State‐of‐the‐Art of Advanced Distillation Technologies in China

Focusing on energy conservation and process intensification, a comprehensive overview of advanced distillation technologies in the past four decades in China is presented. Novel trays, packings, and gas and liquid distributors based on the fundamentals of such technologies are described. Hybrid distillation and distillation assisted by an external force field on the basis of process intensification principles like reactive distillation, extractive distillation, Higee technology, microwave-assisted distillation, etc. are reported. Energy-saving technologies such as dividing-wall column and internally heat integrated distillation column together with some important examples regarding the industrial application of advanced distillation technologies are evaluated. As a guide to develop distillation processes, a green distillation concept is proposed. Future perspectives of distillation techniques in China are indicated.

[1]  Benshuai Guo,et al.  Analysis and simulation of reactive distillation for gasoline alkylation desulfurization , 2012 .

[2]  Kejin Huang,et al.  A Simplified Scheme of Externally Heat-Integrated Double Distillation Columns (EHIDDiC) with Three External Heat Exchangers , 2010 .

[3]  Ting Qiu,et al.  Study on Feasibility of Reactive Distillation Process for the Direct Hydration of Cyclohexene to Cyclohexanol Using a Cosolvent , 2013 .

[4]  Wang Chenchen,et al.  Liquid flow behavior study in SiC foam corrugated sheet using a novel ultraviolet fluorescence technique coupled with CFD simulation , 2015 .

[5]  Songlin Xu,et al.  A new entrainer for separation of tetrahydrofuran–water azeotropic mixture by extractive distillation , 2006 .

[6]  Zhigang Lei,et al.  Influence of salt added to solvent on extractive distillation , 2002 .

[7]  D. Zhang,et al.  Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids , 2008 .

[8]  Li Xiao,et al.  Novel Procedure for Production of Isopropanol by Transesterification of Isopropyl Acetate with Reactive Distillation , 2014 .

[9]  Kejin Huang,et al.  Operation of Dividing-Wall Distillation Columns. 2. A Double Temperature Difference Control Scheme , 2013 .

[10]  Miguel J. Bagajewicz,et al.  Mass/heat‐exchange network representation of distillation networks , 1992 .

[11]  Xingang Li,et al.  Pressure Drop Models of Seepage Catalytic Packing Internal for Catalytic Distillation Column , 2012 .

[12]  Guohua Gao,et al.  Hydrodynamic and Mass Transfer Performances of a New SiC Foam Column Tray , 2012 .

[13]  Bolun Yang,et al.  Multi-fields synergy in the process of reactive distillation coupled with membrane separation , 2005 .

[14]  A. Tsutsumi,et al.  Towards further internal heat integration in design of reactive distillation columns—part I: The design principle , 2005 .

[15]  Zhibao Li,et al.  A new process for fuel ethanol dehydration based on modeling the phase equilibria of the anhydrous MgCl2 + ethanol + water system , 2015 .

[16]  Guang Q. Wang,et al.  Performance of a rotating zigzag bed—A new HIGEE , 2008 .

[17]  Xun Huang,et al.  Reactive Distillation Column for Disproportionation of Trichlorosilane to Silane: Reducing Refrigeration Load with Intermediate Condensers , 2013 .

[18]  Qian Liu,et al.  Separation of bio-oil by molecular distillation , 2009 .

[19]  Ying Wang,et al.  Distillation in a Counterflow Concentric-Ring Rotating Bed , 2014 .

[20]  Peng Bai,et al.  New Operation Strategy for Separation of Ethanol–Water by Extractive Distillation , 2012 .

[21]  Hui Zhang,et al.  Hydrodynamic Simulations of Seepage Catalytic Packing Internal for Catalytic Distillation Column , 2012 .

[22]  Jun Hong Liu,et al.  Design and control of acetic acid dehydration system via heterogeneous azeotropic distillation , 2004 .

[23]  Xiuping Li,et al.  Continuous Distillation Experiment with Rotating Packed Bed , 2008 .

[24]  Jun Chen,et al.  Application of Mechanical Vapor Recompression Heat Pump to Double-Effect Distillation for Separating N,N-Dimethylacetamide/Water Mixture , 2015 .

[25]  Jinghai Li,et al.  Multiscale Discrete Supercomputing – A Game Changer for Process Simulation? , 2015 .

[26]  Weimin Zhang,et al.  One-Pot Spray-Dried Graphene Sheets-Encapsulated Nano-Li4Ti5O12 Microspheres for a Hybrid BatCap System , 2014 .

