Sealing efficiency of cement-based materials containing extruded cementitious capsules

Abstract The intensive use of cement-based building materials is a growing concern in terms of environmental impact, since they significantly contribute to the global anthropogenic CO2 emissions. The development of self-sealing cementitious materials could be a possible approach to improve the structural durability and thus reduce overall cost and environmental impact. In the present work, the efficiency of a self-sealing system using extruded cementitious capsules was experimentally investigated, and different healing agents were tested (specifically, a water-repellent agent, a polyurethane precursor and a solution of silica gel immobilized ureolytic bacteria). The self-sealing efficiency was evaluated in terms of capability to autonomously seal localized cracks induced in a controlled way. An active crack width control technique was adopted during the cracking procedure, in order to reduce the variation of the crack width within a series of specimens. Water permeability and capillary water absorption tests were performed to quantify the crack sealing ability, along with qualitative visual analysis of the crack faces. Positive results were achieved when using the water-repellent agent in water absorption tests, the bacterial agent in water-flow tests and the polyurethane precursor in both cases. This suggests that the proposed self-sealing system is sufficiently versatile to be used with different healing agents and that it can be effective in prolonging the material functionality by selecting the most appropriate agent for the real operating conditions.

[1]  Didier Snoeck,et al.  Numerical investigation of crack self-sealing in cement-based composites with superabsorbent polymers , 2019, Cement and Concrete Composites.

[2]  Abir Al-Tabbaa,et al.  Encapsulation of expansive powder minerals within a concentric glass capsule system for self-healing concrete , 2016 .

[3]  Nele De Belie,et al.  Neutron Radiography Based Visualization and Profiling of Water Uptake in (Un)cracked and Autonomously Healed Cementitious Materials , 2016, Materials.

[4]  R. Kahhat,et al.  Production of cement in Peru: Understanding carbon-related environmental impacts and their policy implications , 2019, Resources, Conservation and Recycling.

[5]  Nele De Belie,et al.  The efficiency of self-healing concrete using alternative manufacturing procedures and more realistic crack patterns , 2015 .

[6]  Abir Al-Tabbaa,et al.  Autogenous self-healing of cement with expansive minerals-II: Impact of age and the role of optimised expansive minerals in healing performance , 2019, Construction and Building Materials.

[7]  Robby Caspeele,et al.  Novel active crack width control technique to reduce the variation on water permeability results for self-healing concrete , 2019, Construction and Building Materials.

[8]  Liberato Ferrara,et al.  Self-healing capability of concrete with crystalline admixtures in different environments , 2015 .

[9]  Liberato Ferrara,et al.  A methodology to assess crack-sealing effectiveness of crystalline admixtures under repeated cracking-healing cycles , 2018, Construction and Building Materials.

[10]  Marco Scalerandi,et al.  Ultrasonic Monitoring of the Interaction between Cement Matrix and Alkaline Silicate Solution in Self-Healing Systems , 2017, Materials.

[11]  Arkadiusz Kwiecień,et al.  External treatments for the preventive repair of existing constructions: A review , 2018, Construction and Building Materials.

[12]  A. Al-Tabbaa,et al.  Self-healing of drying shrinkage cracks in cement-based materials incorporating reactive MgO , 2016 .

[13]  Nele De Belie,et al.  The efficiency of self-healing cementitious materials by means of encapsulated polyurethane in chloride containing environments , 2014 .

[14]  A. Al-Tabbaa,et al.  Microfluidic fabrication of microcapsules tailored for self-healing in cementitious materials , 2018, Construction and Building Materials.

[15]  Carolyn M. Dry,et al.  Three-part methylmethacrylate adhesive system as an internal delivery system for smart responsive concrete , 1996 .

[16]  P. Dubruel,et al.  Capsules with evolving brittleness to resist the preparation of self-healing concrete , 2016 .

[17]  Nele De Belie,et al.  Self-healing phenomena in cement-based materials , 2013 .

[18]  Eirini Tziviloglou,et al.  Bacteria-based self-healing concrete to increase liquid tightness of cracks , 2016 .

[19]  J. Ollivier,et al.  Interfacial transition zone in concrete , 1995 .

