Synthesis and characterization of terbium doped barium cerates as a proton conducting SOFC electrolyte

A novel proton conductor, BaCe0.95Tb0.05O3� a (BCTb) perovskite was synthesized via the EDTA-citrate acid complexing method, followed by high temperature calcination. The properties of the powders were characterized by thermo gravimetric-differential thermal analysis (TG-DTA), X-ray diffraction (XRD), Scanning electron microscopy (SEM) and the conductivity measurement using the 4-probe method. In order to obtain the pure perovskite structure, the calcination temperature was elevated at 1000 � C or greater. The elec

[1]  M. Cai,et al.  Preparation and hydrogen permeation of BaCe0.95Nd0.05O3−δ membranes , 2009 .

[2]  X. Tan,et al.  Nonoxidative Methane Coupling in a SrCe0.95Yb0.05O3-α (SCYb) Hollow Fiber Membrane Reactor , 2006 .

[3]  F. Chen,et al.  Novel BaCe0.7In0.2Yb0.1O3−δ proton conductor as electrolyte for intermediate temperature solid oxide fuel cells , 2011 .

[4]  G. Meng,et al.  Novel layered perovskite oxide PrBaCuCoO5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells , 2010 .

[5]  Xingjian Xue,et al.  A novel cobalt-free layered GdBaFe2O5+δ cathode for proton conducting solid oxide fuel cells , 2010 .

[6]  Wei Liu,et al.  A stable BaCeO3-based proton conductor for intermediate-temperature solid oxide fuel cells , 2010 .

[7]  Y. S. Lin,et al.  Electrical conducting properties of proton-conducting terbium-doped strontium cerate membrane , 1999 .

[8]  Qing Yang,et al.  Preparation via microemulsion method and proton conduction at intermediate-temperature of BaCe1−xYxO3−α , 2009 .

[9]  D. Dong,et al.  A new stable BaCeO3-based proton conductor for intermediate-temperature solid oxide fuel cells , 2009 .

[10]  H. Iwahara,et al.  Protonic conduction in Zr-substituted BaCeO3 , 2000 .

[11]  Y. S. Lin,et al.  Hydrogen permeation through terbium doped strontium cerate membranes enabled by presence of reducing gas in the downstream , 2009 .

[12]  Wei Liu,et al.  A novel anode supported BaCe0.4Zr0.3Sn0.1Y0.2O3−δ electrolyte membrane for proton conducting solid oxide fuel cells , 2008 .

[13]  H. Yahiro,et al.  Influence of microstructure of perovskite-type oxide cathodes on electrochemical performances of pro , 2011 .

[14]  Sun-Ju Song,et al.  Partial conductivities of mixed conducting BaCe0.65Zr0.2Y0.15O3–δ , 2010 .

[15]  K. Knight,et al.  Perovskite solid electrolytes: Structure, transport properties and fuel cell applications , 1995 .

[16]  Dense perovskite hollow fibre membranes , 2006 .

[17]  Yamato Asakura,et al.  Prospect of hydrogen technology using proton-conducting ceramics , 2004 .

[18]  H. Iwahara Proton conducting ceramics and their applications , 1996 .

[19]  X. Tan,et al.  Preparation and Oxygen Permeation Properties of Highly Asymmetric La0.6Sr0.4Co0.2Fe0.8O3−α Perovskite Hollow-Fiber Membranes , 2009 .

[20]  Q. Ma,et al.  Ceramic membrane fuel cells based on solid proton electrolytes , 2007 .

[21]  W. Liu,et al.  Indium as an ideal functional dopant for a proton-conducting solid oxide fuel cell , 2009 .

[22]  H. Iwahara,et al.  Hydrogen pumps using proton-conducting ceramics and their applications , 1999 .

[23]  X. Qi Electrical conduction and hydrogen permeation through mixed proton–electron conducting strontium cerate membranes , 2000 .

[24]  H. Iwahara,et al.  Technological challenges in the application of proton conducting ceramics , 1995 .

[25]  Emiliana Fabbri,et al.  Materials challenges toward proton-conducting oxide fuel cells: a critical review. , 2010, Chemical Society reviews.