A meta-analysis of the mechanical properties of ice-templated ceramics and metals
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[1] E. Levänen,et al. Mechanical performance and CO2 uptake of ion-exchanged zeolite A structured by freeze-casting , 2015 .
[2] E. Olevsky,et al. Sintering of bi-porous titanium dioxide scaffolds: Experimentation, modeling and simulation , 2015 .
[3] Q. Jiang,et al. Effects of composition and sintering temperature on the structure and compressive property of the lamellar Al2O3–ZrO2 scaffolds prepared by freeze casting , 2015, Journal of Materials Science.
[4] D. Dunand,et al. Microstructure of Fe2O3 scaffolds created by freeze-casting and sintering , 2015 .
[5] Weiming Su,et al. Impregnation of porous mullite with Na2SO4 phase change material for thermal energy storage , 2015 .
[6] R. Clowes,et al. Aligned macroporous monoliths with intrinsic microporosity via a frozen-solvent-templating approach. , 2015, Chemical communications.
[7] F. Müller,et al. Mechanical properties of porous β-tricalcium phosphate composites prepared by ice-templating and poly(ε-caprolactone) impregnation. , 2015, ACS applied materials & interfaces.
[8] Shan Qiu,et al. Novel freeze-casting fabrication of aligned lamellar porous alumina with a centrosymmetric structure , 2014 .
[9] Dou Zhang,et al. Lamellar BaTiO3 and its composites fabricated by the freeze casting technique , 2014 .
[10] A. Zamanian,et al. Fabrication of a novel nanostructured calcium zirconium silicate scaffolds prepared by a freeze-casting method for bone tissue engineering , 2014 .
[11] F. Müller,et al. Structure and mechanical properties of β-TCP scaffolds prepared by ice-templating with preset ice front velocities. , 2014, Acta biomaterialia.
[12] Yuping Zeng,et al. High-strength porous Si3N4 ceramics prepared by freeze casting and silicon powder nitridation process , 2014 .
[13] M. Grae Worster,et al. Freezing colloidal suspensions: periodic ice lenses and compaction , 2014, Journal of Fluid Mechanics.
[14] Q. Jiang,et al. Preparation of High-Strength Al–Mg–Si/Al2O3 Composites with Lamellar Structures Using Freeze Casting and Pressureless Infiltration Techniques , 2014, Acta Metallurgica Sinica (English Letters).
[15] J. F. Nascimento,et al. Synthesis and structural evaluation of freeze-cast porous alumina , 2014 .
[16] W. Li,et al. Facile synthesis of hierarchical porous TiO(2) ceramics with enhanced photocatalytic performance for micropolluted pesticide degradation. , 2014, ACS applied materials & interfaces.
[17] Yuvraj Singh Negi,et al. Microstructural and mechanical properties of porous biocomposite scaffolds based on polyvinyl alcohol, nano-hydroxyapatite and cellulose nanocrystals , 2014, Cellulose.
[18] C. Guizard,et al. Crystal Templating with Mutually Miscible Solvents: A Simple Path to Hierarchical Porosity , 2014, 1506.08992.
[19] Ho-Hwan Chun,et al. In vitro biodegradable and mechanical performance of biphasic calcium phosphate porous scaffolds with unidirectional macro-pore structure , 2014 .
[20] Manabu Fukushima,et al. Macroporous Ceramics by Gelation–Freezing Route Using Gelatin , 2014 .
[21] Tingting Xu,et al. Piezoelectric Properties of a Pioneering 3‐1 Type PZT/Epoxy Composites Based on Freeze‐Casting Processing , 2014 .
[22] A. Husmann,et al. Ice-templated structures for biomedical tissue repair: From physics to final scaffolds , 2014 .
[23] Weixing Chen,et al. Fabrication of Highly Porous Chromium Carbide with Multiple Pore Structure , 2014 .
[24] M. Meyers,et al. Bioinspired Scaffolds with Varying Pore Architectures and Mechanical Properties , 2014 .
[25] K. Zhou,et al. Effects of alcohol additives on pore structure and morphology of freeze-cast ceramics , 2014 .
[26] M. Fukushima,et al. Fabrication of Highly Porous Silica Thermal Insulators Prepared by Gelation–Freezing Route , 2014 .
