Coating of a lignocellulosic aggregate with pectin/polyethylenimin mixtures: Effects on flax shive and cement-shive composite properties

Abstract Lignocellulosic lightweight concretes are a potential contributor to sustainable development. However, lignocellulosic aggregates are not always fully compatible with cement matrices leading to setting delays, significant dimensional variations and low mechanical strengths. An aggregate treatment, reducing water absorption and water-soluble molecule release, can avoid or reduce these drawbacks. In this study a coating treatment, using a pectin/polyethylenimin (PP) mixture, was applied to flax shives, which is a lignocellulosic by-product. Before shive coating, a dilution with distilled water or a micro-wave heating were conducted to decrease PP mixture viscosity. The PP treatment involved a decrease in shive water absorption. Compared to standard shive concrete, treated shive concrete exhibited a decrease in setting delay with an increase in cement hydration enthalpy, an increase in mechanical strengths and a significant reduction in dimensional variations. Although a slight increase in thermal conductivity and bulk density was measured, the cement-shive composite obtained still belongs to the insulating concrete category.

[1]  M. Bederina,et al.  Effect of the addition of wood shavings on thermal conductivity of sand concretes: Experimental study and modelling , 2007 .

[2]  A. Ouensanga,et al.  Sugar cane bagasse fibre reinforced cement composites. Part I. Influence of the botanical components of bagasse on the setting of bagasse/cement composite , 2003 .

[3]  Frank Rendell,et al.  Lightweight wood chipping concrete durability , 2006 .

[4]  R. Dheilly,et al.  Reuse of waste oils in the treatment of wood aggregates , 2000 .

[5]  B. M. Suleiman,et al.  The transient plane source technique : experimental design criteria , 1991 .

[6]  R. Dheilly,et al.  Influence of sucrose addition on the performance of a lignocellulosic composite with a cementious matrix , 2008 .

[7]  A. Olorunnisola Effects of husk particle size and calcium chloride on strength and sorption properties of coconut husk–cement composites , 2009 .

[8]  R. Dheilly,et al.  Effects of aggregate coating on the hygral properties of lignocellulosic composites , 2011 .

[9]  T. Vuorinen,et al.  Thermal Modifications in Softwood Studied by FT‐IR and UV Resonance Raman Spectroscopies , 2005 .

[10]  Fadhel Aouadi,et al.  Cement-bonded straw board subjected to accelerated processing , 2004 .

[11]  B. Dupré Contribution à la valorisation des coproduits du lin : impact du vécu et de la variabilité génétique sur les propriétés des composites élaborés , 2005 .

[12]  G. Zacchi,et al.  Isolation and characterization of water-soluble hemicelluloses from flax shive. , 2003, Carbohydrate research.

[13]  Cristina Becchio,et al.  Improving environmental sustainability of concrete products: Investigation on MWC thermal and mechanical properties , 2009 .

[14]  B. Ridley,et al.  Pectins: structure, biosynthesis, and oligogalacturonide-related signaling. , 2001, Phytochemistry.

[15]  Etienne Wurtz,et al.  Transient hygrothermal behaviour of a hemp concrete building envelope , 2010 .

[16]  V. Lužáková,et al.  Role of surface charge in deposition of filler particles onto pulp fibres , 1998 .

[17]  A. Pizzi,et al.  Durability of heat-treated wood , 2002, Holz als Roh- und Werkstoff.

[18]  C. Ganapathy,et al.  Lightweight concrete made from oil palm shell (OPS): Structural bond and durability properties , 2007 .

[19]  M. Bederina,et al.  Effect of the treatment of wood shavings on the physico-mechanical characteristics of wood sand concretes , 2009 .

[20]  R. Dheilly,et al.  Impact of aggregate coating with a PEC elastomer on properties of lightweight flax shive concrete , 2011 .

[21]  L. Aggarwal,et al.  Bagasse-reinforced cement composites , 1995 .

[22]  C. Pagnoux,et al.  Interaction fibre de chanvre/ciment: influence sur les propriétés mécaniques du composite , 2007 .