[20]  Stefan Jacobsen,et al.  Effect of cracking and healing on chloride transport in OPC concrete , 1996 .

[21]  Nico Boon,et al.  Application of microorganisms in concrete: a promising sustainable strategy to improve concrete durability , 2016, Applied Microbiology and Biotechnology.

[22]  S. R. Karade,et al.  Properties of polymer-modified mortars using epoxy and acrylic emulsions , 2007 .

[23]  P. Palmero,et al.  Valorisation of alumino-silicate stone muds: From wastes to source materials for innovative alkali-activated materials , 2017 .

[24]  Mustafa Erdemir,et al.  Utilization and efficiency of ground granulated blast furnace slag on concrete properties – A review , 2016 .

[25]  P. Dubruel,et al.  Alginate biopolymers: Counteracting the impact of superabsorbent polymers on mortar strength , 2016 .

[26]  Tomoya Nishiwaki,et al.  Development of Self-Healing System for Concrete with Selective Heating around Crack , 2006 .

[27]  João P. Luís,et al.  Self-healing concrete : encapsulated polymer precursors as healing agents for active cracks , 2016 .

[28]  Liberato Ferrara,et al.  A Review of Self‐Healing Concrete for Damage Management of Structures , 2018 .

[29]  Acrylate-endcapped polymer precursors: effect of chemical composition on the healing efficiency of active concrete cracks , 2017 .

[30]  Nele De Belie,et al.  Use of silica gel or polyurethane immobilized bacteria for self-healing concrete , 2012 .

[31]  Glenn Thierens,et al.  A Novel Design of Autonomously Healed Concrete: Towards a Vascular Healing Network , 2017, Materials.

[32]  S. Van Vlierberghe,et al.  Crack Mitigation in Concrete: Superabsorbent Polymers as Key to Success? , 2017, Materials.

[33]  Hubert Rahier,et al.  Influence of mix composition on the extent of autogenous crack healing by continued hydration or calcium carbonate formation , 2012 .

[34]  Abir Al-Tabbaa,et al.  The effect of varying volume fraction of microcapsules on fresh, mechanical and self-healing properties of mortars , 2016 .

[35]  Nele De Belie,et al.  Self-Healing in Cementitious Materials—A Review , 2013 .

[36]  K. Paine,et al.  Alkaliphilic Bacillus species show potential application in concrete crack repair by virtue of rapid spore production and germination then extracellular calcite formation , 2017, Journal of applied microbiology.

[37]  Paola Antonaci,et al.  Experimental analysis of self-healing cement-based materials incorporating extruded cementitious hollow tubes , 2016 .

[38]  P. Dubruel,et al.  Visualization of water penetration in cementitious materials with superabsorbent polymers by means of neutron radiography , 2012 .

[39]  Ying Li,et al.  Preparation and application of microcapsules containing toluene-di-isocyanate for self-healing of concrete , 2019, Construction and Building Materials.

[40]  Robert John Lark,et al.  Experimental investigation of adhesive-based self-healing of cementitious materials , 2010 .

[41]  Towards encapsulation of thiol-ene mixtures: Synthesis of thioacetate cross-linker for in-situ deprotection , 2019, Materials Letters.

[42]  Nele De Belie,et al.  Quantification of the Service Life Extension and Environmental Benefit of Chloride Exposed Self-Healing Concrete. , 2016 .

[43]  Kenneth R. Lauer,et al.  Autogenous healing of cement paste , 2017 .

[44]  Nele De Belie,et al.  Pore structure description of mortars containing ground granulated blast-furnace slag by mercury intrusion porosimetry and dynamic vapour sorption , 2017 .

[45]  E. F. Wagner Autogenous Healing of Cracks in Cement‐Mortar Linings for Gray‐Iron and Ductile‐Iron Water Pipe , 1974 .

[46]  H. Van Damme,et al.  Kneading and extrusion of dense polymer-cement pastes , 2006 .

[47]  Veerle Cnudde,et al.  Comparison of different approaches for self-healing concrete in a large-scale lab test , 2016 .

[48]  João Feiteira,et al.  Screening of Different Encapsulated Polymer-Based Healing Agents for Chloride Exposed Self-Healing Concrete Using Chloride Migration Tests , 2018 .

