Effect of Filler Size on the Thermal Properties of ER/BaTiO3 Composites

Summary Epoxy resin/barium titanate nano- and micro-composites were prepared and studied, varying the filler content. Thermal properties of the composite systems were examined by means of Thermogravimetric/Differential Thermal Analysis, while dielectric response was assessed via Dielectric Relaxation Spectroscopy. Decomposition temperature found not to vary with filler size, while thermal stability of reinforced systems is enhanced compared to epoxy resin. Nanocomposites exhibit, improved thermal properties compared to micro-composites at the same filler content. Composite systems attain higher values of dielectric permittivity, and relaxation processes are present in all studied systems.

[1]  G. Psarras,et al.  Development and characterization of a novolac resin/BaTiO3 nanoparticles composite system , 2012 .

[2]  G. Psarras,et al.  Dielectric response, functionality and energy storage in epoxy nanocomposites: Barium titanate vs exfoliated graphite nanoplatelets , 2012 .

[3]  Lei Zhu,et al.  Polymer nanocomposites for electrical energy storage , 2011 .

[4]  T. Hanemann,et al.  Dielectric property improvement of polymer-nanosized strontium titanate-composites for applications in microelectronics , 2011 .

[5]  I. Mondragon,et al.  Dynamics of in situ synthetized silver-epoxy nanocomposites as studied by dielectric relaxation spectroscopy , 2011 .

[6]  C. Randall,et al.  Epoxy-based nanocomposites for electrical energy storage. I: Effects of montmorillonite and barium titanate nanofillers , 2010 .

[7]  Heli Jantunen,et al.  Polymer–Ceramic Composites of 0–3 Connectivity for Circuits in Electronics: A Review , 2010 .

[8]  G. Psarras,et al.  Electrical response and functionality of polymer matrix-titanium carbide composites , 2010 .

[9]  M. Castro,et al.  BaTiO3–Epoxy Composites for Electronic Applications , 2009 .

[10]  Z. Dang,et al.  Study on microstructure and dielectric property of the BaTiO3/epoxy resin composites , 2008 .

[11]  T. Mandal Characterization of tetragonal BaTiO3 nanopowders prepared with a new soft chemistry route , 2007 .

[12]  Frans Baeten,et al.  Barium titanate characterization by differential scanning calorimetry , 2006 .

[13]  S. Akbar,et al.  Hydrothermal Synthesis and Dielectric Properties of Tetragonal BaTiO3 , 1994 .