Calorimetric-state estimators for chemical reactor diagnosis and control: review of methods and applications

Abstract The advanced control of stirred tank reactors can be based on models which contain exclusively the conservation equations of energy and species, without using further sophisticated modelling terms. These basic models allow determination of the instantaneous heat production, the conversion and the reactive production rate from state estimation algorithms. These “calorimetric”-state estimators are based on easily available signals, like temperatures, pressures, flows, and on credible model information, like conservation equations. The design of these estimators is quite simple, as they are based on linear models. This contribution gives an overview of control applications which use these state estimators based on calorimetric principles. Available models, signal processing principles and control structures will be reviewed. These advanced control loops assist basic automation structures in improving dynamic response behaviour, control performance and disturbance rejection. They introduce new strategies into reactor control.

[1]  W. H. Ray,et al.  The Control of Copolymer Composition Distributions in Batch and Tubular Reactors , 1969 .

[2]  K. Reichert,et al.  Reaction calorimeter a contribution to safe operation of exothermic polymerizations , 1988 .

[3]  Alan S. Foss Critique of chemical process control theory , 1973 .

[4]  D. Bonvin,et al.  Application of estimation techniques to batch reactors—II. Experimental studies in state and parameter estimation , 1989 .

[5]  T. Trüeb,et al.  Development of an Algorithm for Temperature Control of Stirred Batch Reactors , 1974 .

[6]  Uwe Budde,et al.  Automatic polymerization reactor with on-line data measurement and reactor control , 1988 .

[7]  Karl-Heinz Reichert,et al.  Mikrocomputergesteuerter Laborreaktor zur Durchführung von Polymerisationen , 1985 .

[8]  Vern W. Weekman,et al.  Advanced control practice in the chemical process industry: A view from industry , 1976 .

[9]  T. J. Buckley,et al.  High Precision Microcalorimetry: Apparatus, Procedures, and Biochemical Applications. , 1986, Journal of research of the National Bureau of Standards.

[10]  H. Amrehn Computer control in the polymerization industry , 1977, Autom..

[11]  S. Igarashi,et al.  A constant heat-flux calorimeter for measuring heat transfer data☆ , 1979 .

[12]  M. Agarwal,et al.  Experimental Estimation of Concentrations From Reactor Temperature Measurement , 1988 .

[13]  Daniel L. Gordon,et al.  Control of Particle Size Distribution Through Emulsifier Metering Based on Rate of Conversion , 1981 .

[14]  K. Nakao,et al.  Learning Control of a Batch Reactor , 1988 .

[15]  W. Litz,et al.  The thermokinetic reactor TKR and its possible applications in chemical research and engineering , 1983 .

[16]  Wm.R. Parrish,et al.  Recent Advances in Calorimetry , 1986 .

[17]  H. Amrehn DDC of Chemical and Related Systems , 1975 .

[18]  Charles H. Wells Application of modern estimation and identification techniques to chemical processes , 1971 .

[19]  H. Schuler,et al.  SEMIBATCH REACTOR DYNAMICS AND STATE ESTIMATION , 1986 .

[20]  V. Torra,et al.  Recent progress in numerical methods for the determination of thermokinetics , 1981 .

[21]  J. Villadsen,et al.  Isothermal reaction calorimeters—I. A literature review , 1987 .

[22]  I. Åkesson Adaptive Automatic Control of Reaction Speed in Exothermal Batch Processes , 1985 .

[23]  R. S. H. Wu,et al.  Dynamic thermal analyser for monitoring batch processes , 1985 .

[24]  U von Stockar,et al.  The heat generated by yeast cultures with a mixed metabolism in the transition between respiration and fermentation , 1989, Biotechnology and bioengineering.

[25]  M. L. Mcglashan,et al.  Current trends in precise calorimetry , 1984 .

[26]  W. Regenass Calorimetric monitoring of industrial chemical processes , 1985 .

[27]  Alexander Penlidis,et al.  STATE ESTIMATION FOR POLYMERIZATION REACTORS , 1986 .

[28]  John Villadsen,et al.  Isothermal reaction calorimeters—II. Data treatment , 1987 .

[29]  George R. Gavalas,et al.  Sequential estimation of states and kinetic parameters in tubular reactors with catalyst decay , 1969 .

[30]  John H. Seinfeld,et al.  Optimal control of a continuous stirred tank reactor with transportation lag , 1969 .

[31]  D. Bonvin,et al.  On line procedures for supervising the operation of batch reactors , 1988 .

[32]  Jean-Marie Flaus,et al.  COMPARISON OF ESTIMATION METHODS FOR BIOTECHNOLOGICAL PROCESSES , 1988 .

[33]  H. Søeberg,et al.  Optimal data aquisition for heat flow calorimeter , 1984 .

[34]  D. Bonvin,et al.  On the Dynamics of a Bench-scale Calorimeter , 1986 .

[35]  Carlos E. Garcia,et al.  Internal model control. A unifying review and some new results , 1982 .

[36]  B. J. Cott,et al.  Temperature control of exothermic batch reactors using generic model control , 1989 .

[37]  Coleman B. Brosilow,et al.  The structure and design of Smith predictors from the viewpoint of inferential control , 1979 .

[38]  G. E. Eliçabe,et al.  Adaptive Control of a Polymerization Reactor , 1987 .

[39]  C. R. Cutler,et al.  Dynamic matrix control¿A computer control algorithm , 1979 .

[40]  R. Aris,et al.  Studies in optimization—VII The application of Pontryagin's methods to the control of batch and tubular reactors , 1964 .

[41]  J. Richalet,et al.  Model predictive heuristic control: Applications to industrial processes , 1978, Autom..

[42]  Dominique Bonvin,et al.  Application of estimation techniques to batch reactors—I. Modelling thermal effects , 1989 .

[43]  W. Litz Development and use of a constant flow stirred thermokinetic reactor (steady-state TKR) , 1987 .

[44]  John F. MacGregor,et al.  On-line Reactor Energy Balances via Kalman Filtering , 1987 .

[45]  Arthur Jutan,et al.  Combined feedforward-feedback servo control scheme for an exothermic batch reactor , 1984 .

[46]  R.W.H. Sargent,et al.  Applications of linear estimation theory to chemical processes: a feasibility study , 1969 .

[47]  I. Marison,et al.  Calorimetric investigation of aerobic fermentations , 1987, Biotechnology and bioengineering.

[48]  John H. Seinfeld,et al.  Optimal stochastic control of nonlinear systems , 1970 .

[49]  J. R. Richards,et al.  Perspectives on industrial reactor control , 1988 .

[50]  Karl-Heinz Reichert,et al.  Sichere Reaktionsführung von Polymerisationen , 1988 .