[27]  Shengjun Zhang,et al.  Experimental investigation of moderately high temperature water source heat pump with non-azeotropic refrigerant mixtures , 2010 .

[28]  San-Jang Wang,et al.  Control of a high‐purity ethylene glycol reactive distillation column with insights of process dynamics , 2009 .

[29]  Furong Gao,et al.  Control and Profile Setting of Reactive Distillation Column for Benzene Chloride Consecutive Reaction System , 2013 .

[30]  Kejin Huang,et al.  A fundamental principle and systematic procedures for process intensification in reactive distillation columns , 2010 .

[31]  Jianbing Qian,et al.  High-powered adaptive valve tray : A new generation tray offers new advantages , 2006 .

[32]  Zhiwen Qi,et al.  Analysis of intensification mechanism of auxiliary reaction on reactive distillation: Methyl acetate hydrolysis process as example , 2014 .

[33]  San-Jang Wang,et al.  Design and Analysis of Internally Heat-Integrated Reactive Distillation Processes , 2012 .

[34]  Liu Xuejun,et al.  Liquid Entrainment and Flooding in a Rotating Zigzag Bed , 2015 .

[35]  S. Xu,et al.  Separation of tetrahydrofuran-water azeotropic mixture by batch extractive distillation process , 2006 .

[36]  Lanyi Sun,et al.  Shortcut Method for the Design of Reactive Dividing Wall Column , 2014 .

[37]  Xiao Feng,et al.  A novel multi-effect methanol distillation process , 2010 .

[38]  Yiqing Luo,et al.  Reversibility Analysis for Design Optimization of an Internally Heat‐Integrated Distillation Column , 2013 .

[39]  Kejin Huang,et al.  Externally Heat-Integrated Double Distillation Column (EHIDDiC): Basic Concept and General Characteristics , 2010 .

[40]  Shiqing Lu,et al.  Dynamic control analysis for manufacturing ethanol fuel via reactive distillation , 2011 .

[41]  Chunjian Xu,et al.  Design and Control of Extractive Dividing-Wall Column for Separating Methylal–Methanol Mixture , 2012 .

[42]  Xingang Li,et al.  Liquid Flow Behavior of a Seepage Catalytic Packing Internal for Catalytic Distillation Column , 2014 .

[43]  Zhixian Gao,et al.  Synthesis of High‐Purity Methylal via Extractive Catalytic Distillation , 2012 .

[44]  Kejin Huang,et al.  Employing Top–Bottom Recycled Reactive Distillation to the Separations of Adipic Acid and Glutaric Acid Esterifications , 2013 .

[45]  Zhiwen Qi,et al.  Alkylation of Benzene with Ethylene in a Packed Reactive Distillation Column , 2004 .

[46]  Shaotong Jiang,et al.  Optimization of Molecular Distillation for Recovery of Tocopherol from Rapeseed Oil Deodorizer Distillate Using Response Surface and Artificial Neural Network Models , 2007 .

[47]  Jinsheng Sun,et al.  Modeling fixed triangular valve tray hydraulics using computational fluid dynamics , 2012 .

[48]  Weijiang Zhang,et al.  Design, Optimization and Control of Extractive Distillation for the Separation of Trimethyl Borate–Methanol , 2014 .

[49]  Yingxia Li,et al.  Monolith catalysts for the alkylation of benzene with propylene , 2013 .

[50]  Chunjian Xu,et al.  Design and Control of Distillation System for Methylal/Methanol Separation. Part 1: Extractive Distillation Using DMF as an Entrainer , 2012 .

[51]  Jiwei Qin,et al.  Design and control of reactive distillation–recovery distillation flowsheet with a decanter for synthesis of N-propyl propionate , 2014 .

[52]  J. Gao,et al.  Investigation of ethyl lactate reactive distillation process , 2007 .

[53]  Guang Q. Wang,et al.  A New Crossflow Rotating Bed, Part 2: Structure Optimization , 2014 .

[54]  Wei Chen,et al.  Circumventing the Black-Hole Problem in Design and Control of Dividing-Wall Distillation Columns , 2012 .

[55]  Qunxiong Zhu,et al.  A totally heat-integrated distillation column (THIDiC) – the effect of feed pre-heating by distillate , 2008 .

[56]  Yong Jin,et al.  Characteristics of the reactive distillation column with a novel internal , 2002 .

[57]  Chi Wai Hui,et al.  Energy Optimization for a Multistage Crude Oil Distillation Process , 2015 .

[58]  Guang Q. Wang,et al.  Progress on Higee distillation—Introduction to a new device and its industrial applications , 2011 .

