论文信息 - trans-Allylstannylation of certain acetylenes catalysed by ZrCl4 - 字舞流文

trans-Allylstannylation of certain acetylenes catalysed by ZrCl4

The trans-allylstannylation of simple acetylenes 1 is catalysed by ZrCl4 to produce the corresponding alkenylstannanes 3 (or alkenes 4 upon protonolysis of the C–Sn bond) in a regio- and stereo-selective manner.

Yoshinori Yamamoto | N. Asao | Y. Matsukawa

[1] M. Yamada,et al. Carboindation of Alkynes. Regio- and Stereoselective Allylation of Carbon-Carbon Triple Bonds of Alkynols by Allylic Indium Reagents , 1995 .

[2] S. Murai,et al. Pd-Catalyzed Coupling Reaction of Acetylenes, Iodotrimethylsilane, and Organozinc Reagents for the Stereoselective Synthesis of Vinylsilanes , 1995 .

[3] M. Kotora,et al. Copper catalyzed CC bond formation reaction of allylzirconation products of alkynes , 1994 .

[4] Yoshinori Yamamoto,et al. SELECTIVE REACTIONS USING ALLYLIC METALS , 1993 .

[5] E. Negishi. Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses , 1981 .

[6] W. Oppolzer. Intramolecular, Stoichiometric (Li, Mg, Zn) and Catalytic (Ni, Pd, Pt) Metallo‐Ene Reactions in Organic Synthesis [New Synthetic Methods (75)] , 1989 .