Preparation and thermal performance of gypsum boards incorporated with microencapsulated phase change materials for thermal regulation

Abstract The application of phase change materials (PCMs) for solar thermal-energy storage has received considerable attention in recent years due to their high storage density. A series of microencapsulated PCMs (micro-PCMs) with good phase change behavior have been synthesized through in-situ polymerization and the applications of the obtained micro-PCMs in thermal regulation of gypsum boards are presented in this study. Scanning electron microscope images reveal that the micro-PCMs were dispersed homogeneously in the gypsum boards. Differential scanning calorimeter results show that all the gypsum boards with different weight percentages of the micro-PCMs possess good phase change behavior. The melting and freezing temperatures as well as the latent heat of the gypsum board with 50 wt% or 60 wt% micro-PCMs and 3 wt% glass fibers are quite suitable for the potential thermal energy storage of building applications. Thermal cycling tests indicate that the gypsum board with micro-PCMs maintains excellent thermal reliability after 60 melting–freezing cycles. Furthermore, the gypsum boards with micro-PCMs show a good thermal-regulated property. The temperature of the board incorporated with 60 wt% micro-PCMs can be kept in the rage of 22–27 °C for about 1735 s due to the phase change of the inside micro-PCMs. In addition, the thermal-regulated gypsum boards achieve good thermal stability, high thermal capacity and thermal conductivity, especially for the sample incorporated with 50 wt% micro-PCMs. From the above results, it can be concluded that the gypsum boards incorporated with 50 wt% micro-PCMs have a good potential for thermal energy storage purpose in buildings.

[1]  Xiaodong Wang,et al.  Fabrication and performances of microencapsulated phase change materials based on n-octadecane core and resorcinol-modified melamine–formaldehyde shell , 2009 .

[2]  P. Xue,et al.  Micro-encapsulated paraffin/high-density polyethylene/wood flour composite as form-stable phase change material for thermal energy storage , 2009 .

[3]  M. Sanchez,et al.  Thermal testing and numerical simulation of gypsum wallboards incorporated with different PCMs content , 2011 .

[4]  F. Kuznik,et al.  Experimental assessment of a phase change material for wall building use , 2009 .

[5]  Xingrong Zeng,et al.  Preparation, characterization and thermal properties of nanocapsules containing phase change material n-dodecanol by miniemulsion polymerization with polymerizable emulsifier , 2012 .

[6]  Yi Jiang,et al.  Thermal storage and nonlinear heat-transfer characteristics of PCM wallboard , 2008 .

[7]  Frédéric Kuznik,et al.  A review on phase change materials integrated in building walls , 2011 .

[8]  Zongjin Li,et al.  Development of thermal energy storage concrete , 2004 .

[9]  J. Kenar,et al.  Latent heat characteristics of biobased oleochemical carbonates as potential phase change materials , 2010 .

[10]  G. Song,et al.  Preparation and characterization of flame retardant form-stable phase change materials composed by EPDM, paraffin and nano magnesium hydroxide , 2010 .

[11]  Dong Zhang,et al.  Experimental study on the phase change behavior of phase change material confined in pores , 2007 .

[12]  Wei Li,et al.  Fabrication and characterization of microencapsulated n-octadecane with different crosslinked methylmethacrylate-based polymer shells , 2012 .

[13]  Luisa F. Cabeza,et al.  Use of microencapsulated PCM in buildings and the effect of adding awnings , 2012 .

[14]  Mario A. Medina,et al.  Development of a thermally enhanced frame wall with phase‐change materials for on‐peak air conditioning demand reduction and energy savings in residential buildings , 2005 .

[15]  M. Hawlader,et al.  Microencapsulated PCM thermal-energy storage system , 2003 .

[16]  R. Velraj,et al.  Phase change material-based building architecture for thermal management in residential and commercial establishments , 2008 .

[17]  Hui Chen,et al.  Preparation of phase change materials microcapsules by using PMMA network‐silica hybrid shell via sol‐gel process , 2009 .

[18]  Mohammed M. Farid,et al.  A Review on Energy Conservation in Building Applications with Thermal Storage by Latent Heat Using Phase Change Materials , 2021, Thermal Energy Storage with Phase Change Materials.

[19]  A. Aydin,et al.  High-chain fatty acid esters of 1-hexadecanol for low temperature thermal energy storage with phase change materials , 2012 .

[20]  D. Bentz,et al.  Potential applications of phase change materials in concrete technology , 2007 .

[21]  Li-jiu Wang,et al.  Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage , 2010 .

[22]  S. C. Kaushik,et al.  DEVELOPMENT OF PHASE CHANGE MATERIALS BASED MICROENCAPSULATED TECHNOLOGY FOR BUILDINGS: A REVIEW , 2011 .