RhCl(PPh3)3/NaI Catalyst System for Hydrosilylation of 1-Alkynes: Stereodivergent Syntheses of E- and Z-Alkenylsilanes with Heteroatom Substituents on Silicon

Both (E)- and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

[1]  T. Hiyama,et al.  Synthesis of cyclopropylsilanols by the Simmons-Smith reaction of alkenylsilanols and lithium alkenylsilanolates , 1997 .

[2]  T. Ikariya,et al.  An Efficient Rhodium(I) Initiator for Stereospecific Living Polymerization of Phenylacetylenes , 1996 .

[3]  R. Takeuchi,et al.  A Selective Synthesis of (E)-Vinylsilanes by Cationic Rhodium Complex-Catalyzed Hydrosilylation of 1-Alkynes and Tandem Hydrosilylation/Isomerization Reaction of Propargylic Alcohols to .beta.-Silyl Ketones , 1995 .

[4]  T. Hiyama,et al.  Palladium-catalyzed cross-coupling reaction of organometalloids through activation with fluoride ion , 1994 .

[5]  M. Doyle,et al.  RHODIUM(II) PERFLUOROBUTYRATE CATALYZED HYDROSILYLATION OF 1-ALKYNES. TRANS ADDITION AND REARRANGEMENT TO ALLYLSILANES , 1991 .

[6]  I. Ojima,et al.  Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition , 1990 .

[7]  K. Yokota,et al.  Polymerization of m-Chlorophenylacetylene Initiated by [Rh(norbornadiene)Cl]2-Triethylamine Catalyst Containing Long-Lived Propagation Species , 1990 .

[8]  T. Fujisawa,et al.  Optically Active Sulfoxides as Ferroelectric Liquid Crystals and Chiral Dopants for Them , 1990 .

[9]  K. Tamao,et al.  Palladium-catalyzed cross-coupling reaction of alkenylalkoxysilanes with aryl and alkenyl halides in the presence of a fluoride ion , 1989 .

[10]  P. Hitchcock,et al.  A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)] , 1987 .

[11]  Tatsuo Tanaka,et al.  Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes , 1983 .

[12]  F. Hartley,et al.  The preparation of cis- and trans-[RhI(CO)(PAr3)2] (Ar= Aryl) and their ready dissociation in solution , 1983 .

[13]  J. Yoshida,et al.  Organofluorosilicates in organic synthesis. 1. A novel general and practical method for anti-Markownikoff hydrohalogenation of olefins via organopentafluorosilicates derived from hydrosilylation products , 1978 .