[27] Hong-Chae Park,et al. Porous hydroxyapatite scaffolds containing calcium phosphate glass-ceramics processed using a freeze/gel-casting technique , 2014, Metals and Materials International.
[28] A. Zamanian,et al. Phase transformation, microstructural and mechanical properties of hydroxyapatite/alumina nanocomposite scaffolds produced by freeze casting , 2013 .
[29] R. Ritchie,et al. On the development of ice-templated silicon carbide scaffolds for nature-inspired structural materials , 2013 .
[30] S. Deville. Ice-templating, freeze casting: Beyond materials processing , 2013 .
[31] T. Button,et al. The effect of particle size in freeze casting of porous alumina–zirconia composite , 2013 .
[32] E. Maire,et al. Cellular solids studied by x-ray tomography and finite element modeling–a review , 2013 .
[33] V. Medri,et al. Ice templating of ZrB2 porous architectures , 2013 .
[34] Xiao Xie,et al. Large-range Control of the Microstructures and Properties of Three-dimensional Porous Graphene , 2013, Scientific Reports.
[35] J. Walz,et al. Effects of Solids Loading on Sintering and Properties of Freeze-Cast Kaolinite–Silica Porous Composites , 2013 .
[36] Chao Gao,et al. Multifunctional, Ultra‐Flyweight, Synergistically Assembled Carbon Aerogels , 2013, Advanced materials.
[37] Wei Zhou,et al. A Floating Porous Crystalline TiO2 Ceramic with Enhanced Photocatalytic Performance for Wastewater Decontamination , 2013 .
[38] U. Wegst,et al. Structure-property-processing correlations in freeze-cast composite scaffolds. , 2013, Acta biomaterialia.
[39] D. Fang,et al. Microstructure and properties of highly porous Y2SiO5 ceramics produced by a new water-based freeze casting , 2013 .
[40] U. Wegst,et al. Platelets self-assemble into porous nacre during freeze casting. , 2013, Journal of the mechanical behavior of biomedical materials.
[41] Haijiao Zhang,et al. Effects of solid content on the phase assemblages, mechanical and dielectric properties of porous α-SiAlON ceramics fabricated by freeze casting , 2013 .
[42] Xinghong Zhang,et al. Microstructure and mechanical properties of ZrB2–SiC porous ceramic by camphene-based freeze casting , 2013 .
[43] Haiyan Du,et al. Preparation of porous Y2SiO5 ceramics with relatively high compressive strength and ultra-low thermal conductivity by a TBA-based gel-casting method , 2013 .
[44] Liu Qiang,et al. Fabrication of gradient porous β-SiAlON ceramics via a camphene-based freeze casting process , 2012 .
[45] U. Wegst,et al. Ice‐Templated Scaffolds with Microridged Pores Direct DRG Neurite Growth , 2012 .
[46] J. Halloran,et al. Porous Ceramics by Photopolymerization with Terpene–Acrylate Vehicles , 2012 .
[47] K. Lu,et al. Fabrication of porous nanocomposites with controllable specific surface area and strength via suspension infiltration. , 2012, Langmuir : the ACS journal of surfaces and colloids.
[48] J. Chevalier,et al. Mechanical properties of porous ceramics in compression: On the transition between elastic, brittle, and cellular behavior , 2012 .
[49] A. Zamanian,et al. Evaluating Initial Content of the Slurry and Cooling Rate on the Microstructural and Mechanical Characteristics of Freeze Casted Hydroxyapatite Macroporous Scaffolds , 2012 .
[50] F. Müller,et al. β-TCP Scaffolds with an Interconnected and Aligned Porosity Fabricated via Ice-Templating , 2012 .
[51] A. Zamanian,et al. The Effect of Sintering Temperature on the Microstructural and Mechanical Characteristics of Hydroxyapatite Macroporous Scaffolds Prepared via Freeze-Casting , 2012 .
[52] Toshio Suzuki,et al. Morphology control and electrochemical properties of LiFePO4/C composite cathode for lithium ion batteries , 2012 .
[53] D. Fang,et al. Effect of pre-oxidation on the microstructure, mechanical and dielectric properties of highly porous silicon nitride ceramics , 2012 .
[54] K. Mallick,et al. Preparation and Characterization of Porous Bioglass® and PLLA Scaffolds for Tissue Engineering Applications , 2012 .
