There exists a gap between existing security mechanisms and their ability to detect advancing threats. Antivirus and EDR (End Point Detection and Response) aim to detect and prevent threats; such security mechanisms are reactive. This approach did not prove to be effective in protecting against stealthy attacks. SCADA (Supervisory Control and Data Acquisition) security is crucial for any country. However, SCADA is always an easy target for adversaries due to a lack of security for heterogeneous devices. An attack on SCADA is mainly considered a national-level threat. Recent research on SCADA security has not considered “unknown threats,” which has left a gap in security. The proactive approach, such as threat hunting, is the need of the hour. In this research, we investigated that threat hunting in conjunction with cyber deception and kill chain has countervailing effects on detecting SCADA threats and mitigating them. We have used the concept of “decoy farm” in the SCADA network, where all attacks are engaged. Moreover, we present a novel threat detection and prevention approach for SCADA, focusing on unknown threats. To test the effectiveness of approach, we emulated several SCADA, Linux and Windows based attacks on a simulated SCADA network. We have concluded that our approach detects and prevents the attacker before using the current reactive approach and security mechanism for SCADA with enhanced protection for heterogeneous devices. The results and experiments show that the proposed threat hunting approach has significantly improved the threat detection ability.