[59]  Hsiao-Ping Huang,et al.  A Simple Multiloop Tuning Method for PID Controllers with No Proportional Kick , 1999 .

[60]  Yang Yuan,et al.  Operation of Dividing-Wall Distillation Columns. 3. A Simplified Double Temperature Difference Control Scheme , 2014 .

[61]  Guang Q. Wang,et al.  Studies on Performance of Crossflow Concentric-Ring Rotating Bed , 2009 .

[62]  Qian Liu,et al.  Pyrolysis characteristics of bio-oil fractions separated by molecular distillation , 2010 .

[63]  Hao Yu,et al.  Design and Control of Dividing-Wall Column for the Synthesis of n-Propyl Propionate by Reactive Distillation , 2015 .

[64]  Zhongliang Liu,et al.  Experimental study on a new method for improving the performance of thermal vapor compressors for multi-effect distillation desalination systems , 2014 .

[65]  Qunsheng Li,et al.  Modeling Flow-Guided Sieve Tray Hydraulics Using Computational Fluid Dynamics , 2014 .

[66]  Yong Jin,et al.  Liquid Holdup for Two-Phase Countercurrent Flow in the Packed Column with a Novel Internal , 2002 .

[67]  Pengfei Liu,et al.  Hydrodynamics and Mass-Transfer Analysis of a Distillation Ripple Tray by Computational Fluid Dynamics Simulation , 2013 .

[68]  Yong Jin,et al.  Mass transfer coefficient for two-phase countercurrent flow in a packed column with a novel internal , 2004 .

[69]  Xinggao Liu,et al.  Investigating Control Schemes for an Ideal Thermally Coupled Distillation Column (ITCDIC) , 2005 .

[70]  Liang Chang,et al.  Modeling, Characteristic Analysis, and Optimization of Ideal Internal Thermally Coupled Air Separation Columns , 2012 .

[71]  Kejin Huang,et al.  Operation of Dividing-Wall Columns. 1. A Simplified Temperature Difference Control Scheme , 2013 .

[72]  X. G. Yuan,et al.  A modified model of computational mass transfer for distillation column , 2007 .

[73]  Jie Zhang,et al.  Simulation of structured catalytic packings in a bubble-point reactor , 2013 .

[74]  Zhigang Lei,et al.  Extractive Distillation: A Review , 2003 .

[75]  Pan Lijun,et al.  Design and control of reactive distillation for hydrolysis of methyl lactate , 2011 .

[76]  Xigang Yuan,et al.  Comparison between Different Configurations of Internally and Externally Heat-Integrated Distillation by Numerical Simulation , 2013 .

[77]  T. Qiu,et al.  Novel Procedure for Coproduction of Ethyl Acetate and n-Butyl Acetate by Reactive Distillation , 2012 .

[78]  Jun Chen,et al.  Simulation and Optimization of Distillation Processes for Separating a Close-Boiling Mixture of n-Butanol and Isobutanol , 2014 .

[79]  Gongpin Liu,et al.  Novel Reactive Distillation–Pervaporation Coupled Process for Ethyl Acetate Production with Water Removal from Reboiler and Acetic Acid Recycle , 2012 .

[80]  Kejin Huang,et al.  Avoiding the Black-Hole Problem by the Arrangements of Multiple Intermediate Products to Dividing-Wall Distillation Columns , 2013 .

[81]  Wangfeng Cai,et al.  Design and Control of Extraction Distillation for Dehydration of Tetrahydrofuran , 2013 .

[82]  Jun Li,et al.  Design of Catalytic Divided Wall Column , 2011 .

[83]  Atsushi Tsutsumi,et al.  Towards further internal heat integration in design of reactive distillation columns—Part II. The process dynamics and operation , 2006 .

[84]  Guang Q. Wang,et al.  New HIGEE-Rotating Zigzag Bed and Its Mass Transfer Performance , 2008 .

[85]  Hu-Lin Li,et al.  Computational Fluid Dynamics Simulation of 13CO Distillation in Structured Packing , 2012 .

[86]  Guo Tao,et al.  Performance comparison and parametric optimization of subcritical Organic Rankine Cycle (ORC) and transcritical power cycle system for low-temperature geothermal power generation , 2011 .

[87]  Jiquan Fu,et al.  Simulation of salt-containing extractive distillation for the system of ethanol/water/ethanediol/KAc. 1. Calculation of the vapor-liquid equilibrium for the salt-containing system , 2004 .

[88]  San-Jang Wang,et al.  Towards further internal heat integration in design of reactive distillation columns—Part III: Application to a MTBE reactive distillation column , 2008 .