[55] Hyoun‐Ee Kim,et al. Reverse freeze casting: a new method for fabricating highly porous titanium scaffolds with aligned large pores. , 2012, Acta biomaterialia.
[56] D. Fang,et al. Microstructure, mechanical and dielectric properties of highly porous silicon nitride ceramics produced by a new water-based freeze casting , 2012 .
[57] E. Maire,et al. Particle redistribution and structural defect development during ice templating , 2012, 1804.08699.
[58] Rui Guo,et al. Microstructure and Electrical Properties of Porous PZT Ceramics with Unidirectional Pore Channel Structure Fabricated by Freeze-Casting , 2012 .
[59] Mei-shuan Li,et al. Preparation of porous alumina ceramic with ultra-high porosity and long straight pores by freeze casting , 2012, Journal of Porous Materials.
[60] T. Yang,et al. Porous alumina/zirconia layered composites with unidirectional pore channels processed using a tertiary-butyl alcohol-based freeze casting , 2012 .
[61] Yuping Zeng,et al. Fabrication porous Si3N4 ceramics via starch consolidation–freeze drying process , 2012 .
[62] Robert W. Style,et al. The kinetics of ice-lens growth in porous media , 2012, Journal of Fluid Mechanics.
[63] Wenle Li,et al. Freeze casting of porous materials: review of critical factors in microstructure evolution , 2012 .
[64] E. Maire,et al. Ice Shaping Properties, Similar to That of Antifreeze Proteins, of a Zirconium Acetate Complex , 2011, PloS one.
[65] E. Maire,et al. Dynamics of the Freezing Front During the Solidification of a Colloidal Alumina Aqueous Suspension: In Situ X‐Ray Radiography, Tomography, and Modeling , 2011, 1804.00046.
[66] Apala Majumdar,et al. Frost Heave in Colloidal Soils , 2011, SIAM J. Appl. Math..
[67] Robert W. Style,et al. Ice-lens formation and geometrical supercooling in soils and other colloidal materials. , 2011, Physical review. E, Statistical, nonlinear, and soft matter physics.
[68] Seog-Young Yoon,et al. TBA-based freeze/gel casting of porous hydroxyapatite scaffolds , 2011 .
[69] Hongjie Wang,et al. Porous Si3N4 Fabricated by Phase Separation Method Using Benzoic Acid as Pore-Forming Agent , 2011 .
[70] Rui Guo,et al. Piezoelectric Properties of the 1–3 Type Porous Lead Zirconate Titanate Ceramics , 2011 .
[71] Rui Guo,et al. Effects of pore size and orientation on dielectric and piezoelectric properties of 1–3 type porous PZT ceramics , 2011 .
[72] K. Zhou,et al. Porous hydroxyapatite ceramics fabricated by an ice-templating method , 2011 .
[73] K. Zhao,et al. Porous hydroxyapatite ceramics by ice templating: Freezing characteristics and mechanical properties , 2011 .
[74] F. Ye,et al. Effect of solid content on pore structure and mechanical properties of porous silicon nitride ceramics produced by freeze casting , 2011 .
[75] Xuetong Zhang,et al. Aligned/unaligned conducting polymer cryogels with three-dimensional macroporous architectures from ice-segregation-induced self-assembly of PEDOT-PSS. , 2011, Langmuir : the ACS journal of surfaces and colloids.
[76] Rui Guo,et al. Enhanced piezoelectric property of porous lead zirconate titanate ceramics with one dimensional ordered pore structure , 2010 .
[77] Yong Huang,et al. Control of pore channel size during freeze casting of porous YSZ ceramics with unidirectionally aligned channels using different freezing temperatures , 2010 .
[78] S. Yoon,et al. Recycling of Coal Fly Ash for Fabrication of Porous Mullite Composite , 2010 .
[79] M. Fukushima,et al. Fabrication and properties of ultra highly porous silicon carbide by the gelation–freezing method , 2010 .
[80] Haijiao Zhang,et al. Effect of sintering temperature on microstructure and mechanical properties of highly porous silicon nitride ceramics produced by freeze casting , 2010 .
[81] Haijiao Zhang,et al. Pore structure and mechanical properties in freeze cast porous Si3N4 composites using polyacrylamide as an addition agent , 2010 .
