Evaluation of the possibility of copper recovery from tailings by flotation through bench-scale, commissioning, and industrial tests

Abstract The present research aims at recovering copper by reprocessing of tailings at China Molybdenum Co. Ltd. (CMOC) from bench-scale to industrial tests. It focuses on the determination of the reagents' dosage and pulp concentration that enables to obtain the highest recovery of copper by flotation of the studied tailings. Based on the results of bench-scale tests, commissioning and industrial tests were conducted at CMOC and satisfactory results were achieved. Compared to the prior year's database, it was concluded that the reprocessing of tailings by flotation appeared to be an attractive practice because it could enable to minimize the footprint of mineral processing on the local environment. Meanwhile, the reprocessing of tailing could generate an extra profit of $1,205 800 per year for CMOC. Furthermore, the application of this technique at Sanqiang flotation plant was considered to be successful. These results indicate that the studied tailings represents an important source of secondary raw material for the extraction of copper and it opens up an alternative way for greening copper extraction. Finally, it is proved that the reprocessing of tailing by flotation is reliable, economical and promising in copper extraction industry, and therefore, cleaner production of copper concentrate is feasible.

[1]  R. Schibli,et al.  “2 + 1” Dithiocarbamate–isocyanide chelating systems for linking M(CO)3+ (M = 99mTc, Re) fragment to biomolecules , 2004 .

[2]  J. Laskowski,et al.  Review of the flotation of molybdenite. Part I: Surface properties and floatability , 2016 .

[3]  G. Mudd The Environmental sustainability of mining in Australia: key mega-trends and looming constraints , 2010 .

[4]  Gavin M. Mudd,et al.  Modelling future copper ore grade decline based on a detailed assessment of copper resources and mining , 2014 .

[5]  Helen R. Watling,et al.  The bioleaching of sulphide minerals with emphasis on copper sulphides — A review , 2006 .

[6]  Yan-jun Li,et al.  Flotation behaviors and mechanisms of chalcopyrite and galena after cyanide treatment , 2016 .

[7]  Yue-hua Hu,et al.  Synthesis of acetic acid-[(hydrazinylthioxomethyl)thio]-sodium and its application on the flotation separation of molybdenite from galena , 2017 .

[8]  Samuel Niza,et al.  The material basis of the global economy Worldwide patterns of natural resource extraction and their implications for sustainable resource use policies , 2007 .

[9]  Claude Bazin,et al.  Distribution of reagents down a flotation bank to improve the recovery of coarse particles , 2001 .

[10]  B. Xia,et al.  Human health risk from soil heavy metal contamination under different land uses near Dabaoshan Mine, Southern China. , 2012, The Science of the total environment.

[11]  Jan D. Miller,et al.  Ultrasound treatment on tailings to enhance copper flotation recovery , 2016 .

[12]  Özgür Eren,et al.  Reusing copper tailings in concrete: corrosion performance and socioeconomic implications for the Lefke-Xeros area of Cyprus , 2016 .

[13]  Qiang Li,et al.  Improving resource utilization efficiency in China's mineral resource-based cities: A case study of Chengde, Hebei province , 2015 .

[14]  Archana Agrawal,et al.  Problems, prospects and current trends of copper recycling in India: An overview , 2010 .

[15]  G. Mudd,et al.  Using sustainability reporting to assess the environmental footprint of copper mining , 2013 .

[16]  S. Jian,et al.  Utilization of iron tailings as substitute in autoclaved aerated concrete: physico-mechanical and microstructure of hydration products , 2016 .

[17]  Mei Zhang,et al.  Feasible conversion of solid waste bauxite tailings into highly crystalline 4A zeolite with valuable application. , 2014, Waste management.

[18]  Marcos A.S. Barrozo,et al.  Influence of particle size and reagent dosage on the performance of apatite flotation , 2008 .

[19]  Xianping Luo,et al.  The critical importance of pulp concentration on the flotation of galena from a low grade lead–zinc ore , 2016 .

[20]  Yue-hua Hu,et al.  Evaluation of the replacement of NaCN with depressant mixtures in the separation of copper–molybdenum sulphide ore by flotation , 2017 .

[21]  J. Yianatos,et al.  Speciation and leachability of copper in mine tailings from porphyry copper mining: influence of particle size. , 2005, Chemosphere.

[22]  N. Iglesias,et al.  Ferric leaching of copper slag flotation tailings , 2009 .

[23]  T. A. Pivovarova,et al.  Percolation bioleaching of copper and zinc and gold recovery from flotation tailings of the sulfide complex ores of the Ural region, Russia , 2012 .

[24]  Yanting Xie,et al.  Recovery of nickel, copper and cobalt from low-grade Ni–Cu sulfide tailings , 2005 .

[25]  G. Mudd Global trends in gold mining: Towards quantifying environmental and resource sustainability , 2007 .

[26]  P. Franzmann,et al.  Growth and activity of pure and mixed bioleaching strains on low grade chalcopyrite ore , 2008 .

[27]  M. Gericke,et al.  Bioleaching of copper sulphide concentrate using extreme thermophilic bacteria , 1999 .

[28]  H. Shirazi,et al.  Recovery of copper from reverberatory furnace slag by flotation , 2004 .

[29]  Kai-bin Fu,et al.  Effects of ultraviolet irradiation on bacteria mutation and bioleaching of low-grade copper tailings , 2011 .

[30]  T. Kondrat'eva,et al.  Leaching of copper and zinc from copper converter slag flotation tailings using H2SO4 and biologically generated Fe2(SO4)3 , 2012 .

[31]  S. Ilyas,et al.  Fungal Bioleaching of Metals From Mine Tailing , 2013 .

[32]  D. Banerjee,et al.  Comparison of two sequential extraction procedures for heavy metal partitioning in mine tailings. , 2010, Chemosphere.

[33]  Tao Chen,et al.  Metal recovery from the copper sulfide tailing with leaching and fractional precipitation technology , 2014 .

[34]  Wen-qing Qin,et al.  Cooperative bioleaching of chalcopyrite and silver-bearing tailing by mixed moderately thermophilic culture: An emphasis on the chalcopyrite dissolution with XPS and electrochemical analysis , 2015 .

[35]  Michel Shengo Lutandula,et al.  Recovery of cobalt and copper through reprocessing of tailings from flotation of oxidised ores , 2013 .

[36]  Yunfa Chen,et al.  Comprehensive recovery of metals from cyanidation tailing , 2015 .

[37]  G. Karimi,et al.  Removal of hematite from silica sand ore by reverse flotation technique , 2008 .

[38]  M. Dimitrijević,et al.  Investigation of the possibility of copper recovery from the flotation tailings by acid leaching. , 2008, Journal of hazardous materials.

[39]  M. Gericke,et al.  Tank bioleaching of low-grade chalcopyrite concentrates using redox control , 2010 .

[40]  Chang-Ping Yu,et al.  Using material/substance flow analysis to support sustainable development assessment: A literature review and outlook , 2012 .

[41]  M. Owor,et al.  Impact of tailings from the Kilembe copper mining district on Lake George, Uganda , 2007 .

[42]  Qi Liu,et al.  Effect of calcium ions and citric acid on the flotation separation of chalcopyrite from galena using dextrin , 2000 .

[43]  Jianshe Liu,et al.  Leaching of heavy metals from Dexing copper mine tailings pond , 2013 .

[44]  Xue-duan Liu,et al.  The effect of potential heap construction methods on column bioleaching of copper flotation tailings containing high levels of fines by mixed cultures , 2016 .

[45]  D. Koca,et al.  On modelling the global copper mining rates, market supply, copper price and the end of copper reserves , 2014 .