Fourier Transform Study of NMR Spin-Lattice Relaxation by

When a nuclear spin system is subjected to a repetitive sequence of strong radiofrequency pulses, a steady state is established where there is a dynamic balance between the effect of the pulses and spin relaxation. Under certain readily satisfied pulse conditions, the deviation of the intensity of the free induction signal from its thermal equilibrium value is an exponential function of the pulse interval with time constant equal to the spin–lattice relaxation time. The determination is unaffected by spin–spin relaxation provided that the interval between pulses is long enough to permit all transverse components of magnetization to be eliminated, and provided precautions are taken to inhibit spin‐echo formation. Through Fourier transformation of the transient response, high resolution spectra with many component resonances may be studied, and the spin–lattice relaxation times of the individual lines determined. The technique lends itself particularly well to repeated accumulation of the transient signal f...