[82] T. Yang,et al. Porous mullite composite with controlled pore structure processed using a freeze casting of TBA-based coal fly ash slurries , 2010 .
[83] K. Maeda,et al. Freeze-thawing as a path to concentrate aqueous solution , 2010 .
[84] K. Zhao,et al. Fabrication of aligned lamellar porous alumina using directional solidification of aqueous slurries with an applied electrostatic field , 2010 .
[85] B. Bal,et al. Preparation and in vitro evaluation of bioactive glass (13-93) scaffolds with oriented microstructures for repair and regeneration of load-bearing bones. , 2010, Journal of biomedical materials research. Part A.
[86] Xiaoxing Liu,et al. Elasticity and strength of partially sintered ceramics , 2010 .
[87] Ulrike G K Wegst,et al. Biomaterials by freeze casting , 2010, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.
[88] P. García-Casillas,et al. Chitosan/MWCNT composites prepared by thermal induced phase separation , 2010 .
[89] Dou Zhang,et al. Porous Al2O3–ZrO2 composites fabricated by an ice template method , 2010 .
[90] Hong-Chae Park,et al. Freeze casting of aqueous coal fly ash/alumina slurries for preparation of porous ceramics , 2010 .
[91] M. Gutiérrez,et al. Bacteria incorporation in deep-eutectic solvents through freeze-drying. , 2010, Angewandte Chemie.
[92] S. Deville. Freeze-Casting of Porous Biomaterials: Structure, Properties and Opportunities , 2010, Materials.
[93] Yumin Zhang,et al. Freeze casting of aqueous alumina slurries with glycerol for porous ceramics , 2010 .
[94] Jiecai Han,et al. Camphene-based freeze-cast ZrO2 foam with high compressive strength , 2010 .
[95] Yuping Zeng,et al. Effect of polyvinyl alcohol additive on the pore structure and morphology of the freeze-cast hydroxyapatite ceramics. , 2010, Materials science & engineering. C, Materials for biological applications.
[96] E. Maire,et al. In situ X-ray radiography and tomography observations of the solidification of aqueous alumina particle suspensions. Part I: Initial instants , 2009, 1710.04929.
[97] He Jun-hui. Preparation and formation mechanism of porous ultralightweight zirconia by ice templating , 2009 .
[98] Hyoun‐Ee Kim,et al. Fabrication of porous titanium scaffolds with high compressive strength using camphene-based freeze casting , 2009 .
[99] Hyoun‐Ee Kim,et al. Compressive strength and processing of camphene-based freeze cast calcium phosphate scaffolds with aligned pores , 2009 .
[100] Hyun-Do Jung,et al. Fabrication of titanium scaffolds with porosity and pore size gradients by sequential freeze casting , 2009 .
[101] E. Saiz,et al. Architectural Control of Freeze‐Cast Ceramics Through Additives and Templating , 2009, 1710.04095.
[102] R. Moreno,et al. Shaping of porous alumina bodies by freeze casting , 2009 .
[103] I G Turner,et al. Fabrication of HA/TCP scaffolds with a graded and porous structure using a camphene-based freeze-casting method. , 2009, Acta biomaterialia.
[104] Hyoun‐Ee Kim,et al. Improvement of compressive strength of porous hydroxyapatite scaffolds by adding polystyrene to camphene-based slurries , 2009 .
[105] Jiecai Han,et al. Ultra-high-porosity zirconia ceramics fabricated by novel room-temperature freeze-casting , 2009 .
[106] P. Voorhees,et al. Morphological analysis of pores in directionally freeze-cast titanium foams , 2009 .
[107] Q. Fu,et al. Manipulation of Porous Bioceramic Microstructures by Freezing of Suspensions Containing Binary Mixtures of Solvents , 2008 .
[108] M. Fukushima,et al. Fabrication and properties of ultra highly porous cordierite with oriented micrometer-sized cylindrical pores by gelation and freezing method , 2008 .
[109] E. Landi,et al. Porous hydroxyapatite/gelatine scaffolds with ice-designed channel-like porosity for biomedical applications. , 2008, Acta biomaterialia.
[110] Fatih Dogan,et al. Freeze casting of porous hydroxyapatite scaffolds. II. Sintering, microstructure, and mechanical behavior. , 2008, Journal of biomedical materials research. Part B, Applied biomaterials.
