Blue-Hazard-Free Organic Light-Emitting Diode with a Lifetime Greater than 200,000 h

Blue-hazard-free lighting is in urgent need in order to protect human eyes and physiology. A candlelight-style organic light emitting diode (OLED) is so far the safest measure for its blue-hazard-free, low-color-temperature illumination. However, lifetime is still the most critical reliability issue in OLEDs, especially in lighting applications that are closely associated with high current density operation. Here, we present a novel approach to develop blue-hazard-free OLEDs with a lifetime exceeding 200,000 h at 1000 cd/m2 by employing a tandem structure with ultra-high purity emitter. The resultant device shows a current efficacy of 37.4 cd/A, an external quantum efficiency (EQE) of 22.7%, an 80 CRI, and a 78 SRI with a 223,500 h lifetime (t50). Additionally, the resultant device also exhibits a long retina exposure duration of 12,300 s (3.42 h) and suppresses very less melatonin generation (1.7%), demonstrating that the fabricated OLED device is a highly prospective general lighting source to safeguard human health.

[1]  Yanfeng Dai,et al.  Low color-temperature, high color rendering index hybrid white organic light-emitting diodes by the effective control of exciton recombination zone , 2017 .

[2]  J. Kido,et al.  High‐Performance Green OLEDs Using Thermally Activated Delayed Fluorescence with a Power Efficiency of over 100 lm W−1 , 2016, Advanced materials.

[3]  Lianqiao Yang,et al.  Extremely low color‐temperature white organic electroluminescence devices based on the control of exciton recombination zone , 2016 .

[4]  K. Leo,et al.  Degradation Mechanisms and Reactions in Organic Light-Emitting Devices. , 2015, Chemical reviews.

[5]  J. Jou,et al.  Pseudo‐natural Light for Displays and Lighting , 2015 .

[6]  Junbiao Peng,et al.  Efficient hybrid white organic light-emitting diodes with extremely long lifetime: the effect of n-type interlayer , 2014, Scientific Reports.

[7]  Dongge Ma,et al.  Hybrid Organic Light-Emitting Diodes with Low Color-Temperature and High Efficiency for Physiologically-Friendly Night Illumination , 2014 .

[8]  H. Hara,et al.  Damage of photoreceptor-derived cells in culture induced by light emitting diode-derived blue light , 2014, Scientific Reports.

[9]  Ken-Tsung Wong,et al.  A universal, easy-to-apply light-quality index based on natural light spectrum resemblance , 2014 .

[10]  G. Brainard,et al.  Breast cancer and circadian disruption from electric lighting in the modern world , 2014, CA: a cancer journal for clinicians.

[11]  Jwo-Huei Jou,et al.  Candle Light‐Style Organic Light‐Emitting Diodes , 2013 .

[12]  Ching‐Wu Wang,et al.  Organic light-emitting diode-based plausibly physiologically-friendly low color-temperature night light , 2012 .

[13]  P. Blom,et al.  Device Physics of White Polymer Light‐Emitting Diodes , 2012 .

[14]  Ching‐Wu Wang,et al.  High efficiency low color-temperature organic light-emitting diodes with a blend interlayer , 2011 .

[15]  Min-Koo Han,et al.  Flexible OLEDs and organic electronics , 2011 .

[16]  Jwo-Huei Jou,et al.  Sunlight-style color-temperature tunable organic light-emitting diode , 2009 .

[17]  Gregor Schwartz,et al.  White organic light-emitting diodes with fluorescent tube efficiency , 2009, Nature.

[18]  Kian Soo Ong,et al.  Flexible top-emitting electroluminescent devices on polyethylene terephthalate substrates , 2005 .

[19]  L. Hung,et al.  High-contrast organic light-emitting diodes , 2004 .

[20]  Yoshio Taniguchi,et al.  Dynamic turn-on behavior of organic light-emitting devices with different work function cathode metals under fast pulse excitation , 2003 .

[21]  J. Arendt Melatonin, circadian rhythms, and sleep. , 2000, The New England journal of medicine.

[22]  T. Williams,et al.  Photoreversal of Rhodopsin Bleaching , 1964, The Journal of general physiology.

[23]  S. M. Pauley Lighting for the human circadian clock: recent research indicates that lighting has become a public health issue. , 2004, Medical hypotheses.

[24]  Bruce E. Stuck,et al.  Guidelines on limits of exposure to ultraviolet radiation of wavelengths between 180 nm and 400 nm (incoherent optical radiation). , 2004, Health physics.