A NEW TYPE COPPER(II)-GADOLINIUM(III) COMPLEX OF PHENOL-BASED SIDE-OFF TYPE DINUCLEATING LIGAND CONTAINING FULLY SATURATED AMINO NITROGENS AS COORDINATING ATOMS

The copper(II)-gadolinium(III) complex of a phenol-based side-off type di-nucleating ligand was newly synthesized, using N, N′-dimethyl-N,N′-ethylene-di(5-bromo-3-formyl-2-hydroxybenzylamine). Structural analysis revealed that one of the two formyl groups is converted into a hemiacetal group and the two dinuclear CuGd units are bridged by the alcoholic oxygens of acetal groups of each unit to construct the tetranuclear (CuGd)2 core.

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