[89]  Xiaosong Hu,et al.  Purification process of octacosanol extracts from rice bran wax by molecular distillation , 2007 .

[90]  Guohua Gao,et al.  Multiscale Simulation and Experimental Study of Novel SiC Structured Packings , 2012 .

[91]  Chunli Li,et al.  Separation of Ethyl Acetate‐Dichloromethane‐Ethanol by Extractive Distillation: Simulation and Optimization , 2013 .

[92]  Hao Yu,et al.  Design and Control of Dividing-Wall Column for tert-Butanol Dehydration System via Heterogeneous Azeotropic Distillation , 2015 .

[93]  Siming Li,et al.  Entrainer Screening for Separation of Isoparaffins and Naphthenes by Extractive Distillation , 2009 .

[94]  Shengkai Yang,et al.  Design and Control of an Extractive Distillation System for Benzene/Acetonitrile Separation Using Dimethyl Sulfoxide as an Entrainer , 2013 .

[95]  I-Lung Chien,et al.  Investigating the need of a pre-concentrator column for acetic acid dehydration system via heterogeneous azeotropic distillation , 2006 .

[96]  Günter Wozny,et al.  Simulation study on a reactive distillation process of methyl acetate hydrolysis intensified by reaction of methanol dehydration , 2013 .

[97]  Xinli Zhu,et al.  A fluid–dynamic model for flow pattern on a distillation tray , 2000 .

[98]  Hui Liu,et al.  Performance and applications of flow-guided sieve trays for distillation of highly viscous mixtures , 2008 .

[99]  Zhigang Lei,et al.  Process improvement on separating C4 by extractive distillation , 2002 .

[100]  Weisong Li,et al.  Temperature Control for Extractive Dividing-Wall Column with an Adjustable Vapor Split: Methylal/Methanol Azeotrope Separation , 2013 .

[101]  Kejin Huang,et al.  Reactive Distillation Columns with a Top-Bottom External Recycle , 2012 .

[102]  Hong Li,et al.  Influence of a microwave irradiation field on vapor–liquid equilibrium , 2013 .

[103]  Hui Zhang,et al.  A method for modeling a catalytic distillation process based on seepage catalytic packing internal , 2013 .

[104]  Xiaohua Li,et al.  Pressure Drop Model on Rotating Zigzag Bed as a New High-Gravity Technology , 2013 .

[105]  K. T. Yu,et al.  Computational Fluid Dynamics Simulation of Three-Dimensional Liquid Flow and Mass Transfer on Distillation Column Trays , 2004 .

[106]  Min Xu,et al.  Equilibrium Model and Performances of an Isopropanol–Acetone–Hydrogen Chemical Heat Pump with a Reactive Distillation Column , 2013 .

[107]  Zhao Lei,et al.  Design, optimization, and control of reactive distillation column for the synthesis of tert-amyl ethyl ether , 2013 .

[108]  X. Zhang,et al.  Development of gas chromatography-mass spectrometry following microwave distillation and simultaneous headspace single-drop microextraction for fast determination of volatile fraction in Chinese herb. , 2007, Journal of chromatography. A.

[109]  Qiaoling Zhang,et al.  Stabilization performance of methanol-diesel emulsified fuel prepared using an impinging stream-rotating packed bed , 2016 .

[110]  Limin Yang,et al.  Simulation and Optimization of Distillation Processes for Separating the Methanol–Chlorobenzene Mixture with Separate Heat-Pump Distillation , 2013 .

[111]  Qiuxiang Yin,et al.  CFD Study on the Local Mass Transfer Efficiency in the Gas Phase of Structured Packing , 2013 .

[112]  Jiwei Qin,et al.  Design and Control of Extractive Dividing-Wall Column for Separating Ethyl Acetate–Isopropyl Alcohol Mixture , 2014 .

[113]  Xiao Feng,et al.  Optimal Design and Optimal Operation of Separate Heat Pump Distillation , 2008 .

[114]  Qunsheng Li,et al.  Application of CAMD in separating hydrocarbons by extractive distillation , 2005 .

[115]  Shi Min Xu,et al.  CFD simulation of hydrodynamics of valve tray , 2009 .

[116]  David Shan-Hill Wong,et al.  Dynamics and Control of a Heterogeneous Azeotropic Distillation Column: Conventional Control Approach , 1999 .

[117]  Bingjiang Zhang,et al.  Design and simulation of an entrainer-enhanced ethyl acetate reactive distillation process , 2011 .

