2010 .

[34]  Friedhelm Bechstedt,et al.  Gap bowing and Stokes shift in InxGa1−xN alloys: First-principles studies , 2002 .

[35]  W. Lu,et al.  Indium segregation measured in InGaN quantum well layer , 2014, Scientific Reports.

[36]  Un Jeong Kim,et al.  Nearly single-crystalline GaN light-emitting diodes on amorphous glass substrates , 2011 .

[37]  Jong-In Shim,et al.  Nonradiative recombination mechanisms in InGaN/GaN-based light-emitting diodes investigated by temperature-dependent measurements , 2014 .

[38]  Yang Jiang,et al.  A novel wavelength-adjusting method in InGaN-based light-emitting diodes , 2013, Scientific Reports.

[39]  M. H. Crawford,et al.  Internal quantum efficiency and non-radiative recombination coefficient of GaInN/GaN multiple quantum wells with different dislocation densities , 2009, 2009 Conference on Lasers and Electro-Optics and 2009 Conference on Quantum electronics and Laser Science Conference.

[40]  Umesh K. Mishra,et al.  “S-shaped” temperature-dependent emission shift and carrier dynamics in InGaN/GaN multiple quantum wells , 1998 .

[41]  Manasreh Optical absorption near the band edge in GaN grown by metalorganic chemical-vapor deposition. , 1996, Physical review. B, Condensed matter.

[42]  Less strained and more efficient GaN light-emitting diodes with embedded silica hollow nanospheres , 2013, Scientific reports.

[43]  A. Yoshikawa,et al.  Bowing of the band gap pressure coefficient in InxGa1−xN alloys , 2008 .

[44]  Seong-Ju Park,et al.  Green Gap Spectral Range Light-Emitting Diodes with Self-Assembled InGaN Quantum Dots Formed by Enhanced Phase Separation , 2011 .

[45]  Robert W. Martin,et al.  Origin of Luminescence from InGaN Diodes , 1999 .

[46]  Yong-Hoon Cho,et al.  Ultrashort carrier lifetime of vapor–liquid–solid-grown GaN/InGaN multi-quantum-well coaxial nanorods , 2014 .

[47]  Christian Kisielowski,et al.  Local indium segregation and bang gap variations in high efficiency green light emitting InGaN/GaN diodes , 2006 .

[48]  Gerhard Fasol Room-Temperature Blue Gallium Nitride Laser Diode , 1996, Science.