Manganese incorporation behavior in molecular beam epitaxial gallium arsenide

A secondary ion mass spectrometric study of the substrate temperature and As4/Ga flux‐ratio dependence of the chemical incorporation behavior of manganese in molecular beam epitaxial GaAs is presented. At molecular beam epitaxial growth temperatures, manganese competitively surface segregates, desorbs, and complexes with As at the surface. No significant diffusion was observed. The incorporation model of Wood et al. qualitatively explains the observed behavior.

[1]  R. Dingle,et al.  Optical and electrical properties of Mn‐doped GaAs grown by molecular‐beam epitaxy , 1975 .

[2]  C. Wood,et al.  Improved Molecular-Beam Epitaxial GaAs Power FET's, , 1980 .

[3]  L. Vieland Behavior of Manganese in GaAs , 1962 .

[4]  T. C. Lee,et al.  Edge emission involving manganese impurities in GaAs at 4.2°K , 1964 .

[5]  J. S. Blakemore,et al.  Impurity Conduction and the Metal-Nonmetal Transition in Manganese-Doped Gallium Arsenide , 1973 .

[6]  M. Seltzer Diffusion of manganese into gallium arsenide , 1965 .

[7]  K. Weiser,et al.  Electroluminescent Gallium Arsenide Diodes with Negative Resistance , 1964 .

[8]  Kiyoshi Takahashi,et al.  Ionized Zn doping of GaAs molecular beam epitaxial films , 1975 .

[9]  A. Cho,et al.  P‐N Junction Formation during Molecular‐Beam Epitaxy of Ge‐Doped GaAs , 1971 .

[10]  J. S. Blakemore,et al.  Transport and Photoelectrical Properties of Gallium Arsenide Containing Deep Acceptors , 1972 .

[11]  B. A. Joyce,et al.  Tin‐doping effects in GaAs films grown by molecular beam epitaxy , 1978 .

[12]  M. Ilegems Beryllium doping and diffusion in molecular‐beam epitaxy of GaAs and AlxGa1−xAs , 1977 .

[13]  J. S. Blakemore,et al.  Thermal activation energy of manganese acceptors in gallium arsenide as a function of impurity spacing , 1973 .

[14]  A. Cho,et al.  Magnesium‐doped GaAs and Alx Ga1−x As by molecular beam epitaxy , 1972 .

[15]  J. Woodall,et al.  Volatile metal oxide incorporation in layers of GaAs and Ga1−xAlxAs grown by molecular beam epitaxy , 1981 .

[16]  F. Alexandre,et al.  Influence of growth conditions on tin incorporation in GaAs grown by molecular beam epitaxy , 1980 .

[17]  C. Wood,et al.  Magnesium‐ and calcium‐doping behavior in molecular‐beam epitaxial III‐V compounds , 1982 .