Organic solar cells with solution-processed graphene transparent electrodes

We demonstrate that solution-processed graphene thin films can serve as transparent conductive anodes for organic photovoltaic cells. The graphene electrodes were deposited on quartz substrates by spin coating of an aqueous dispersion of functionalized graphene, followed by a reduction process to reduce the sheet resistance. Small molecular weight organic solar cells can be directly deposited on such graphene anodes. The short-circuit current and fill factor of these devices on graphene are lower than those of control device on indium tin oxide due to the higher sheet resistance of the graphene films. We anticipate that further optimization of the reduction conditions will improve the performance of these graphene anodes.

[1]  Franco Cacialli,et al.  Workfunction of purified and oxidised carbon nanotubes , 1999 .

[2]  Barry P Rand,et al.  4.2% efficient organic photovoltaic cells with low series resistances , 2004 .

[3]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[4]  S. Chua,et al.  A mechanical assessment of flexible optoelectronic devices , 2001 .

[5]  A. Heeger,et al.  High Sensitivity Polymer Photosensors for Image Sensing Applications , 1999 .

[6]  Masahiro Fujiwara,et al.  Thin-film particles of graphite oxide 1:: High-yield synthesis and flexibility of the particles , 2004 .

[7]  K. Müllen,et al.  Transparent, conductive graphene electrodes for dye-sensitized solar cells. , 2008, Nano letters.

[8]  Stephen R. Forrest,et al.  Efficient, high-bandwidth organic multilayer photodetectors , 2000 .

[9]  C. Tang Two‐layer organic photovoltaic cell , 1986 .

[10]  R. Stoltenberg,et al.  Evaluation of solution-processed reduced graphene oxide films as transparent conductors. , 2008, ACS nano.

[11]  S. Forrest,et al.  Highly efficient phosphorescent emission from organic electroluminescent devices , 1998, Nature.

[12]  Stephen R. Forrest,et al.  Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques. , 1997, Chemical reviews.

[13]  N. Balasubramanian,et al.  Studies on Evaporated Indium Tin Oxide (ITO)/Silicon Junctions and an Estimation of ITO Work Function , 1991 .

[14]  John R. Reynolds,et al.  Transparent, Conductive Carbon Nanotube Films , 2004, Science.

[15]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[16]  P. Peumans,et al.  Control of Electric Field Strength and Orientation at the Donor–Acceptor Interface in Organic Solar Cells , 2008 .

[17]  Yi Cui,et al.  Solution-processed metal nanowire mesh transparent electrodes. , 2008, Nano letters.

[18]  Stephen R. Forrest,et al.  Small molecular weight organic thin-film photodetectors and solar cells , 2003 .

[19]  W. S. Hummers,et al.  Preparation of Graphitic Oxide , 1958 .

[20]  Stephen R. Forrest,et al.  Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells , 2001 .

[21]  J. L. McChesney,et al.  Synthesis and characterization of atomically thin graphite films on a silicon carbide substrate , 2006 .

[22]  J. Lagemaat,et al.  Single-wall carbon nanotube networks as a transparent back contact in CdTe solar cells , 2007 .

[23]  J. B. DuBow,et al.  The operation of the semiconductor‐insulator‐semiconductor solar cell: Experiment , 1979 .

[24]  Klaus Kern,et al.  Electronic transport properties of individual chemically reduced graphene oxide sheets. , 2007, Nano letters.

[25]  S. Stankovich,et al.  Graphene-silica composite thin films as transparent conductors. , 2007, Nano letters.

[26]  L. Jay Guo,et al.  Nanoimprinted Semitransparent Metal Electrodes and Their Application in Organic Light‐Emitting Diodes , 2007 .

[27]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[28]  Liangbing Hu,et al.  Organic solar cells with carbon nanotube network electrodes , 2006 .

[29]  B. Parkinson,et al.  Investigation of band bending and charging phenomena in frontier orbital alignment measurements of para-quaterphenyl thin films grown on highly oriented pyrolytic graphite and SnS2 , 2000 .

[30]  Frank Nüesch,et al.  A photoelectron spectroscopy study on the indium tin oxide treatment by acids and bases , 1999 .