Hydrogen separation from multicomponent gas mixtures containing CO, N2 and CO2 using Matrimid asymmetric hollow fiber membranes

The application of hollow fiber membranes for the separation of industrial gas mixtures relies on the correct characterization of the permeation of the involved gaseous components through the hollow fiber membranes. Thus, this study is focused on the characterization of the permeation through Matrimid® hollow fiber membranes of four gas mixtures containing H2 (H2/N2, H2/CO, H2/CO2), and the quaternary gas mixture H2/N2/CO/CO2, working at a constant temperature of 303 K and pressures up to 10 bar. The main differences and similarities in the gas permeation properties of hollow fibers with respect to flat membranes, as well as in the permeation of gas mixtures with respect to pure gases, are discussed. Our results suggest that for mixtures containing H2 and CO2 hollow fiber membranes perform better than flat membranes given that a lower depression in the permeability of H2 has been observed. At 2.3 bar feed pressure, ideal selectivity values obtained for H2/N2, H2/CO and H2/CO2 gas pairs were 74.4, 42.6 and 5 respectively, with a H2 permeance of 50.2×10−8 m3(STP) m−2 s−1 kPa−1. The specific behavior observed in the permeation through hollow fiber has been explained by a combination of different phenomena such as hollow fiber membrane substructure resistance, CO2 induced plasticization and competitive sorption effects between the components of the gaseous mixtures.

[1]  Matthias Wessling,et al.  CO2 sorption and transport behavior of ODPA-based polyetherimide polymer films , 2010 .

[2]  S. Nunes,et al.  Polyimide Asymmetric Membranes for Hydrogen Separation: Influence of Formation Conditions on Gas Transport Properties , 2006 .

[3]  T. Nenoff,et al.  Membranes for hydrogen separation. , 2007, Chemical reviews.

[4]  Seyed Saeid Hosseini,et al.  Gas separation membranes developed through integration of polymer blending and dual-layer hollow fiber spinning process for hydrogen and natural gas enrichments , 2010 .

[5]  B. Freeman,et al.  Transport of Gases and Vapors in Glassy and Rubbery Polymers , 2006 .

[6]  R. Baker Other Membrane Processes , 2004 .

[7]  Hans-Werner Rösler Membrantechnolgie in der Prozessindustrie – Polymere Membranwerkstoffe , 2005 .

[8]  Tai‐Shung Chung,et al.  Polymeric membranes for the hydrogen economy: Contemporary approaches and prospects for the future , 2009 .

[9]  E. Favvas,et al.  Characterization of highly selective microporous carbon hollow fiber membranes prepared from a commercial co-polyimide precursor , 2008 .

[10]  Separation of Hydrogen from Carbon Monoxide Using a Hollow Fiber Polyimide Membrane: Experimental and Simulation , 2007 .

[11]  C. F. Curtiss,et al.  Molecular Theory Of Gases And Liquids , 1954 .

[12]  Matthias Wessling,et al.  Accelerated plasticization of thin-film composite membranes used in gas separation , 2001 .

[13]  Yiming Cao,et al.  Effects of cross-linkers with different molecular weights in cross-linked Matrimid 5218 and test temperature on gas transport properties , 2008 .

[14]  John A. Turner,et al.  Sustainable Hydrogen Production , 2004, Science.

[15]  W. Koros,et al.  Morphology of integral-skin layers in hollow-fiber gas-separation membranes , 2003 .

[16]  W. Koros,et al.  A model for permeation of mixed gases and vapors in glassy polymers , 1981 .

[17]  R. Baker Membrane Technology and Applications , 1999 .

[18]  Kenji Haraya,et al.  Gas permeation and separation by an asymmetric polyimide hollow fiber membrane , 1989 .

[19]  C. Téllez,et al.  Mixed matrix membranes comprising glassy polymers and dispersed mesoporous silica spheres for gas separation , 2011 .

[20]  E. Drioli,et al.  On the unusual solvent retention and the effect on the gas transport in perfluorinated Hyflon AD® membranes , 2007 .

[21]  E. Favvas,et al.  Preparation, characterization and gas permeation properties of carbon hollow fiber membranes based on Matrimid® 5218 precursor , 2007 .

[22]  J. M. Henis,et al.  Composite Hollow Fiber Membranes for Gas Separation: The Resistance Model Approach , 1981 .

[23]  Matthias Wessling,et al.  Plasticization-resistant glassy polyimide membranes for CO2/CO4 separations , 1998 .

[24]  W. Koros,et al.  Characterization of substructure resistance in asymmetric gas separation membranes , 1999 .

[25]  J. Ferraris,et al.  Gas permeability properties of Matrimid® membranes containing the metal-organic framework Cu–BPY–HFS , 2008 .

[26]  I. Ortiz,et al.  Mixed gas separation study for the hydrogen recovery from H2/CO/N2/CO2 post combustion mixtures using a Matrimid membrane , 2011 .

[27]  Matthias Wessling,et al.  On the subtle balance between competitive sorption and plasticization effects in asymmetric hollow fiber gas separation membranes , 2005 .

[28]  S. C. Kumbharkar,et al.  High performance polybenzimidazole based asymmetric hollow fibre membranes for H 2/CO 2 separation , 2011 .

[29]  W. Koros,et al.  Thickness‐dependent sorption and effects of physical aging in a polyimide sample , 2005 .

[30]  Matthias Wessling,et al.  CO2-induced plasticization phenomena in glassy polymers , 1999 .

[31]  I. Pinnau,et al.  Relationship between substructure resistance and gas separation properties of defect-free integrally skinned asymmetric membranes , 1991 .

[32]  Yiming Cao,et al.  Gas permeation performance of cellulose hollow fiber membranes made from the cellulose/N-methylmorpholine-N-oxide/H2O system , 2004 .

[33]  I. Ortiz,et al.  On the improved absorption of carbon monoxide in the ionic liquid 1-hexyl-3-methylimidazolium chlorocuprate , 2012 .

[34]  Vicki Chen,et al.  Factors affect defect-free Matrimid® hollow fiber gas separation performance in natural gas purification , 2010 .

[35]  W. Koros,et al.  Antiplasticization and plasticization of Matrimid® asymmetric hollow fiber membranes—Part A. Experimental , 2010 .

[36]  K. Nagai,et al.  Polymer Membranes for Hydrogen Separations , 2006 .

[37]  Tai‐Shung Chung,et al.  Hydrogen separation and purification in membranes of miscible polymer blends with interpenetration networks , 2008 .

[38]  Marcel Mulder,et al.  Basic Principles of Membrane Technology , 1991 .

[39]  William J. Koros,et al.  Formation of defect-free polyimide hollow fiber membranes for gas separations , 2000 .

[40]  Takeshi Matsuura,et al.  Synthetic Membranes and Membrane Separation Processes , 1993 .

[41]  G. Koops,et al.  High flux polyethersulfone-polyimide blend hollow fiber membranes for gas separation , 2002 .

[42]  Matthias Wessling,et al.  Materials dependence of mixed gas plasticization behavior in asymmetric membranes , 2007 .

[43]  Matthias Wessling,et al.  Auto and mutual plasticization in single and mixed gas C3 transport through Matrimid-based hollow fiber membranes , 2008 .