[111] F. Doğan,et al. Freeze casting of porous hydroxyapatite scaffolds. I. Processing and general microstructure. , 2008, Journal of biomedical materials research. Part B, Applied biomaterials.
[112] Hyoun‐Ee Kim,et al. Piezoelectric Properties of PZT‐Based Ceramic with Highly Aligned Pores , 2008 .
[113] Hyoun‐Ee Kim,et al. In-situ fabrication of porous hydroxyapatite (HA) scaffolds with dense shells by freezing HA/camphene slurry , 2008 .
[114] F. Doğan,et al. Freeze-cast hydroxyapatite scaffolds for bone tissue engineering applications , 2008, Biomedical materials.
[115] Hyoun‐Ee Kim,et al. Aligned porous alumina ceramics with high compressive strengths for bone tissue engineering , 2008 .
[116] S. Deville. Freeze‐Casting of Porous Ceramics: A Review of Current Achievements and Issues , 2008, 1710.04201.
[117] Yuping Zeng,et al. Properties of Microstructure‐Controllable Porous Yttria‐Stabilized Ziroconia Ceramics Fabricated by Freeze Casting , 2008 .
[118] Hyoun‐Ee Kim,et al. In Situ Synthesis of Porous Silicon Carbide (SiC) Ceramics Decorated with SiC Nanowires , 2007 .
[119] Yong Huang,et al. Ceramics with Special Porous Structures Fabricated by Freeze‐Gelcasting: Using tert‐Butyl Alcohol as a Template , 2007 .
[120] T. Ohji,et al. Advanced Processing and Manufacturing Technologies for Structural and Multifunctional Materials III , 2007 .
[121] Hyoun‐Ee Kim,et al. Fabrication of Porous PZT–PZN Piezoelectric Ceramics With High Hydrostatic Figure of Merits Using Camphene‐Based Freeze Casting , 2007 .
[122] Yuping Zeng,et al. Fabrication of Mullite Ceramics With Ultrahigh Porosity by Gel Freeze Drying , 2007 .
[123] Hyoun‐Ee Kim,et al. Generation of Large Pore Channels for Bone Tissue Engineering Using Camphene-Based Freeze Casting , 2007 .
[124] Hyoun‐Ee Kim,et al. Highly porous hydroxyapatite bioceramics with interconnected pore channels using camphene-based freeze casting , 2007 .
[125] Brian E. Granger,et al. IPython: A System for Interactive Scientific Computing , 2007, Computing in Science & Engineering.
[126] J. Ferreira,et al. Nano‐TiO2‐Coated Unidirectional Porous Glass Structure Prepared by Freeze Drying and Solution Infiltration , 2007 .
[127] Young-Hag Koh,et al. Freeze casting of porous Ni–YSZ cermets , 2007 .
[128] T. Ikoma,et al. Structural and Tissue Reaction Properties of Novel Hydroxyapatite Ceramics with Unidirectional Pores , 2007 .
[129] Eduardo Saiz,et al. Freeze casting of hydroxyapatite scaffolds for bone tissue engineering. , 2006, Biomaterials.
[130] F. Aldinger,et al. Freeze Casting of Aluminium Nitride , 2006 .
[131] H. Bahn,et al. Fabrication of a Porous Bioactive Glass–Ceramic Using Room-Temperature Freeze Casting , 2006 .
[132] André R. Studart,et al. Processing Routes to Macroporous Ceramics: A Review , 2006 .
[133] Eduardo Saiz,et al. Freezing as a Path to Build Complex Composites , 2006, Science.
[134] A. Cooper,et al. Aligned porous materials by directional freezing of solutions in liquid CO2. , 2005, Journal of the American Chemical Society.
[135] P. Gielisse,et al. Engineered porous ceramics using a directional freeze-drying process , 2005, 28th International Spring Seminar on Electronics Technology: Meeting the Challenges of Electronics Technology Progress, 2005..
[136] Paolo Colombo,et al. Cellular Ceramics: Structure, Manufacturing, Properties and Applications , 2005 .
[137] J. Halloran,et al. Porous Ceramic Bodies with Interconnected Pore Channels by a Novel Freeze Casting Technique , 2005 .
[138] L. Gibson. Biomechanics of cellular solids. , 2005, Journal of biomechanics.
