Copper(II) Acetate as a Motif for Metal-Assembled Complexes

In this review, a new method for the preparation of metal-assembled complexes based on copper(II) acetate type dinuclear systems has been reported. A variety of coordination modes of carboxylato group were classified into ten types of groups including bis-, tris-, and tetrakis-bridging based on our complexes and discussed in relation to mononuclear, dinuclear, oligonuclear, and polynuclear systems. An interdimer interaction could not be observed in temperature dependence of magnetic susceptibilities at 4.5—300 K region in case of one-dimensional chain systems of copper(II) pivalate with N,N'-bidentate ligands such as pyrazine, 4,4'-bipyridine, 1,4-diazabicyclo[2.2.2]octane. Adsorption property for nitrogen gas was found in a chain system of copper(II) benzoate with pyrazine. Mesomorphic properties were also found for chain systems of copper(II) carboxylates with long alkyl chains. By using copper(II) trichloroacetate, a chain molecule consisting of alternated arrangement of tetranuclear cubane and pyrazine was isolated. Two-dimensional and three-dimensional assembled complexes were obtained by reactions of copper(II) trifluoroacetate and copper(II) propionate, respectively, with pyrazine. Bis-adducts of copper(II) propionate with pyridyl nitronyl nitroxides, copper(II) acetate with a stable adamantanyloxyamino radical, and dinuclear copper(II) complexes with 4-carboxy-2,2,6,6-tetramethylpiperidinyloxy and 3-carboxy-2,2,5,5-tetramethyl-1-pyrrolidinyloxy were prepared as radical-containing copper(II) acetate systems.

[1]  M. Mikuriya,et al.  Synthesis and Structural Characterization of Dinuclear Manganese(III) Complexes with Cyclam-Based Macrocyclic Ligands Having Schiff-Base Pendant Arms as Chelating Agents , 2008 .

[2]  M. Mikuriya,et al.  Syntheses, Crystal Structures, and Magnetic Properties of a Stable Aminoxyl Radical and Its Copper(II) Complex , 2008 .

[3]  M. Mikuriya,et al.  Dinuclear copper(II) complexes with {Cu2(mu-hydroxo)bis(mu-carboxylato)}+ cores and their reactions with sugar phosphate esters: A substrate binding model of fructose-1,6-bisphosphatase. , 2006, Inorganic chemistry.

[4]  M. Mikuriya,et al.  One-Dimensional Coordination Polymers from the Self-Assembly of Copper(II) Carboxylates and 4,4′-Dithiobis(pyridine) , 2005 .

[5]  H. Sakiyama,et al.  Synthesis, structure, and magnetic properties of dinuclear nickel(II) complexes with a phenol-based dinucleating ligand with four methoxyethyl chelating arms , 2005 .

[6]  M. Mikuriya,et al.  Oligonuclear Metal-Assembly of Antiferromagnetic Ni4 and Ferromagnetic Ni6 Clusters with Non-Schiff-Base Tetradentate Ligand. , 2003 .

[7]  M. Mikuriya,et al.  Alkoxo-Bridged Dinuclear and Tetranuclear Copper(II) Complexes with Schiff-Bases Derived from Benzoylacetone and 1,n-Diamino-n'-hydroxyalkanes (n, n' = 3, 2; 4, 2; and 5, 3). , 2002 .

[8]  MikuriyaMasahiro,et al.  Dinuclear Copper(II) Complexes of Free Radical Carboxylic Acids , 2002 .

[9]  T. Tokii,et al.  Synthesis and Structural Characterization of Di-μ-Phenoxo-Bridged Dinuclear Iron(III) Complexes with Ferromagnetic or Weak Antiferromagnetic Coupling , 2001 .

[10]  Katsunori Tanaka,et al.  Antiferromagnetic Adducts of Copper(II) Propionate with Pyridyl Nitronyl Nitroxides. , 2000 .

[11]  R. E. Del Sesto,et al.  Copper(II) benzoate nitroxide dimers and chains: structure and magnetic studies. , 2000, Inorganic chemistry.

[12]  J. Sutter,et al.  A dimeric Cu(II) acetate complex containing axially coordinated p-pyridyl nitronyl nitroxide radicals: [CuII(CH3COO)2(NITpPy)]2 , 2000 .

