JEM spotlight: Environmental monitoring of airborne nanoparticles.

The aim of this work was to review the existing instrumental methods to monitor airborne nanoparticles in different types of indoor and outdoor environments in order to detect their presence and to characterise their properties. Firstly the terminology and definitions used in this field are discussed, which is followed by a review of the methods to measure particle physical characteristics including number, concentration, size distribution and surface area. An extensive discussion is provided on the direct methods for particle elemental composition measurements, as well as on indirect methods providing information on particle volatility and solubility, and thus in turn on volatile and semivolatile compounds of which the particle is composed. A brief summary of broader considerations related to nanoparticle monitoring in different environments concludes the paper.

[1]  K. Hämeri,et al.  A novel tandem differential mobility analyzer with organic vapor treatment of aerosol particles , 2001 .

[2]  G. Mcfiggans,et al.  Inversion of tandem differential mobility analyser (TDMA) measurements , 2009 .

[3]  Tareq Hussein,et al.  Diurnal and annual characteristics of particle mass and number concentrations in urban, rural and Arctic environments in Finland , 2003 .

[4]  Finn Palmgren,et al.  Experimental studies of ultrafine particles in streets and the relationship to traffic , 2001 .

[5]  Yifang Zhu,et al.  Seasonal Trends of Concentration and Size Distribution of Ultrafine Particles Near Major Highways in Los Angeles Special Issue of Aerosol Science and Technology on Findings from the Fine Particulate Matter Supersites Program , 2004 .

[6]  Lidia Morawska,et al.  Concentrations of submicrometre particles from vehicle emissions near a major road , 2000 .

[7]  J. Smith,et al.  Thermal Desorption Chemical Ionization Mass Spectrometer for Ultrafine Particle Chemical Composition , 2003 .

[8]  D. Westerdahl,et al.  Characterization of on-road vehicle emission factors and microenvironmental air quality in Beijing, China , 2009 .

[9]  Bert Brunekreef,et al.  Concentrations of ultrafine, fine and PM2.5 particles in three European cities , 2001 .

[10]  M. Röösli,et al.  Airborne particle number profiles, particle mass distributions and particle-bound PAH concentrations within the city environment of Basel: an assessment as part of the BRISKA Project , 2000 .

[11]  Roy M. Harrison,et al.  Sources and concentration of nanoparticles (<10 nm diameter) in the urban atmosphere , 2001 .

[12]  D. Collins,et al.  Physical and chemical properties of the aerosol within the southeastern Pacific marine boundary layer , 2007 .

[13]  P. Paatero,et al.  Modal structure and spatial-temporal variations of urban and suburban aerosols in Helsinki-Finland , 2005 .

[14]  Z. Ristovski,et al.  Intercomparison study of six HTDMAs: results and general recommendations for HTDMA operation , 2008 .

[15]  Liisa Pirjola,et al.  Winter and summer time size distributions and densities of traffic-related aerosol particles at a busy highway in Helsinki , 2006 .

[16]  M. Emmenegger,et al.  The epiphaniometer, a new device for continuous aerosol monitoring , 1988 .

[17]  Simona Silvia Merola,et al.  The Diesel Exhaust Aftertreatment (DEXA) Cluster: A Systematic Approach to Diesel Particulate Emission Control in Europe , 2004 .

[18]  P. Mcmurry,et al.  Aerodynamic Focusing of Nanoparticles: I. Guidelines for Designing Aerodynamic Lenses for Nanoparticles , 2005 .

[19]  Peter H. McMurry,et al.  A Design Tool for Aerodynamic Lens Systems , 2006 .

[20]  L Morawska,et al.  A model for determination of motor vehicle emission factors from on-road measurements with a focus on submicrometer particles. , 2001, The Science of the total environment.

[21]  J. Pettersson,et al.  Chemical Analysis of Individual Alkali-Containing Aerosol Particles: Design and Performance of a Surface Ionization Particle Beam Mass Spectrometer , 2004 .

[22]  Kerrie Mengersen,et al.  Spatial variation in particle number size distributions in a large metropolitan area , 2007 .

[23]  Matthias Ketzel,et al.  Particle and trace gas emission factors under urban driving conditions in Copenhagen based on street and roof-level observations , 2003 .

[24]  S. Hering,et al.  Performance Evaluation of a Recently Developed Water-Based Condensation Particle Counter , 2005 .

