N′-(2-Chlorobenzylidene)-2-(3,4-dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)acetohydrazide

The asymmetric unit of the title compound, C20H18ClN5O3S, contains two independent molecules with significantly different conformations of the heterocyclic thiazine rings. In both molecules, the thiazine rings adopt half-chair conformations, with the S atoms displaced by 0.382 (3) and 0.533 (3) Å and N atoms −0.351 and −0.275 Å, respectively, from the planes formed by the remaining ring atoms. The crystal structure is stabilized by weak intermolecular N—H⋯O and C—H⋯O interactions.

[1]  Matloob Ahmad,et al.  2-(3,4-Dimethyl-5,5-dioxo-2H,4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N′-(3-methoxybenzylidene)acetohydrazide dimethylformamide hemisolvate , 2010, Acta crystallographica. Section E, Structure reports online.

[2]  Muhammad Irfan Ashiq,et al.  1-(4-Hydroxy-2-methyl-1,1-dioxo-2H-1,2-benzothiazin-3-yl)ethanone , 2008, Acta crystallographica. Section E, Structure reports online.

[3]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[4]  D. Cremer,et al.  General definition of ring puckering coordinates , 1975 .

[5]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[6]  M. Parvez,et al.  N-(X-chlorophenyl)-4-hydroxy-2-methyl-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide (with X = 2 and 4). , 2008, Acta crystallographica. Section C, Crystal structure communications.

[7]  R. Blessing Outlier Treatment in Data Merging , 1997 .