Effect of Fiber–Matrix Interface Friction on Compressive Strength of High-Modulus Carbon Composites

Carbon-fiber-reinforced polymers (CFRPs) enable lightweight, strong, and durable structures for many engineering applications including aerospace, automotive, biomedical, and others. High-modulus (HM) CFRPs enable the most significant improvement in mechanical stiffness at a lower weight, allowing for extremely lightweight aircraft structures. However, low fiber-direction compressive strength has been a major weakness of HM CFRPs, prohibiting their implementation in the primary structures. Microstructural tailoring may provide an innovative means for breaking through the fiber-direction compressive strength barrier. This has been implemented by hybridizing intermediate-modulus (IM) and HM carbon fibers in HM CFRP toughened with nanosilica particles. The new material solution almost doubles the compressive strength of the HM CFRPs, achieving that of the advanced IM CFRPs currently used in airframes and rotor components, but with a much higher axial modulus. The major focus of this work has been understanding the fiber–matrix interface properties governing the fiber-direction compressive strength improvement of the hybrid HM CFRPs. In particular, differences in the surface topology may cause much higher interface friction for IM carbon fibers compared to the HM fibers, which is responsible for the interface strength improvement. In situ Scanning Electron Microscopy (SEM)-based experiments were developed to measure interface friction. Such experiments reveal an approximately 48% higher maximum shear traction due to interface friction for IM carbon fibers compared to the HM fibers.

[1]  Ashok R. Khare Fibres , 2021, Principles of Spinning.

[2]  A. Makeev,et al.  In-Situ SEM Based Method for Assessing Fiber-Matrix Interface Shear Strength in CFRPs , 2020 .

[3]  A. Makeev,et al.  Understanding compressive strength improvement of high modulus carbon-fiber reinforced polymeric composites through fiber-matrix interface characterization , 2020 .

[4]  A. Makeev,et al.  Microstructural Methods for Developing High-Performance Composite Materials , 2020 .

[5]  Chenggao Li,et al.  Influence of Elevated Temperature Treatment on the Microstructures and Mechanical Properties of Carbon Fibers in Argon Environment , 2019, Journal of Materials Engineering and Performance.

[6]  A. Makeev,et al.  Improving compressive strength of high modulus carbon-fiber reinforced polymeric composites through fiber hybridization , 2019, International Journal of Engineering Science.

[7]  Junjun Zhong,et al.  Evolution of microstructure and electrical property in the conversion of high strength carbon fiber to high modulus and ultrahigh modulus carbon fiber , 2018, Composites Part A: Applied Science and Manufacturing.

[8]  Yentl Swolfs,et al.  Fibre hybridisation in polymer composites: a review , 2014 .

[9]  Bhavani V. Sankar,et al.  Mechanical properties of hybrid composites using finite element method based micromechanics , 2014 .

[10]  X. Qin,et al.  A comparison of the effect of graphitization on microstructures and properties of polyacrylonitrile and mesophase pitch-based carbon fibers , 2012 .

[11]  Lianghua Xu,et al.  Correlation between graphite crystallite distribution morphology and the mechanical properties of carbon fiber during heat treatment , 2011 .

[12]  Yequn Liu,et al.  Microstructure difference between core and skin of T700 carbon fibers in heat-treated carbon/carbon composites , 2011 .

[13]  Z. Zhang,et al.  Effect of heat treatment on carbon fiber surface properties and fibers/epoxy interfacial adhesion , 2011 .

[14]  Stephan Puchegger,et al.  Structural development of PAN-based carbon fibers studied by in situ X-ray scattering at high temperatures under load , 2010 .

[15]  Zhenping Zhu,et al.  Effect of microstructure on the mechanical properties of PAN-based carbon fibers during high-temperature graphitization , 2008, Journal of Materials Science.

[16]  Dong-feng Li,et al.  Effect of microstructure on the modulus of PAN-based carbon fibers during high temperature treatment and hot stretching graphitization , 2007 .

[17]  Satish Kumar,et al.  The processing, properties, and structure of carbon fibers , 2005 .

[18]  O. Paris,et al.  Texture of PAN- and pitch-based carbon fibers , 2002 .

[19]  Xiao Hu,et al.  Hybrid effects on tensile properties of hybrid short-glass-fiber-and short-carbon-fiber-reinforced polypropylene composites , 2001 .

[20]  R. Young,et al.  Effects of plasma oxidation on the surface and interfacial properties of ultra-high modulus carbon fibres , 2001 .

[21]  J. G. Venner Carbon and Graphite Fibers , 2000 .

[22]  B. Roebuck,et al.  Critical review of interface testing methods for composites. , 1998 .

[23]  P. D. Jero,et al.  Effect of interfacial roughness parameters on the fiber pushout behavior of a model composite , 1994 .

[24]  D. H. Isaac,et al.  Processing of Carbon Fibers: Texture Enhancement Induced by Hot Stretching , 1994 .

[25]  D. H. Isaac,et al.  Carbon Fiber Processing: Effects of Hot Stretching on Mechanical Properties , 1994 .

[26]  L. Schadler,et al.  Interphase behaviour in graphite-thermoplastic monofilament composites , 1992 .

[27]  T. Stecenko,et al.  Mechanical behaviour of carbon and glass hybrid fibre reinforced polyester composites , 1992 .

[28]  P. D. Jero,et al.  Effect of Interfacial Roughness on the Frictional Stress Measured Using Pushout Tests , 1991 .

[29]  W. Carter,et al.  Micro-mechanical aspects of asperity-controlled friction in fiber-toughened ceramic composites , 1991 .

[30]  P. D. Jero,et al.  The contribution of interfacial roughness to sliding friction of ceramic fibers in a glass matrix , 1990 .

[31]  M. Endo Structure of mesophase pitch-based carbon fibres , 1988 .

[32]  Bernhard Wietek Fibers , 1963, Fiber Concrete.

[33]  Zhaohui Chen,et al.  Influence of heat treatment on physical–chemical properties of PAN-based carbon fiber , 2006 .

[34]  C. Sauder,et al.  The tensile behavior of carbon fibers at high temperatures up to 2400 °C , 2004 .

[35]  D. Edie The effect of processing on the structure and properties of carbon fibers , 1998 .

[36]  R. Young,et al.  Effect of fibre microstructure upon the modulus of PAN- and pitch-based carbon fibres , 1995 .

[37]  R. Young,et al.  Analysis of the fragmentation test for carbon-fibre/epoxy model composites by means of Raman spectroscopy , 1994 .