[13]  H. Azuma,et al.  Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4,4′-Bipyridine, 1,4-Diazabicyclo[2.2.2]octane, Triethylamine, and Pyridine , 1999 .

[14]  Gene-Hsiang Lee,et al.  MAGNETO-STRUCTURAL CORRELATION OF DIMERIC COPPER(II) CARBOXYLATES WITH PYRIDYL-SUBSTITUTED NITRONYL NITROXIDES , 1999 .

[15]  M. Mikuriya,et al.  New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring , 1999 .

[16]  M. Mikuriya,et al.  Structural Characterization and Magnetic Properties of Triply Carboxylato-Bridged Dinuclear Copper(II) Complexes , 1999 .

[17]  S. Takamizawa,et al.  Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine , 1999 .

[18]  H. Azuma,et al.  Synthesis, X-Ray Structures, and Magnetic Properties of [Cu2(piv)4(Et3N)2] and [Cu6(piv)6(EtO)6] (Hpiv = Pivalic Acid): Role of Base for Dinuclear Adduct and Oligonuclear Formation , 1999 .

[19]  M. Mikuriya,et al.  Unexpected coordination behavior of dinucleating ligand: infinite zigzag chain of alternating sodium(I) and dinuclear-zinc(II) units , 1998 .

[20]  M. Mikuriya,et al.  Synthesis and Structural Characterization of Manganese(II) Complexes with N,N′-Bis(2-pyridylmethylene)-1,3-diaminopropan-2-ol or N,N′-Bis(2-pyridylmethylene)-1,3-propanediamine , 1997 .

[21]  M. Sundberg,et al.  Comparison of the structural parameters in copper(II) acetate-type dimers containing distorted square pyramidal CuO4O and CuO4N chromophores , 1996 .

[22]  A. Kawamori,et al.  Synthesis of a Tetranuclear Manganese Complex with a Cubane Core at the MnIIMnIIIMnIIMnIII Oxidation Level , 1995 .

[23]  M. Mikuriya,et al.  Synthesis and Characterization of Tetranuclear Manganese (III) Complexes with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol , 1995 .

[24]  M. Handa,et al.  Chain Compounds Formed by the Reaction of Copper(II) Carboxylate [Cu2(O2CR)4] (R = C(CH3)3, CCl3) and Bridging Ligand L (L = Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane) , 1995 .

[25]  S. Ohba.  Crystal Structures and Magnetic Properties of Dimeric Copper Carboxylates , 1993 .

[26]  A. Kawamori,et al.  Synthesis and Characterization of Mononuclear (Mn(II) and Mn(III)) and Dinuclear (Mn(II)Mn(II) and Mn(II)Mn(III)) Complexes with 2,6-Bis[N-(2-pyridylethyl)iminomethyl]-4-methylphenol , 1993 .

[27]  M. Mikuriya,et al.  Synthesis, properties, and crystal structures of a series of dinuclear manganese(III) complexes with 1,5-bis(salicylideneamino)3-pentanol and various anions : formation of a tetranuclear manganese(III) complex , 1992 .

[28]  N. E. Sherman.  Ultrasonic velocity and attenuation in aqueous kaolin dispersions , 1991 .

[29]  H. Uekusa,et al.  Structural comparisons between copper(II) triorganosilanecarboxylate, -germanecarboxylate and -acetate dimers , 1990 .

[30]  K. Kasamatsu,et al.  Linear Chain Compounds of Molybdenum(II) Acetate Dimer Linked by Linear-bidentate Ligands, Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane , 1990 .

[31]  T. Tokii,et al.  Structural, magnetic and spectroscopic characterization of novel di-μ-carboxylato-bridged binuclear copper(II) complexes with 1,10-phenanthroline , 1990 .

[32]  M. Mikuriya,et al.  Synthesis and characterization of trinuclear Schiff-base complexes containing sulphur dioxide or hydrogensulphite ions as bridging groups. Crystal structure of [Zn{(µ-CH3CO2)(salpd-µ-O,O′)Cu}2][salpd = propane-1,3-diylbis(salicylideneiminate)] , 1990 .

