论文信息 - The nature of the surface chemical bond: a comparison between the molecular and solid state pictures

The nature of the surface chemical bond: a comparison between the molecular and solid state pictures

When an adsorbate interacts with a cluster, the chemisorption energy and the reactivity are often found to oscillate as a function of cluster size. This has been demonstrated both in theoretical model calculations 1,2 and in cluster beam experiments.Since in many of the theoretical studies the cluster is used as a model for an infinite surface and the ultimate goal is to make predictions of reactivities on real metal surfaces, it is very important to understand the origin of these oscillations. Et cetera...

P. Siegbahn | I. Panas

[1] Michael C. Zerner,et al. The Challenge of d and f electrons : theory and computation , 1989 .

[2] P. Siegbahn,et al. Model studies of the chemisorption of hydrogen and oxygen on nickel surfaces , 1988 .

[3] Hermann,et al. Size dependence of surface cluster models: CO adsorbed on Cu(100). , 1987, Physical review. B, Condensed matter.

[4] K. Christmann. Relaxation and Reconstruction: How Metal Surfaces Respond to the Chemisorption of Gases , 1987 .

[5] R. Smalley,et al. Surface reactions of metal clusters. II. Reactivity surveys with D2, N2, and CO , 1985 .

[6] Cox,et al. Correspondence between electron binding energy and chemisorption reactivity of iron clusters. , 1985, Physical review letters.

[7] G. Ertl,et al. The Nature of the surface chemical bond , 1979 .