Facile synthesis of Ag@Au core-sheath nanowires with greatly improved stability against oxidation.

We report a facile synthesis of Ag@Au core-sheath nanowires through the conformal deposition of Au atoms onto the surface of pre-synthesized Ag nanowires. The resulting Ag@Au nanowires showed morphology and optical properties almost identical to the pristine Ag nanowires, but with greatly improved stability under different corrosive environments.

[1]  Younan Xia,et al.  A General Approach to the Synthesis of M@Au/Ag (M = Au, Pd, and Pt) Nanorattles with Ultrathin Shells Less Than 2.5 nm Thick , 2017 .

[2]  M. Chi,et al.  Facile Synthesis of Sub-20 nm Silver Nanowires through a Bromide-Mediated Polyol Method. , 2016, ACS nano.

[3]  L. J. Albuquerque,et al.  Effects of Gold Salt Speciation and Structure of Human and Bovine Serum Albumins on the Synthesis and Stability of Gold Nanostructures , 2016, Front. Chem..

[4]  J. Ristein,et al.  Functionalization of Silver Nanowires Surface using Ag-C Bonds in a Sequential Reductive Method. , 2015, ACS applied materials & interfaces.

[5]  Xiaojun Guo,et al.  Neutral-pH PEDOT:PSS as over-coating layer for stable silver nanowire flexible transparent conductive films , 2014 .

[6]  Bo-Tau Liu,et al.  Transparent conductive silver nanowire electrodes with high resistance to oxidation and thermal shock , 2014 .

[7]  I. Park,et al.  Ag@Ni core-shell nanowire network for robust transparent electrodes against oxidation and sulfurization. , 2014, Small.

[8]  B. Wiley,et al.  Metal Nanowire Networks: The Next Generation of Transparent Conductors , 2014, Advanced materials.

[9]  S. Han,et al.  Highly transparent Au-coated Ag nanowire transparent electrode with reduction in haze. , 2014, ACS applied materials & interfaces.

[10]  D. Qin,et al.  Galvanic replacement-free deposition of Au on Ag for core-shell nanocubes with enhanced chemical stability and SERS activity. , 2014, Journal of the American Chemical Society.

[11]  Younan Xia,et al.  25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well‐Controlled Properties , 2013, Advanced materials.

[12]  Moon J. Kim,et al.  On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals , 2013, Proceedings of the National Academy of Sciences.

[13]  C. Niu Carbon nanotube transparent conducting films , 2011 .

[14]  Henry Du,et al.  Effect of oxidation on surface-enhanced Raman scattering activity of silver nanoparticles: a quantitative correlation. , 2011, Analytical chemistry.

[15]  Liangbing Hu,et al.  Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures , 2011, Advanced materials.

[16]  T. Waite,et al.  Silver Nanoparticle−Reactive Oxygen Species Interactions: Application of a Charging−Discharging Model , 2011 .

[17]  Yi Cui,et al.  Scalable coating and properties of transparent, flexible, silver nanowire electrodes. , 2010, ACS nano.

[18]  Younan Xia,et al.  Dissolving Ag from Au-Ag Alloy Nanoboxes with H(2)O(2): A Method for Both Tailoring the Optical Properties and Measuring the H(2)O(2) Concentration. , 2010, The journal of physical chemistry. C, Nanomaterials and interfaces.

[19]  Kwang S. Kim,et al.  Roll-to-roll production of 30-inch graphene films for transparent electrodes. , 2009, Nature nanotechnology.

[20]  Seok‐In Na,et al.  Efficient and Flexible ITO‐Free Organic Solar Cells Using Highly Conductive Polymer Anodes , 2008 .

[21]  G. Hartland,et al.  Electronic dephasing in bimetallic gold-silver nanoparticles examined by single particle spectroscopy. , 2005, The journal of physical chemistry. B.

[22]  R. Gordon Criteria for Choosing Transparent Conductors , 2000 .

[23]  A. Henglein Colloidal Silver Nanoparticles: Photochemical Preparation and Interaction with O2, CCl4, and Some Metal Ions , 1998 .

[24]  G. Whitesides,et al.  Microcontact Printing of Alkanethiols on Silver and Its Application in Microfabrication , 1996 .