Design of a permanent magnet with a mechanical sweep suitable for variable-temperature continuous-wave and pulsed EPR spectroscopy.

A magnetic system is introduced which consists of three nested rings of permanent magnets of a Halbach dipolar layout and is capable for EPR spectroscopy. Two of the rings can be rotated independently to adjust the magnetic flux in the center and even allow for mechanical field sweeps. The presented prototype achieves a magnetic flux range of 0.0282-0.3013T with a minimal sweep of 0.15mT and homogeneity of about 10(-3). First applications with CW and pulsed Mims ENDOR as well as ESEEM experiments on a sample of a glycine single crystal doped with 1% copper nitrate demonstrate that flux range, sweep accuracy and homogeneity of this prototype is sufficient for EPR experiments on most solid samples. Together with a recently improved design magnets can be build which could serve as compact and easily transportable replacement of standard electromagnets with negligible consumption of power or coolants.

[1]  Gunnar Jeschke,et al.  Distance measurements in the nanometer range by pulse EPR. , 2002, Chemphyschem : a European journal of chemical physics and physical chemistry.

[2]  M. Ikeya,et al.  A portable spectrometer for ESR microscopy, dosimetry and dating , 1989 .

[3]  Gunnar Jeschke,et al.  Principles of pulse electron paramagnetic resonance , 2001 .

[4]  A. Furuse,et al.  Portable ESR Spectrometer with Neomax (NdFeB) permanent magnet circuit , 1993 .

[5]  C. Mcdowell,et al.  Ligand ENDOR spectra of Cu(II) impurity complexes in α‐glycine crystals , 1979 .

[6]  Torque in nested Halbach cylinders , 1999, IEEE International Magnetics Conference.

[7]  A. Milov,et al.  Pulsed electron double resonance (PELDOR) and its applications in free-radicals research , 1998 .

[8]  E. Danieli,et al.  Mobile sensor for high resolution NMR spectroscopy and imaging. , 2009, Journal of magnetic resonance.

[9]  Hans-Peter Raich,et al.  Design and construction of a dipolar Halbach array with a homogeneous field from identical bar magnets: NMR Mandhalas , 2004 .

[10]  K. Halbach Design of permanent multipole magnets with oriented rare earth cobalt material , 1980 .

[11]  Klaus Halbach,et al.  Strong Rare Earth Cobalt Quadrupoles , 2010, IEEE Transactions on Nuclear Science.

[12]  Richard L. Magin,et al.  Miniature permanent magnet for table‐top NMR , 2003 .

[13]  M. Ikeya,et al.  An Electron Spin Resonance System for In-vivo Human Tooth Dosimetry , 1990 .

[14]  Y. Shin,et al.  Determination of the distance between two spin labels attached to a macromolecule. , 1995, Proceedings of the National Academy of Sciences of the United States of America.

[15]  Y. Yamamoto,et al.  Development of portable ESR spectrometer as a reader for alanine dosimeters , 1993 .

[16]  M. Abele,et al.  Applications of yokeless flux confinement , 1988 .

[17]  J. Mallinson One-sided fluxes -- A magnetic curiosity? , 1973 .

[18]  T. Prisner,et al.  Long-range distance determinations in biomacromolecules by EPR spectroscopy , 2007, Quarterly Reviews of Biophysics.

[19]  Brandon D Armstrong,et al.  Portable X-band system for solution state dynamic nuclear polarization. , 2008, Journal of magnetic resonance.

[20]  G. Jeschke,et al.  Distance measurements on spin-labelled biomacromolecules by pulsed electron paramagnetic resonance. , 2007, Physical chemistry chemical physics : PCCP.