[25]  D. Kittelson,et al.  The influence of dilution conditions on diesel exhaust particle size distribution measurements , 1999 .

[26]  L. Morawska,et al.  Hygroscopic behavior of partially volatilized coastal marine aerosols using the volatilization and humidification tandem differential mobility analyzer technique , 2005 .

[27]  David B. Kittelson,et al.  Nanoparticle emissions on Minnesota highways , 2004 .

[28]  Gwi-Nam Bae,et al.  Monitoring Multiwalled Carbon Nanotube Exposure in Carbon Nanotube Research Facility , 2008 .

[29]  Roy M. Harrison,et al.  Measurements of the physical properties of particles in the urban atmosphere , 1999 .

[30]  Sara Janhäll,et al.  Roadside measurements of fine and ultrafine particles at a major road north of Gothenburg , 2002 .

[31]  S. J. Gregg,et al.  Adsorption Surface Area and Porosity , 1967 .

[32]  P. Laj,et al.  Design and Validation of a Volatility Hygroscopic Tandem Differential Mobility Analyzer (VH-TDMA) to Characterize the Relationships Between the Thermal and Hygroscopic Properties of Atmospheric Aerosol Particles , 2008 .

[33]  Hiroaki Minoura,et al.  Roadside nanoparticles corresponding to vehicle emissions during one signal cycle , 2009 .

[34]  M. Gallagher,et al.  A case study of aerosol (4.6 nm, 2003 .

[35]  G. Oberdörster,et al.  Nanotoxicology: An Emerging Discipline Evolving from Studies of Ultrafine Particles , 2005, Environmental health perspectives.

[36]  Alla Zelenyuk,et al.  SPLAT II: An Aircraft Compatible, Ultra-Sensitive, High Precision Instrument for In-Situ Characterization of the Size and Composition of Fine and Ultrafine Particles , 2009 .

[37]  T. Petäjä,et al.  On Operation of the Ultra-Fine Water-Based CPC TSI 3786 and Comparison with Other TSI Models (TSI 3776, TSI 3772, TSI 3025, TSI 3010, TSI 3007) , 2008 .

[38]  B. Cohen,et al.  Deposition of charged particles on lung airways. , 1998, Health physics.

[39]  Andrew D. Maynard,et al.  Overview of methods for analysing single ultrafine particles , 2000, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[40]  L. Morawska,et al.  Diesel bus emissions measured in a tunnel study. , 2004, Environmental science & technology.

[41]  J C Chow,et al.  Measurement methods to determine compliance with ambient air quality standards for suspended particles. , 1995, Journal of the Air & Waste Management Association.

[42]  Tomas Baer,et al.  Aerosol mass spectrometry: An introductory review , 2006 .

[43]  Sara Janhäll,et al.  Size resolved traffic emission factors of submicrometer particles , 2004 .

[44]  J. Schneider,et al.  In situ measurements of particle number concentration, chemically resolved size distributions and black carbon content of traffic-related emissions on German motorways, rural roads and in city traffic , 2008 .

[45]  Kerrie Mengersen,et al.  Differences in airborne particle and gaseous concentrations in urban air between weekdays and weekends , 2002 .

[46]  Kimberly A Prather,et al.  Recent advances in our understanding of atmospheric chemistry and climate made possible by on-line aerosol analysis instrumentation. , 2005, Analytical chemistry.

[47]  Annette Peters,et al.  Source apportionment of ambient fine particle size distribution using positive matrix factorization in Erfurt, Germany. , 2008, The Science of the total environment.

[48]  G. P. Wyers,et al.  THE STEAM-JET AEROSOL COLLECTOR , 1995 .

[49]  Xin-Zhong Liang,et al.  Climatic forcing of nitrogen oxides through changes in tropospheric ozone and methane; global 3D model studies , 1999 .

[50]  B. Wehner,et al.  Particle number size distributions in a street canyon and their transformation into the urban-air background: measurements and a simple model study , 2002 .

[51]  K. Prather,et al.  Analysis of atmospheric aerosols. , 2008, Annual review of analytical chemistry.

[52]  K. Lehtinen,et al.  The composition of nucleation and Aitken modes particles during coastal nucleation events: evidence for marine secondary organic contribution , 2006 .

