Toward Hybrid Materials: Group Transfer Polymerization of 3-(Trimethoxysilyl)propyl Methacrylate.

In this study, the group transfer polymerization (GTP) of the functional monomer 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) is reported to produce polymers of different architectures and topologies. TMSPMA is successfully polymerized and copolymerized with GTP to produce well-defined (co)polymers that can be used to fabricate functional hybrid materials like hydrogels and films.

[1]  P. Fletcher,et al.  ABC triblock copolymer micelles: spherical versus worm-like micelles depending on the preparation method. , 2015, Macromolecular rapid communications.

[2]  M. Ward,et al.  Well-defined "clickable" copolymers prepared via one-pot synthesis. , 2014, Chemical communications.

[3]  A. Pan,et al.  Fabrication pentablock copolymer/silica hybrids as self-assembly coatings. , 2014, Journal of colloid and interface science.

[4]  Zesheng An,et al.  Emerging synthetic strategies for core cross-linked star (CCS) polymers and applications as interfacial stabilizers: bridging linear polymers and nanoparticles. , 2013, Macromolecular rapid communications.

[5]  K. Kuroda,et al.  Siloxane-Bond Formation Promoted by Lewis Acids: A Nonhydrolytic Sol-Gel Process and the Piers-Rubinsztajn Reaction. , 2013, ChemPlusChem.

[6]  T. Satoh,et al.  Recent progress in organocatalytic group transfer polymerization , 2013 .

[7]  M. Ward,et al.  Thermoresponsive gels based on ABA triblock copolymers: Does the asymmetry matter? , 2013 .

[8]  M. Ward,et al.  Multicompartment thermoresponsive gels: does the length of the hydrophobic side group matter? , 2012 .

[9]  Yi Shi,et al.  Thermo-responsive organic–inorganic hybrid vesicles with tunable membrane permeability , 2012 .

[10]  M. Ward,et al.  Thermoresponsive triblock copolymers based on methacrylate monomers: effect of molecular weight and composition , 2012 .

[11]  Youliang Zhao,et al.  Facile synthesis of V-shaped copolymer brushes grafted onto the surface of graphene oxide via coupling reactions. , 2011, Chemical communications.

[12]  S. Perrier,et al.  Construction of temperature responsive hybrid crosslinked self‐assemblies based on PEG‐b‐P(MMA‐co‐MPMA)‐b‐PNIPAAm triblock copolymer: ATRP synthesis and thermoinduced association behavior , 2011 .

[13]  T. Georgiou,et al.  “Comb-like” non-ionic polymeric macrosurfactants , 2010 .

[14]  M. Ward,et al.  Thermoresponsive terpolymers based on methacrylate monomers: Effect of architecture and composition , 2010 .

[15]  R. Zhuo,et al.  Temperature and pH Double Responsive Hybrid Cross-Linked Micelles Based on P(NIPAAm-co-MPMA)-b-P(DEA): RAFT Synthesis and Schizophrenic Micellization , 2009 .

[16]  R. Koepsel,et al.  Nonleaching antibacterial glass surfaces via "Grafting Onto": the effect of the number of quaternary ammonium groups on biocidal activity. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[17]  C. S. Patrickios,et al.  Star polymers and polymer networks containing a novel, hydrolyzable diacetal-based dimethacrylate cross-linker: Synthesis, characterization, and hydrolysis kinetics , 2007 .

[18]  Li Wang,et al.  Preparation of organic/inorganic hybrid nanomaterials using aggregates of poly(stearyl methacrylate)-b-poly(3-(trimethoxysilyl) propyl methacrylate) as precursor , 2007 .

[19]  C. Tsitsilianis,et al.  Multi‐Compartment Unimolecular Micelles from (ABC)n Multi‐Arm Star Triblock Terpolymers , 2007 .

[20]  T. Georgiou,et al.  Synthesis, characterization, and evaluation as transfection reagents of ampholytic star copolymers: effect of star architecture. , 2006, Biomacromolecules.

[21]  Hui Zhu,et al.  Gelation Inside Block Copolymer Aggregates and Organic/Inorganic Nanohybrids , 2006 .

[22]  L. Matějka,et al.  Organization in sol–gel polymerization of methacrylate co-oligomers containing trimethoxysilylpropyl methacrylate , 2005 .

[23]  M. Vamvakaki,et al.  Synthesis, characterization, and evaluation as transfection reagents of double-hydrophilic star copolymers: effect of star architecture. , 2005, Biomacromolecules.

[24]  M. Popall,et al.  Applications of hybrid organic–inorganic nanocomposites , 2005 .

[25]  Jianzhong Du,et al.  Hairy Nanospheres by Gelation of Reactive Block Copolymer Micelles , 2005 .

[26]  M. Vamvakaki,et al.  Synthesis of Amphiphilic (ABC)n Multiarm Star Triblock Terpolymers , 2005 .

[27]  Jianzhong Du,et al.  Organic-inorganic hybrid nanoparticles with a complex hollow structure. , 2004, Angewandte Chemie.

[28]  M. Vamvakaki,et al.  Nanoscopic cationic methacrylate star homopolymers: synthesis by group transfer polymerization, characterization and evaluation as transfection reagents. , 2004, Biomacromolecules.

[29]  Jianzhong Du,et al.  Atom-Transfer Radical Polymerization of a Reactive Monomer: 3-(Trimethoxysilyl)propyl Methacrylate , 2004 .

[30]  Jianzhong Du,et al.  Preparation of Organic/Inorganic Hybrid Hollow Particles Based on Gelation of Polymer Vesicles , 2004 .

[31]  Jianzhong Du,et al.  Organic/inorganic hybrid vesicles based on a reactive block copolymer. , 2003, Journal of the American Chemical Society.

[32]  T. Fukuda,et al.  Precision synthesis of organic/inorganic hybrid nanocapsules with a silanol-functionalized micelle template. , 2003, Angewandte Chemie.

[33]  Nikos Hadjichristidis,et al.  Anionic polymerization: High vacuum techniques , 2000 .

[34]  A. Hirao,et al.  Polymerization of monomers containing functional silyl groups. 11. Anionic living polymerization of 3-(tri-2-propoxysilyl)propyl methacrylate , 1992 .

[35]  D. Sogah,et al.  Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiators , 1983 .

[36]  Julian R Jones,et al.  Review of bioactive glass: from Hench to hybrids. , 2013, Acta biomaterialia.

[37]  C. Zhang,et al.  Preparation and characterization of organic-inorganic hybrid nanomaterials using polyurethane-b-poly(3-(trimethoxysilyl) propyl methacrylate) via RAFT polymerization , 2010 .

[38]  C. S. Patrickios,et al.  Synthesis and characterization of amphiphilic star copolymers of 2-(dimethylamino) ethyl methacrylate and methyl methacrylate: Effects of architecture and composition , 2007 .

[39]  O. Webster.  Group Transfer Polymerization: A Critical Review of Its Mechanism and Comparison with Other Methods for Controlled Polymerization of Acrylic Monomers , 2003 .