Kinetics of the phase transition in solid solutions of 4He in 3He at different degrees of supersaturation

Precision measurements of the pressure during phase separation in samples of solid solutions of 4He in 3He have been used to obtain data on the characteristic times of the phase transition. A processing of the results gives additional evidence supporting the view that homogeneous nucleation is realized in 3He–4He solid solutions at significant supercoolings and heterogeneous nucleation at the smallest supercoolings. Two different ways are proposed for comparing the results with a theoretical calculation taking into account the processes at the boundary of a nucleus of the new phase. Both give roughly similar values of the coefficient of surface tension at the nucleus–matrix boundary, and those values agree with those obtained in other studies. It is conjectured that the bcc–hcp transition has a substantial influence on the kinetics of separation at the lowest supersaturations.

[1]  V. Maĭdanov,et al.  Concentration dependence of the diffusion coefficient in separating dilute solid mixtures of 4He in 3He , 2003 .

[2]  A. Ganshin,et al.  4He nanoclusters around vacancies in solid solutions of 4He in 3He , 2003 .

[3]  V. V. Slezov Phase transitions in condensed media at a finite rate of formation of a metastable state , 2003 .

[4]  Y. Okuda,et al.  Nucleation of crystals at the bcc-hcp transition line in solid 4He , 2002 .

[5]  A. Ganshin,et al.  Influence of Supercooling Level on Kinetics of Phase Separation in Solid Mixtures of 4He in 3He , 2002 .

[6]  A. Ganshin,et al.  Observation of Andreev-Pushkarov vacancy clusters in phase-separated solid solutions of 4He in 3He , 2001 .

[7]  S. Balibar,et al.  Comments on Heterogeneous Nucleation in Helium , 2000 .

[8]  A. Ganshin,et al.  Growth and dissolution of 3He liquid drops in a 4He crystalline matrix , 2000 .

[9]  V. Maĭdanov,et al.  Growth and dissolution kinetics of 3He inclusions in phase-separated 3He–4He solid mixtures , 1999 .

[10]  A. Ganshin,et al.  Threshold Effect During Dissolution of 3He Inclusions in Solid 4He , 1999, cond-mat/9908022.

[11]  J. Schmelzer,et al.  Maximum number of new-phase particles nucleated during the decay of solid solutions , 1997 .

[12]  S. Ehrlich,et al.  Phase separation in solid mixtures of helium-3 and helium-4 , 1987 .

[13]  W. Mullin Theory of Phase Separation in Solid 3He-4He Mixtures , 1968 .

[14]  Paul Shewmon,et al.  Diffusion in Solids , 2016 .

[15]  Max Volmer,et al.  Kinetik der Phasenbildung , 1939 .