[53]  K. Okuyama,et al.  Performance Evaluation of an Improved Particle Size Magnifier (PSM) for Single Nanoparticle Detection , 2003 .

[54]  Linsey C Marr,et al.  Characterization of airborne particles during production of carbonaceous nanomaterials. , 2008, Environmental science & technology.

[55]  Matthias Ketzel,et al.  Particle size distribution and particle mass measurements at urban,near-city and rural level in the Copenhagen area and Southern Sweden , 2003 .

[56]  Tami C. Bond,et al.  Calibration and Intercomparison of Filter-Based Measurements of Visible Light Absorption by Aerosols , 1999 .

[57]  H. Wichmann,et al.  Variation of particle number and mass concentration in various size ranges of ambient aerosols in Eastern Germany , 1997 .

[58]  J. Smith,et al.  Sampling nanoparticles for chemical analysis by low resolution electrical mobility classification. , 2009, Environmental science & technology.

[59]  Yifang Zhu,et al.  Study of ultrafine particles near a major highway with heavy-duty diesel traffic , 2002 .

[60]  David Y. H. Pui,et al.  Use of Continuous Measurements of Integral Aerosol Parameters to Estimate Particle Surface Area , 2001 .

[61]  Christer Johansson,et al.  Simulation of NOx and ultrafine particles in a street canyon in Stockholm, Sweden , 2004 .

[62]  K. Prather,et al.  Real-time characterization of individual aerosol particles using time-of-flight mass spectrometry , 1994 .

[63]  J. Smith,et al.  Atmospheric Measurements of Sub-20 nm Diameter Particle Chemical Composition by Thermal Desorption Chemical Ionization Mass Spectrometry , 2004 .

[64]  Mats Gustafsson,et al.  Traffic-generated emissions of ultrafine particles from pavement–tire interface , 2006 .

[65]  P. Paatero,et al.  Estimating time series of aerosol particle number concentrations in the five HEAPSS cities on the basis of measured air pollution and meteorological variables , 2005 .

[66]  Yifang Zhu,et al.  The morphology of ultrafine particles on and near major freeways , 2008 .

[67]  H. Wichmann,et al.  Change of the ambient particle size distribution in East Germany between 1993 and 1999 , 2001 .

[68]  A. Harris,et al.  Thermal observations of gas pistoning at Kilauea Volcano , 2005 .

[69]  Mark J. Nieuwenhuijsen,et al.  Exposure visualisation of ultrafine particle counts in a transport microenvironment , 2006 .

[70]  Lidia Morawska,et al.  The relationship between indoor and outdoor airborne particles in the residential environment , 2001 .

[71]  U. Baltensperger,et al.  Hygroscopic properties of submicrometer atmospheric aerosol particles measured with H-TDMA instruments in various environments—a review , 2008 .

[72]  Karine Sellegri,et al.  Seasonal variation of aerosol size distributions in the free troposphere and residual layer at the puy de Dôme station, France , 2009 .

[73]  Andrey Khlystov,et al.  Ambient aerosol size distributions and number concentrations measured during the Pittsburgh Air Quality Study (PAQS) , 2004 .

[74]  Zoran Ristovski,et al.  Experimental investigation of ultra-fine particle size distribution near a busy road , 2004 .

[75]  Yifang Zhu,et al.  Concentration and Size Distribution of Ultrafine Particles Near a Major Highway , 2002, Journal of the Air & Waste Management Association.

[76]  M. Hallquist,et al.  Evolution of the urban aerosol during winter temperature inversion episodes , 2006 .

[77]  J. Finkelstein,et al.  Acute pulmonary effects of ultrafine particles in rats and mice. , 2000, Research report.

[78]  Scott Fruin,et al.  Mobile platform measurements of ultrafine particles and associated pollutant concentrations on freeways and residential streets in Los Angeles , 2005 .

[79]  H. Hansson,et al.  One year boundary layer aerosol size distribution data from five nordic background stations , 2003 .

[80]  Paul J. Webb,et al.  Partially oxidised organic components in urban aerosol using GCXGC-TOF/MS , 2004 .

[81]  A. Wiedensohler,et al.  Long term measurements of submicrometer urban aerosols: statistical analysis for correlations with meteorological conditions and trace gases , 2002 .

[82]  J. Smith,et al.  An Ultrafine, Water-Based Condensation Particle Counter and its Evaluation under Field Conditions , 2008 .