[118]  Jixin Qian,et al.  Modeling, Control, and Optimization of Ideal Internal Thermally Coupled Distillation Columns , 2000 .

[119]  Lun Li,et al.  Flow-guided sieve-valve tray (FGS-VT) – A novel tray with improved efficiency and hydrodynamics , 2013 .

[120]  Kejin Huang,et al.  Effective Arrangement of an External Recycle in Reactive Distillation Columns , 2014 .

[121]  Anton A. Kiss,et al.  Distillation technology - still young and full of breakthrough opportunities , 2014 .

[122]  Xin Li,et al.  Separation characteristics of biomass pyrolysis oil in molecular distillation , 2010 .

[123]  Jiquan Fu.  Simulation of Salt-Containing Extractive Distillation for the System of Ethanol/Water/Ethanediol/KAc. 2. Simulation of Salt-Containing Extractive Distillation , 2004 .

[124]  Chi Wai Hui,et al.  Retrofitting of the Heat Exchanger Network with Steam Generation in a Crude Oil Distillation Unit , 2015 .

[125]  Xingang Li,et al.  Computational Fluid Dynamics Modeling of Hydrodynamics of a New Type of Fixed Valve Tray , 2014 .

[126]  Qunsheng Li,et al.  Selection of Ionic Liquids as Entrainers for the Separation of Ethyl Acetate and Ethanol , 2009 .

[127]  I-Lung Chien,et al.  Design and Control of a Complete Heterogeneous Azeotropic Distillation Column System , 2004 .

[128]  K. T. Yu,et al.  Computational Fluid-Dynamics and Experimental Verification of Two-Phase Two-Dimensional Flow on a Sieve Column Tray , 1999 .

[129]  Vida N. Sharifi,et al.  Techno-economic feasibility of absorption heat pumps using wastewater as the heating source for desalination , 2011 .

[130]  Bolun Yang,et al.  Process Simulation Based on Experimental Investigations for 3-Methylthiophene Alkylation with Isobutylene in a Reactive Distillation Column , 2012 .

[131]  and Kejin Huang,et al.  Design and Control of a Methyl Tertiary Butyl Ether (MTBE) Decomposition Reactive Distillation Column , 2007 .

[132]  Hui Wan,et al.  Transesterification of Methyl Acetate with n-Propanol: Reaction Kinetics and Simulation in Reactive Distillation Process , 2014 .

[133]  Hao Feng,et al.  Thermodynamic properties of new heat pump working pairs: 1,3-Dimethylimidazolium dimethylphosphate and water, ethanol and methanol , 2010 .

[134]  Lin Cong,et al.  High-purity control of internal thermally coupled distillation columns based on nonlinear wave model , 2011 .

[135]  Kejin Huang,et al.  Balancing design and control of an olefin metathesis reactive distillation column through reactive section distribution , 2011 .

[136]  Yong Jin,et al.  Liquid phase residence time distribution for a two-phase countercurrent flow in a packed column with a novel internal , 2004 .

[137]  Zhigang Lei,et al.  Extractive distillation with ionic liquids: A review , 2014 .

[138]  Zhenming Yang,et al.  A novel potential application of SiC ceramic foam material to distillation: foam monolithic tray , 2015 .

[139]  Yong Jin,et al.  Pressure drop for two phase counter-current flow in a packed column with a novel internal , 2003 .

[140]  I-Lung Chien,et al.  Design and Control of Dimethyl Carbonate−Methanol Separation via Extractive Distillation in the Dimethyl Carbonate Reactive-Distillation Process , 2010 .

[141]  Hsiao-Ping Huang,et al.  Design and Control of Thermally-Coupled Reactive Distillation System for Esterification of an Alcohol Mixture Containing n-Amyl Alcohol and n-Hexanol , 2013 .

[142]  Weisong Li,et al.  Comparison of Pressure-Swing Distillation and Extractive Distillation Methods for Isopropyl Alcohol/Diisopropyl Ether Separation , 2014 .

[143]  K. T. Yu,et al.  New Turbulent Model for Computational Mass Transfer and Its Application to a Commercial-Scale Distillation Column , 2005 .

[144]  Lin Cong,et al.  Adaptive Robust Generic Model Control of High‐Purity Internal Thermally Coupled Distillation Column , 2011 .

[145]  San-Jang Wang,et al.  Simplified design and control of an ideal heat‐integrated distillation column (ideal HIDiC) , 2012 .

[146]  San-Jang Wang,et al.  Design and control of acetic acid dehydration system via heterogeneous azeotropic distillation using p-xylene as an entrainer , 2012 .