[49]  Jun Peng,et al.  Cementitious composite manufactured by extrusion technique , 1999 .

[50]  Nele De Belie,et al.  Acoustic emission analysis for the quantification of autonomous crack healing in concrete , 2012 .

[51]  Nele De Belie,et al.  Improved model for capillary absorption in cementitious materials : progress over the fourth root of time , 2017 .

[52]  Liberato Ferrara,et al.  Effect of crystalline admixtures on the self-healing capability of early-age concrete studied by means of permeability and crack closing tests , 2016 .

[53]  G. Muyzer,et al.  Application of bacteria as self-healing agent for the development of sustainable concrete , 2010 .

[54]  Abir Al-Tabbaa,et al.  Glass encapsulated minerals for self-healing in cement based composites , 2015 .

[55]  Liberato Ferrara,et al.  Experimental characterization of the self-healing capacity of cement based materials and its effects on the material performance: A state of the art report by COST Action SARCOS WG2 , 2018 .

[56]  Veerle Cnudde,et al.  Poly(methyl methacrylate) capsules as an alternative to the 'proof-of-concept' glass capsules used in self-healing concrete , 2018 .

[57]  N. De Belie,et al.  Self-healing of moving cracks in concrete by means of encapsulated polymer precursors , 2016 .

[58]  Antonio Gliozzi,et al.  Correlation of elastic and mechanical properties of consolidated granular media during microstructure evolution induced by damage and repair , 2018 .

[59]  Carola Edvardsen,et al.  Water Permeability and Autogenous Healing of Cracks in Concrete , 1999 .

[60]  B. Lothenbach,et al.  Supplementary cementitious materials , 2011 .

[61]  Guang Ye,et al.  Feasibility of self-healing in cementitious materials – By using capsules or a vascular system? , 2014 .

[62]  Paola Antonaci,et al.  Behaviour of Pre-Cracked Self-Healing Cementitious Materials under Static and Cyclic Loading , 2020, Materials.

[63]  Ahmed Loukili,et al.  Design of polymeric capsules for self-healing concrete , 2015 .

[64]  Ahmed Loukili,et al.  Monitoring of cracking and healing in an ultra high performance cementitious material using the time reversal technique , 2009 .

[65]  Tomoya Nishiwaki,et al.  FUNDAMENTAL STUDY ON DEVELOPMENT OF INTELLIGENT CONCRETE CHARACTERIZED BY SELF-HEALING CAPABILITY FOR STRENGTH , 2000 .

[66]  Eduardus A. B. Koenders,et al.  Effect of exposure conditions on self healing behavior of strain hardening cementitious composites incorporating various cementitious materials , 2013 .

[67]  T. de Schryver,et al.  Enhanced impact energy absorption in self-healing strain-hardening cementitious materials with superabsorbent polymers , 2018, Construction and Building Materials.

[68]  Arpad Horvath,et al.  Towards sustainable concrete. , 2017, Nature materials.

[69]  A. Al-Tabbaa,et al.  Autogenous self-healing of cement with expansive minerals-I: Impact in early age crack healing , 2018, Construction and Building Materials.

[70]  Nele De Belie,et al.  Cross-linkable polyethers as healing/sealing agents for self-healing of cementitious materials , 2016 .

[71]  Kwang-Myong Lee,et al.  Parameters influencing water permeability coefficient of cracked concrete specimens , 2017 .

[72]  Nele De Belie,et al.  Self-healing mortar with pH-sensitive superabsorbent polymers: testing of the sealing efficiency by water flow tests , 2016 .

[73]  Liberato Ferrara,et al.  A “fracture testing” based approach to assess crack healing of concrete with and without crystalline admixtures , 2014 .

[74]  K. Scrivener,et al.  The Interfacial Transition Zone (ITZ) Between Cement Paste and Aggregate in Concrete , 2004 .

[75]  Patric Jacobs,et al.  Self-healing efficiency of cementitious materials containing tubular capsules filled with healing agent , 2011 .

[76]  Paola Antonaci,et al.  Setup of Extruded Cementitious Hollow Tubes as Containing/Releasing Devices in Self-Healing Systems , 2015, Materials.