[83]  Ashok Gidwani,et al.  Aerodynamic Focusing of Nanoparticles: II. Numerical Simulation of Particle Motion Through Aerodynamic Lenses , 2005 .

[84]  Christer Johansson,et al.  Urban scale modeling of particle number concentration in Stockholm , 2005 .

[85]  M. Johnston,et al.  Nanoparticle Mass Spectrometry: Pushing the Limit of Single Particle Analysis , 2006, Applied spectroscopy.

[86]  E. R. Jayaratne,et al.  Spatial distribution of submicrometre particles and CO in an urban microscale environment , 2005 .

[87]  J. Putaud,et al.  Nucleation and growth of new particles in the rural atmosphere of Northern Italy—relationship to air quality monitoring , 2005 .

[88]  Lidia Morawska,et al.  Size selected particles in an urban atmosphere of Brisbane, Australia , 2002 .

[89]  R. Harrison,et al.  Nanotechnology : consequences for human health and the environment , 2007 .

[90]  Hanna Vehkamäki,et al.  Formation and growth rates of ultrafine atmospheric particles: a review of observations , 2004 .

[91]  Y. Song,et al.  Exposure to nanoparticles is related to pleural effusion, pulmonary fibrosis and granuloma , 2009, European Respiratory Journal.

[92]  Markus Kasper Sampling and Measurement of Nanoparticle Emissions for Type Approval and Field Control , 2005 .

[93]  Pasi Aalto,et al.  Atmospheric Chemistry and Physics Discussions , 2001 .

[94]  K. T. Whitby,et al.  The aerosol mobility chromatograph: A new detector for sulfuric acid aerosols , 1978 .

[95]  M. Johnston,et al.  Airborne nanoparticle characterization with a digital ion trap–reflectron time of flight mass spectrometer , 2006 .

[96]  Michael Wensing,et al.  Ultra-fine particles release from hardcopy devices: sources, real-room measurements and efficiency of filter accessories. , 2008, The Science of the total environment.

[97]  R. Jayaratne,et al.  Development of a methodology for the quantification of particle number and gaseous concentrations in a bidirectional bus tunnel and the derivation of emission factors , 2008 .

[98]  L. Morawska,et al.  Exploratory cross-sectional investigations on ambient submicrometer particles in Salzburg, Austria , 2004 .

[99]  Stefanie Hellweg,et al.  Exposure to manufactured nanostructured particles in an industrial pilot plant. , 2008, The Annals of occupational hygiene.

[100]  Jian Wang,et al.  Fast Mixing Condensation Nucleus Counter: Application to Rapid Scanning Differential Mobility Analyzer Measurements , 2002 .

[101]  John A. Gillies,et al.  Exhaust Particle Size Distribution Measurements at the Tuscarora Mountain Tunnel , 2002 .

[102]  Jorma Keskinen,et al.  Electrical low pressure impactor , 1992 .

[103]  M. Stolzenburg,et al.  A Laminar-Flow, Water-Based Condensation Particle Counter (WCPC) , 2005 .

[104]  G. Kasper,et al.  Temporal evolution of nanoparticle aerosols in workplace exposure. , 2008, The Annals of occupational hygiene.

[105]  Hannes Tammet,et al.  Electrical aerosol spectrometer of Tartu University , 2002 .

[106]  P. Mcmurry,et al.  Size distributions of 3-100-nm urban Atlanta aerosols: measurement and observations. , 2002, Journal of aerosol medicine : the official journal of the International Society for Aerosols in Medicine.

[107]  Cheol-Heon Jeong,et al.  Characteristics of nucleation and growth events of ultrafine particles measured in Rochester, NY. , 2004, Environmental science & technology.

[108]  K. Leszczynski,et al.  The investigations of aerosol particle formation in urban background area of Helsinki , 1996 .

[109]  Alfred Wiedensohler,et al.  Particle number size distribution in the urban atmosphere of Beijing, China , 2008 .

[110]  David M. Brown,et al.  Size-dependent proinflammatory effects of ultrafine polystyrene particles: a role for surface area and oxidative stress in the enhanced activity of ultrafines. , 2001, Toxicology and applied pharmacology.

[111]  Quantification of Hourly Speciated Organic Compounds in Atmospheric Aerosols, Measured by an In-Situ Thermal Desorption Aerosol Gas Chromatograph (TAG) , 2009 .

