Oxytree Pruned Biomass Torrefaction: Mathematical Models of the Influence of Temperature and Residence Time on Fuel Properties Improvement

Biowaste generated in the process of Oxytree cultivation and logging represents a potential source of energy. Torrefaction (a.k.a. low-temperature pyrolysis) is one of the methods proposed for the valorization of woody biomass. Still, energy is required for the torrefaction process during which the raw biomass becomes torrefied biomass with fuel properties similar to those of lignite coal. In this work, models describing the influence of torrefaction temperature and residence time on the resulting fuel properties (mass and energy yields, energy densification ratio, organic matter and ash content, combustible parts, lower and higher heating values, CHONS content, H:C and O:C ratios) were proposed according to the Akaike criterion. The degree of the models’ parameters matching the raw data expressed as the determination coefficient (R2) ranged from 0.52 to 0.92. Each model parameter was statistically significant (p < 0.05). Estimations of the value and quantity of the produced torrefied biomass from 1 Mg of biomass residues were made based on two models and a set of simple assumptions. The value of torrefied biomass (€123.4·Mg−1) was estimated based on the price of commercially available coal fuel and its lower heating value (LHV) for biomass moisture content of 50%, torrefaction for 20 min at 200 °C. This research could be useful to inform techno-economic analyses and decision-making process pertaining to the valorization of pruned biomass residues.

[1]  A. Szlek,et al.  Renewable Energy Sources: Engineering, Technology, Innovation , 2020 .

[2]  Jacek A. Koziel,et al.  Fuel Properties of Torrefied Biomass from Pruning of Oxytree , 2019, Data.

[3]  Jacek A. Koziel,et al.  The Effect of Biochar Addition on the Biogas Production Kinetics from the Anaerobic Digestion of Brewers’ Spent Grain , 2019, Energies.

[4]  A. Anandhi,et al.  Predicting biochar properties and functions based on feedstock and pyrolysis temperature: A review and data syntheses , 2019, Journal of Cleaner Production.

[5]  L. M. López-González,et al.  Evolution and perspectives of the bioenergy applications in Spain , 2019, Journal of Cleaner Production.

[6]  D. Štreimikienė,et al.  The role of bioenergy in greenhouse gas emission reduction in EU countries: An Environmental Kuznets Curve modelling , 2019, Resources, Conservation and Recycling.

[7]  Arkadiusz Dyjakon,et al.  The Influence of Apple Orchard Management on Energy Performance and Pruned Biomass Harvesting for Energetic Applications , 2019, Energies.

[8]  S. Hellweg,et al.  Spatially explicit LCA analysis of biodiversity losses due to different bioenergy policies in the European Union. , 2019, The Science of the total environment.

[9]  A. A. Adeleke,et al.  Influence of torrefaction on lignocellulosic woody biomass of nigerian origin , 2019 .

[10]  J. Leahy,et al.  Surface characterization of Miscanthus × giganteus and Willow subjected to torrefaction , 2019, Journal of Analytical and Applied Pyrolysis.

[11]  M. Brusseau,et al.  Physical-Chemical Characteristics of Water , 2019, Environmental and Pollution Science.

[12]  W. Grzywiński,et al.  The use of wood and the possibility of planting trees of the Paulownia genus , 2018 .

[13]  Liang Wang,et al.  Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark , 2018, Applied Energy.

[14]  Simeng Li,et al.  Thermogravimetric, thermochemical, and infrared spectral characterization of feedstocks and biochar derived at different pyrolysis temperatures. , 2018, Waste management.

[15]  Y. Hsieh,et al.  Nitrogen retention of biochar derived from different feedstocks at variable pyrolysis temperatures , 2018, Journal of Analytical and Applied Pyrolysis.

[16]  P. Quicker,et al.  Properties of biochar , 2018 .

[17]  Z. Romanowska-Duda,et al.  Experimental Studies on Energy Crops Torrefaction Process Using Batch Reactor to Estimate Torrefaction Temperature and Residence Time , 2018 .

[18]  L. Nunes,et al.  Torrefaction of woody biomasses from poplar SRC and Portuguese roundwood: Properties of torrefied products , 2018 .

[19]  M. M. Rahman,et al.  Biochar properties and eco-friendly applications for climate change mitigation, waste management, and wastewater treatment: A review , 2017 .

[20]  Liang Wang,et al.  Impact of Torrefaction on Woody Biomass Properties , 2017 .

[21]  Y. Levendis,et al.  Carbon, sulfur and nitrogen oxide emissions from combustion of pulverized raw and torrefied biomass , 2017 .

[22]  J. Tumuluru Comparison of Chemical Composition and Energy Property of Torrefied Switchgrass and Corn Stover , 2015, Front. Energy Res..

[23]  Wei Hsin Chen,et al.  A state-of-the-art review of biomass torrefaction, densification and applications , 2015 .

[24]  I. Đukić,et al.  Specific Heat Capacity of Wood , 2014 .

[25]  J. Bocanegra,et al.  Biomass Yield Potential of Paulownia Trees in a , 2013 .

[26]  Wei Hsin Chen,et al.  Product Yields and Characteristics of Corncob Waste under Various Torrefaction Atmospheres , 2013 .

[27]  C. Söderberg,et al.  Rising policy conflicts in Europe over bioenergy and forestry , 2013 .

[28]  F. Verhoeff,et al.  Ash-Forming Matter in Torrefied Birch Wood: Changes in Chemical Association , 2013 .

[29]  J. R. Hess,et al.  REVIEW: A review on biomass torrefaction process and product properties for energy applications , 2011 .

[30]  Kj Krzysztof Ptasinski,et al.  Biomass upgrading by torrefaction for the production of biofuels: A review , 2011 .

[31]  S. Mani,et al.  Impact of torrefaction on the grindability and fuel characteristics of forest biomass. , 2011, Bioresource technology.

[32]  M. Ahmedna,et al.  CHARACTERIZATION OF DESIGNER BIOCHAR PRODUCED AT DIFFERENT TEMPERATURES AND THEIR EFFECTS ON A LOAMY SAND , 2009 .

[33]  J. Faganeli,et al.  H/C versus O/C atomic ratio characterization of selected coals in Slovenia , 2007 .

[34]  R. Zanzi,et al.  Torrefied Biomass a Substitute for Wood and Charcoal , 2002 .