[139] J. Halloran,et al. Room-Temperature Freeze Casting for Ceramics with Nonaqueous Sublimable Vehicles in the Naphthalene–Camphor Eutectic System , 2005 .
[140] J. Halloran,et al. New Freeze‐Casting Technique for Ceramics with Sublimable Vehicles , 2005 .
[141] S. Sofie,et al. Freeze Casting of Aqueous Alumina Slurries with Glycerol , 2004 .
[142] H. Tamon,et al. Porous properties of silica gels with controlled morphology synthesized by unidirectional freeze-gelation , 2003 .
[143] M. Awano,et al. Preparation of NiO–YSZ tubular support with radially aligned pore channels , 2003 .
[144] Robert W. Zimmerman,et al. Predicting the permeability of sandstone from image analysis of pore structure , 2002 .
[145] S. Kanzaki,et al. Synthesis of Porous Silicon Nitride with Unidirectionally Aligned Channels Using Freeze‐Drying Process , 2002 .
[146] T. Ohji,et al. Filtering Properties of Porous Ceramics with Unidirectionally Aligned Pores , 2002 .
[147] T. Ohji,et al. Pore structure of porous ceramics synthesized from water-based slurry by freeze-dry process , 2001 .
[148] Michael F. Ashby,et al. The out-of-plane properties of honeycombs , 1992 .
[149] B. Lawn,et al. Role of grain size in the strength and R-curve properties of alumina , 1990 .
[150] Michael F. Ashby,et al. The mechanical properties of cellular solids , 1983 .
[151] Shichao Liu,et al. A novel silica aerogel/porous Si3N4 composite prepared by freeze casting and sol-gel impregnation with high-performance thermal insulation and wave-transparent , 2015 .
[152] S. Vijayan,et al. Freeze gelcasting of naphthalene-in-aqueous alumina slurry emulsions for the preparation of macroporous alumina ceramics , 2015 .
[153] Hyoun‐Ee Kim,et al. Dynamic freeze casting for the production of porous titanium (Ti) scaffolds. , 2013, Materials science & engineering. C, Materials for biological applications.
[154] A. Zamanian,et al. The effect of processing parameters and solid concentration on the mechanical and microstructural properties of freeze-casted macroporous hydroxyapatite scaffolds. , 2013, Materials science & engineering. C, Materials for biological applications.
[155] 张妍,et al. Effects of rheological properties on ice-templated porous hydroxyapatite ceramics. , 2013 .
[156] A. Tomsia,et al. Porous and strong bioactive glass (13-93) scaffolds prepared by unidirectional freezing of camphene-based suspensions. , 2012, Acta biomaterialia.
[157] Yuping Zeng,et al. Microstructure and mechanical properties of porous Si3N4 ceramics prepared by freeze-casting , 2012 .
[158] Chen Hong. Aligned porous conductive carbon black/polyvinyl alcohol composite obtained by directional freeze-drying , 2012 .
[159] Q. Fu,et al. Oriented bioactive glass (13-93) scaffolds with controllable pore size by unidirectional freezing of camphene-based suspensions: Microstructure and mechanical response. , 2011, Acta biomaterialia.
[160] Jiecai Han,et al. Highly porous ZrO2 ceramics fabricated by a camphene-based freeze-casting route: Microstructure and properties , 2010 .
[161] I. Nettleship,et al. The Effect of Polyvinyl Alcohol on the Microstructure and Permeability of Freeze-Cast Alumina , 2010 .
[162] 张妍,et al. Porous Hydroxyapatite Ceramics Fabricated by an Ice Templating Process , 2010 .
[163] K. Mallick. Freeze Casting of Porous Bioactive Glass and Bioceramics , 2009 .
[164] R. Oberacker,et al. Control of Lamellae Spacing During Freeze Casting of Ceramics Using Double‐Side Cooling as a Novel Processing Route , 2009 .
[165] D. Dunand,et al. Directionally freeze-cast titanium foam with aligned, elongated pores , 2008 .
[166] M. Gutiérrez,et al. Enzymatic Synthesis of Amorphous Calcium Phosphate−Chitosan Nanocomposites and Their Processing into Hierarchical Structures , 2008 .
[167] S. Kanzaki,et al. Synthesis of Porous Ceramics with Complex Pore Structure by Freeze‐Dry Processing , 2001 .