[112]  U. Lohmann,et al.  Ice Nucleation Studies of Mineral Dust Particles with a New Continuous Flow Diffusion Chamber , 2006 .

[113]  Peng Liu,et al.  Generating Particle Beams of Controlled Dimensions and Divergence: II. Experimental Evaluation of Particle Motion in Aerodynamic Lenses and Nozzle Expansions , 1995 .

[114]  H. Burtscher Physical characterization of particulate emissions from diesel engines: a review , 2005 .

[115]  Martin Mohr,et al.  Mobile measurements of aerosol number and volume size distributions in an Alpine valley: Influence of traffic versus wood burning , 2009 .

[116]  R. Gehrig,et al.  Real-world emission factors of fine and ultrafine aerosol particles for different traffic situations in Switzerland. , 2005, Environmental science & technology.

[117]  Kaarle Hämeri,et al.  Indoor and outdoor particle size characterization at a family house in Espoo-Finland , 2005 .

[118]  A. Wexler,et al.  Ultrafine nitrate particle events in Baltimore observed by real-time single particle mass spectrometry , 2004 .

[119]  B. LaFranchi,et al.  A comprehensive characterization of photoelectron resonance capture ionization aerosol mass spectrometry for the quantitative and qualitative analysis of organic particulate matter , 2006 .

[120]  M. Cheng,et al.  Characterization of ultrafine and fine particles at a site near the Great Smoky Mountains National Park , 2002 .

[121]  J. Chow,et al.  The application of thermal methods for determining chemical composition of carbonaceous aerosols: A review , 2007, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[122]  Peter H. McMurry,et al.  A review of atmospheric aerosol measurements , 2000 .

[123]  Satya Sardar,et al.  Size-fractionated measurements of ambient ultrafine particle chemical composition in Los Angeles using the NanoMOUDI. , 2005, Environmental science & technology.

[124]  J. Morin,et al.  On-road measurements of particle number concentrations and size distributions in urban and tunnel environments , 2004 .

[125]  R. Hillamo,et al.  Urban and rural ultrafine (PM0.1) particles in the Helsinki area , 2001 .

[126]  Luca Stabile,et al.  Temporal size distribution and concentration of particles near a major highway , 2009 .

[127]  Nicholas Good,et al.  Analysis of the hygroscopic and volatile properties of ammonium sulphate seeded and unseeded SOA particles , 2008 .

[128]  J. Joutsensaari,et al.  A method for detecting the presence of organic fraction in nucleation mode sized particles , 2005 .

[129]  David B. Kittelson,et al.  Generating Particle Beams of Controlled Dimensions and Divergence: I. Theory of Particle Motion in Aerodynamic Lenses and Nozzle Expansions , 1995 .

[130]  Zoran Ristovski,et al.  Ambient nano and ultrafine particles from motor vehicle emissions: Characteristics, ambient processing and implications on human exposure , 2008 .

[131]  Ernest Weingartner,et al.  Fine and ultrafine particles in the Zürich (Switzerland) area measured with a mobile laboratory: an assessment of the seasonal and regional variation throughout a year , 2003 .

[132]  W. Whitten,et al.  Detection of chemical warfare-related species on complex aerosol particles deposited on surfaces using an ion trap-based aerosol mass spectrometer. , 2007, Analytical chemistry.

[133]  Zoran Ristovski,et al.  New methods of determination of average particle emission factors for two groups of vehicles on a busy road , 2004 .

[134]  P. Baron,et al.  Exposure to Carbon Nanotube Material: Aerosol Release During the Handling of Unrefined Single-Walled Carbon Nanotube Material , 2004, Journal of toxicology and environmental health. Part A.

[135]  M. Väkevä,et al.  Street level versus rooftop concentrations of submicron aerosol particles and gaseous pollutants in an urban street canyon , 1999 .

[136]  Jie Yang,et al.  Tandem Measurements of Aerosol Properties—A Review of Mobility Techniques with Extensions , 2008 .

[137]  Daniel M. Murphy,et al.  Something in the Air , 2005, Science.

[138]  Teresa Moreno,et al.  Variations of Urban Aerosols in the Western Mediterranean , 2008 .

[139]  Zoran Ristovski,et al.  Relation between particle mass and number for submicrometer airborne particles , 1999 .