[33]  M. Handa,et al.  A Thiolate-Bridged Binuclear Nickel(II) Complex with a Tripod-like N3S-ligand. Formation of a Novel Disulfide-Bridged Binuclear Nickel(II) Complex , 1989 .

[34]  Y. Muto,et al.  Factors affecting the magnetic properties of dimeric copper(II) complexes , 1988 .

[35]  M. Mikuriya,et al.  Syntheses and Characterization of Dinuclear Manganese(II,II) and Manganese(II,III) Complexes with Phenolate and Two Carboxylate Bridges , 1987 .

[36]  M. Mikuriya,et al.  Crystal and Molecular Structures of [Cu2(taec)X](ClO4)3·nH2O (taec=N,N′,N″,N'″-Tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane; X=I, F, NO2, and CH3COO; n=0, 1, or 2). Effect of Incorporation of an Anion X on the Structure of the Complex Cation , 1987 .

[37]  T. Tarantelli,et al.  Exchange interaction in multinuclear transition-metal complexes. 9. Magnetostructural correlations in one-atom acetato-bridged copper(II) dimers , 1986 .

[38]  J. Pletcher,et al.  Carboxysilanes and -germanes. 5. Copper(II) complexes of carboxysilanes and -germanes: structure and magnetic properties. Crystal structure of tetrakis(.mu.-phenyldimethylsilanecarboxylato)bis[aquocopper(II)] , 1986 .

[39]  T. Tarantelli,et al.  Exchange interaction in multinuclear transition-metal complexes. 8. Structural and magnetic studies on bis(acetato)bis(N-methyl-N'-(5-methoxysalicylidene)-1,3-propanediaminato)dicopper dihydrate, a novel "structural" ladderlike compound with "magnetic" alternating-chain behavior , 1986 .

[40]  R. Doedens,et al.  Nitroxyl adducts of copper(II) trihaloacetates: diamagnetic copper(II) complexes with a novel dimeric structure , 1986 .

[41]  W. K. Musker,et al.  Magnetic properties and structural characterizations of dichloro(2,5-dithiahexane)copper(II) and dichloro(4,7-dithiadecane)copper(II): observation of Heisenberg alternating-chain magnetism , 1986 .

[42]  M. Mikuriya,et al.  Structural, Magnetic and IR Spectroscopic Characterization of Dimeric Copper(II) Trichloroacetate Adduct with Benzonitrile. Nature of the Copper(II)–Bezonitrile Bond , 1985 .

[43]  R. Doedens,et al.  Preparation and crystal structure of a diamagnetic copper(II) trichloroacetate complex containing a nitroxyl radical ligand , 1985 .

[44]  M. Melnik.  Study of the relation between the structural data and magnetic interaction in oxo-bridged binuclear copper(II) compounds , 1982 .

[45]  M. Mikuriya,et al.  Binuclear Metal Complexes. XXXVII. Crystal and Molecular Structure of a Binuclear Manganese(III) Complex Bridged by Two Alkoxo Oxygens and Two Bidentate Acetate Ions , 1981 .

[46]  M. Mikuriya,et al.  The Crystal Structure and Magnetic Property of Di-μ-propionato-O,O′-bis[N-p-tolylsalicylideneaminatocopper(II)] , 1977 .

[47]  J. Catterick,et al.  Structures and Physical Properties of Polynuclear Carboxylates , 1977 .

[48]  T. Tokii,et al.  Preparative and Magnetic Studies of Several Binuclear Copper(II) Alkanoate Complexes with Salicylideneamines , 1976 .

[49]  Roald Hoffmann,et al.  Orbital interactions in metal dimer complexes , 1975 .

[50]  Z. Soos,et al.  Interdimer exchange in linear chain copper acetate-pyrazine , 1974 .

[51]  H. B. Jonassen,et al.  Copper(II) Complexes with Subnormal Magnetic Moments , 1964 .

[52]  H. Nakamura,et al.  Spectrochemical Study of Microscopic Crystals. XVI. Structure of Cupric Formate, Acetate and Propionate , 1957 .

[53]  F. Schoening,et al.  X-Ray Evidence for Metal-to-Metal Bonds in Cupric and Chromous Acetate , 1953, Nature.